Colloid and Polymer Science

, Volume 297, Issue 11–12, pp 1499–1505 | Cite as

Superhydrophobic polymer composite coating on glass via spin coating technique

  • Mukesh Kumar Meena
  • Apurba Sinhamahapatra
  • Aditya KumarEmail author
Original Contribution


In this work, a superhydrophobic coating on glass surface has been prepared by using polymethylmethacrylate, SiO2 nanoparticles, and hexadecyltrimethoxysilane via spin coating technique. Coating was characterized by using contact angle measurement technique, scanning electron microscopy, and Fourier-transform infrared spectroscopy. Coating shows the superhydrophobic nature with water contact angle of 165 ± 5° and tilt angle of 7 ± 1°. Thermal, chemical, and mechanical stability of coating was also examined, and it is found excellent wetting stability of coating under harsh conditions. Droplet dynamics behavior of water droplets on coating was also studied and bouncing, pinning, and splashing of water droplets are observed at different impact velocities. Coating also exhibits the excellent self-cleaning nature. Prepared coating shows its several industrial applications.


PMMA Superhydrophobic Self-cleaning Spin coating Polymeric coating 


Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.


  1. 1.
    Guo Z, Liu W (2007) Biomimic from the superhydrophobic plant leaves in nature: binary structure and unitary structure. Plant Sci 172:1103–1112CrossRefGoogle Scholar
  2. 2.
    Bhushan B (2018) Biomimetic: bioinspired hierarchical-structured surfaces for green science and technologythird edn. Springer International, ChamCrossRefGoogle Scholar
  3. 3.
    Lai Y, Tang Y, Gong J, Gong D, Chi L, Lin C, Chen Z (2012) Transparent superhydrophobic/ super hydrophilic TiO2-based coatings for self-cleaning and anti-fogging. J Mater Chem 22:7420–7426CrossRefGoogle Scholar
  4. 4.
    Huang K, Yeh S, Huang C (2015) Surface modification for superhydrophilicity and underwater superoleophobicity: applications in antifog, underwater self- cleaning, and oil-water separation. ACS Appl Mater Interfaces 7:21021–21029CrossRefGoogle Scholar
  5. 5.
    Mishchenko L, Hatton B, Bahadur V, Taylor JA, Krupenkin T, Aizenberg J (2010) Design of ice-free nanostructured surfaces based on repulsion of impacting water droplets. ACS Nano 4:7699–7707CrossRefGoogle Scholar
  6. 6.
    Cao L, Jones AK, Sikka VK, Wu J, Gao D (2009) Anti-icing superhydrophobic coatings. Langmuir 25:12444–12448CrossRefGoogle Scholar
  7. 7.
    Rao AV, Latthe SS, Mahadik SA, Kappenstein C (2011) Mechanically stable and corrosion resistant superhydrophobic sol-gel coatings on copper substrate. Appl Surf Sci 257:5772–5776CrossRefGoogle Scholar
  8. 8.
    Verma LK, Sakhuja M, Son J, Danner AJ, Yang H, Zheng HC, Bhatia CS (2011) Self-cleaning and antireflective packaging glass for solar modules. Renew Energy 36:2489–2493CrossRefGoogle Scholar
  9. 9.
    Qiu W, Xu D, Liu B, Shen L, Guo Q (2015) Fabrication of superhydrophobic surfaces by smoke deposition and application in oil −water separation. RSC Adv 5:71329–71335CrossRefGoogle Scholar
  10. 10.
    Mahadik SA, Parale V, Vhatkara RS, Mahadik DB, Kavale MS, Wagh PB, Gupta S, Gurav J (2013) Superhydrophobic silica coating by dip coating method. Appl Surf Sci 277:67–72CrossRefGoogle Scholar
  11. 11.
    Wang S, Li M, Lu Q (2010) Filter paper with selective absorption and separation of liquids that differ in surface tension. ACS Appl Mater Interfaces 2:677–683CrossRefGoogle Scholar
  12. 12.
    Wang J, Chen X, Kang Y, Yang G, Yu L, Zhang P (2010) Preparation of superhydrophobic poly (methyl methacrylate)-silicon dioxide nanocomposite films. Appl Surf Sci 257:1473–1477CrossRefGoogle Scholar
  13. 13.
    Manoudis PN, Karapanagiotis I, Tsakalof A, Zuburtikudis I, Panayiotou C (2008) Superhydrophobic composite films produced on various substrates. Langmuir 24:11225–11232CrossRefGoogle Scholar
  14. 14.
    Kumar AM, Latthe SS, Sudhagar P, Obot IB, Gasem ZM (2015) In-situ synthesis of hydrophobic SiO2-PMMA composite for surface protective coatings: experimental and quantum chemical analysis. J Polymer 77:79–86CrossRefGoogle Scholar
  15. 15.
    Kinoshita H, Ogasahara A, Fukuda Y, Ohmae N (2010) Superhydrophobic/superhydrophilic micropatterning on a carbon nanotube film using a laser plasma-type hyper thermal atom beam facility. Carbon 48:4403–4408CrossRefGoogle Scholar
  16. 16.
    Hwang HS, Lee SB, Park I (2010) Fabrication of raspberry-like superhydrophobic hollow silica particles. Mater Lett 64:2159–2162CrossRefGoogle Scholar
  17. 17.
    Ma M, Mao Y, Gupta M, Gleason KK, Rutledge GC (2005) Superhydrophobic fabrics produced by electrospinning and chemical vapor deposition. Macromolecules 38:9742–9748CrossRefGoogle Scholar
  18. 18.
    Zhang X, Zhao J, Mo J, Suna R, Li Z, Guo Z (2019) Fabrication of superhydrophobic aluminum surface by droplet etching and chemical modification. J Colloids Surf A567:205–212CrossRefGoogle Scholar
  19. 19.
    Shi Y, yang W, Feng X, Wang Y, Yue G (2015) Fabrication of superhydrophobic ZnO nano rod surface with corrosion resistance via combining thermal oxidation and surface modification. J Mater Lett 151:24–27CrossRefGoogle Scholar
  20. 20.
    Gurav AB, Xu Q, Latthe SS, Vhatkar RS, Liu S, Yoon H, Yoon SS (2015) Superhydrophobic coatings prepared from methyl-modified silica particles using simple dip-coating method. Ceram Int 41:3017–3023CrossRefGoogle Scholar
  21. 21.
    Gao Q, Zhu Q, Guo Y (2009) Formation of highly hydrophobic surfaces on cotton and polyester fabrics using silica sol nanoparticles and non fluorinatedalkylsilane. Ind Eng Chem Res 48:9797–9803CrossRefGoogle Scholar
  22. 22.
    Forooshani HM, Aliofkhazraei M, Rouhaghdam AS (2017) Superhydrophobic aluminum surfaces by mechanical/chemical combined method and its corrosion behavior. J Taiwan Inst Chem Eng 72:220–235CrossRefGoogle Scholar
  23. 23.
    Latthe SS, Demirel AL (2013) Polystyrene/octadecyltrichlorosilane superhydrophobic coatings with hierarchical morphology. Polym Chem 4:246–249CrossRefGoogle Scholar
  24. 24.
    Costa ROR, Freitas RFS (2002) Phase behavior of poly (N-isopropylacrylamide) in binary aqueous solutions. Polymer 43:5879–5885CrossRefGoogle Scholar
  25. 25.
    Ebert D, Bhushan B (2012) Transparent, superhydrophobic, and wear-resistant coatings on glass and polymer substrates using SiO2, ZnO, and ITO nanoparticles. Langmuir 28:11391–11399CrossRefGoogle Scholar
  26. 26.
    Ge M, Cao C, Huang J, Zhang X, Tang Y, Zhou X, Zhang K, Chen Z, Lai Y (2018) Rational design of materials interface at nanoscale towards intelligent oil–water separation. Nanoscale Horiz 3:235–260CrossRefGoogle Scholar
  27. 27.
    Yilgor E, Soz CK, Yilgör I (2018) Wetting behavior of superhydrophobic poly(methyl methacrylate). Prog Org Coat 125:530–536CrossRefGoogle Scholar
  28. 28.
    Guo D, Chen J, Hou K, Xu S, Cheng J, Wen X, Wang S, Huangb C, Pia P (2018) A facile preparation of superhydrophobic hallo site-based meshes for efficient oil–water separation. J Appl Clay Sci 156:195–201CrossRefGoogle Scholar
  29. 29.
    Nanda D, Varshney P, Satapathy M, Mohapatra SS, Bhushan B, Kumar A (2017) Single-step method to fabricate durable superliquiphobic coating on aluminum surface with self-cleaning and anti-fogging properties. J Colloid Interface Sci 507:397–409CrossRefGoogle Scholar
  30. 30.
    Zhang J, CAI J, Li M (2016) Grafting of PMMA brushes layer on Cu surface to create a stable superhydrophobic surface. J Appl Surf Sci 386:309–318CrossRefGoogle Scholar
  31. 31.
    Cassie ABD, Baxter S (1944) Wettability of porous surfaces. Trans Faraday Soc 40:546–551CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Mukesh Kumar Meena
    • 1
  • Apurba Sinhamahapatra
    • 1
  • Aditya Kumar
    • 1
    Email author
  1. 1.Department of Chemical EngineeringIndian Institute of Technology (Indian school of mines)DhanbadIndia

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