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Cycloaliphatic epoxy resin cured with anhydride in the absence of catalyst

  • Anna I. Barabanova
  • Boris V. Lokshin
  • Elena P. Kharitonova
  • Irina V. Karandi
  • Egor S. Afanasyev
  • Andrey A. Askadskii
  • Olga E. Philippova
Invited Article
  • 3 Downloads

Abstract

Understanding mechanisms of cycloaliphatic epoxy resin curing with anhydride is important for the preparation of new thermosetting polymer materials. In this paper, the curing of commercial epoxy monomer 4-epoxycyclohexylmethyl-3,4-epoxycyclohexane-carboxylate ERL-4221 with 4-methylhexahydrophthalic anhydride in the absence of catalyst was studied by two complementary methods: Fourier-transform infrared spectroscopy and differential scanning calorimetry. Different reaction pathways were examined, and the most probable curing mechanism was proposed. It was shown that the synthesized polymer network possesses glass transition temperature of 222 °C, which is among the highest values for cured epoxy resin obtained so far.

Keywords

Cycloaliphatic epoxy resin Curing 

Notes

Funding information

The work was financially supported by the Russian Science Foundation (project no. 17-13-01535).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

396_2018_4430_MOESM1_ESM.docx (185 kb)
ESM 1 (DOCX 185 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Anna I. Barabanova
    • 1
    • 2
  • Boris V. Lokshin
    • 1
  • Elena P. Kharitonova
    • 2
  • Irina V. Karandi
    • 1
  • Egor S. Afanasyev
    • 1
  • Andrey A. Askadskii
    • 1
    • 3
  • Olga E. Philippova
    • 2
  1. 1.A.N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia
  2. 2.Physics DepartmentMoscow State UniversityMoscowRussia
  3. 3.Moscow State University of Civil EngineeringMoscowRussia

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