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Colloid and Polymer Science

, Volume 296, Issue 10, pp 1627–1633 | Cite as

The nucleation effect of self-dispersed β-nucleating agent in ethylene-propylene block copolymerized polypropylene

  • Yaoding Yang
  • Wenxue Zhang
  • Wei Qin
  • Zhong Xin
  • Shicheng Zhao
  • Lan Chen
  • Shuai Zhou
Original Contribution
  • 111 Downloads

Abstract

The problem of agglomeration and poor dispersion results in the low nucleation efficiency of β-nucleating agent (β-NA) in polypropylene. In this paper, a self-dispersed β-NA (Adi-Zn) was prepared in situ (IS) by adding adipic acid and zinc oxide at equimolar ratio in PPB powder during extrusion. The results showed that the nucleation efficiency of Adi-Zn (IS) was better than the direct addition of Adi-Zn. The impact strength of PPB nucleated with 0.05 wt% Adi-Zn (IS) was 25% higher than that with the same additive amount of Adi-Zn. Also, the β-crystal content (kβ value) almost reached 1. Crystallization temperature of PPB nucleated with Adi-Zn (IS) was slightly increased compared with that of Adi-Zn. The reaction mechanism of Adi-Zn (IS) was explored by Fourier transform infrared spectroscopy (FTIR). The results showed that adipic acid and zinc oxide generated zinc adipate, and zinc adipate acted as β-NA during the crystallization of PPB. By means of energy dispersive X-ray (EDX) analysis and transmission electron microscopy (TEM), the reason for the good dispersion of in situ synthetic method was confirmed, which further leads to good nucleation efficiency of Adi-Zn (IS).

Keywords

In situ Self-dispersed Nucleation efficiency β-Nucleating agent 

Notes

Funding information

This work was supported by the National Key R&D Program of China (2016YFB0302201), National Natural Science Foundation of China (Grants 21476085 and 21606084), and the Fundamental Research Funds for the Central Universities (222201717025).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Yaoding Yang
    • 1
  • Wenxue Zhang
    • 2
  • Wei Qin
    • 1
  • Zhong Xin
    • 1
  • Shicheng Zhao
    • 1
  • Lan Chen
    • 1
  • Shuai Zhou
    • 1
  1. 1.Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, Department of Product EngineeringEast China University of Science and TechnologyShanghaiPeople’s Republic of China
  2. 2.Lanzhou Petrochemical Research Center, PetroChinaLanzhouPeople’s Republic of China

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