Colloid and Polymer Science

, Volume 293, Issue 11, pp 3131–3143 | Cite as

Catanionic surfactant systems—thermodynamic and structural conditions revisited

  • Leonardo Chiappisi
  • Hacer Yalcinkaya
  • Vicknesh Kumar Gopalakrishnan
  • Michael Gradzielski
  • Thomas Zemb
Invited Article

Abstract

In this work, we review shortly the current state of knowledge about catanionic surfactant systems with a focus on the detailed understanding based on the molecular buildup of such systems and of the electrostatic interaction that controls their amphiphilic monolayer and bilayer. Particularly relevant here is the extent of hydrophobicity of the oppositely charged partners, which can range from just having a more or less hydrophobic counterion until a real surfactant of opposite charge. Based on this discussion, we then investigate different systems based on cetyltrimethylammonium (CTA) combined with either laurate (L) as an oppositely charged surfactant or naphthalenesulfonate (NS) as a strongly hydrophobic counterion. Both systems were studied for the case of having salt present by combining the two amphiphilic salts but also the salt-free situation which arises from combining the hydroxide with the acid. The phase behavior was determined as well as the mesoscopic structures present, as obtained by small-angle neutron scattering (SANS) and light scattering, which allow to discern formation of wormlike micelles and vesicles. Their presence was then further confirmed by rheological measurements, where in particular normal forces allow to distinguish the two types of aggregates, and control of rheology is a key property in such systems. In addition, the thermodynamic conditions in these systems were determined by means of differential scanning calorimetry (DSC). Based on these results, a consistent understanding of the formed structures and their macroscopic properties that arise from the molecular conditions in these systems is presented.

Keywords

Catanionic surfactants Wormlike micelles Vesicles Phase behavior 

Notes

Acknowledgments

The support of Anja von Lospichl and Benjamin von Lospichl during SANS beamtime is gratefully acknowledged. For the WET-STEM, we are grateful to Johann Ravaux and Anne Laure Fameau. Th. Z would like to thank the Deutsche Forschungsgemeinschaft (DFG) for awarding him a Mercator professorship within the International Graduate Research Training Group 1524 (“Self-Assembled Soft Matter Nano-Structures at Interfaces”).

Supplementary material

396_2015_3739_MOESM1_ESM.pdf (541 kb)
ESM 1 (PDF 540 kb)

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Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  1. 1.Institut de Chimie Séparative de Marcoule (ICSM)Bagnols sur CèzeFrance
  2. 2.Stranski-Laboratorium für Physikalische und Theoretische Chemie, Institut für ChemieTechnische Universität BerlinBerlinGermany

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