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Colloid and Polymer Science

, Volume 292, Issue 12, pp 3137–3146 | Cite as

Effect of alkyl chain length on chemical sensing of polydiacetylene and polydiacetylene/ZnO nanocomposites

  • Aide Wu
  • Yuan Gu
  • Huiquan Tian
  • John F. Federici
  • Zafar Iqbal
Original Contribution

Abstract

Polydiacetylenes (PDAs) and PDA/ZnO nanocomposites based on the monomers 10,12-pentacosadiynoic acid (PCDA), 10,12-tricosadiynoic acid (TCDA), and 10,12-docosadiynedioic acid (DCDA) monomers have been investigated for chromatic chemical sensing of a number of organic liquids. Chromatic sensitivity is associated with the interaction of the organic liquid with the PDA side chain to give rise to the strain-induced blue to red colorimetric transition. Attenuated total reflection (ATR) Fourier transform infrared (FTIR) spectroscopy demonstrated that in the PDA/ZnO nanocomposites, the PDA side chains form chelates with ZnO. The chromatic properties of PDAs and PDA/ZnO composites in organic liquids, to certain extent, depend on the side-chain length and the number of carboxylic head groups. Pure PDAs and PDA/ZnO nanocomposites in different organic liquids studied by Raman spectroscopy show that the chromatic selectivity of PDAs for certain organic liquids with respect to the blue to red phase transition is closely related to the side-chain structure of the PDAs. Moreover, the interactions are stronger with those PDAs where the blue to red transition is irreversible. Density functional theory (DFT) simulations show that the chromatic sensitivity of the PDAs toward a particular organic correlates with the C–C bond torsion angle of the PDA backbone.

Keywords

Conjugated polymer Nanocomposite Chemosensor DFT simulation 

Notes

Acknowledgments

The authors acknowledge support by ARDEC, Picatinny Arsenal, and CarboMet LLC.

Supplementary material

396_2014_3365_MOESM1_ESM.docx (156 kb)
Figure S1 (DOCX 156 kb)

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Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  • Aide Wu
    • 1
  • Yuan Gu
    • 1
  • Huiquan Tian
    • 3
  • John F. Federici
    • 1
  • Zafar Iqbal
    • 2
  1. 1.Department of PhysicsNew Jersey Institute of TechnologyNewarkUSA
  2. 2.Department of Chemistry and Environmental ScienceNew Jersey Institute of TechnologyNewarkUSA
  3. 3.Key Laboratory of Computational GeodynamicsUniversity of Chinese Academy of ScienceBeijingChina

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