Colloid and Polymer Science

, Volume 288, Issue 16–17, pp 1525–1537 | Cite as

Some fundamental aspects of the kinetics of flow-induced crystallization of polymers

Review

Abstract

Some indispensable fundamental aspects of the kinetics of polymer crystallization are summed up. Those aspects are of particular interest in the development of crystalline structures during polymer processing. In this connection also a monograph (Janeschitz-Kriegl 2009) must be mentioned, which has been written last year by the first author of this article. The present paper contains a selection of particularly interesting subjects. It turns out that many of these subjects have eluded a mathematical treatment. The pertinent list is given in the introduction. And those people, who feel pressed to produce computer programs, are exhorted to mind the content of the present article and also of the mentioned monograph in avoiding arbitrary assumptions.

Keywords

Polymers Crystallization Kinetics 

Notes

Acknowledgment

The preparation of this report was carried out in the course of activities sponsored by the Austrian Science Foundation FWF under the contract nb. P 21228-N14.

References

  1. 1.
    Janeschitz-Kriegl H (2009) Crystallization modalities in polymer melt processing. Springer, New YorkGoogle Scholar
  2. 2.
    Van Krevelen DW (1978) Crystallinity of polymers and the means to influence the crystallization process. Chimia 32:279–294Google Scholar
  3. 3.
    Janeschitz-Kriegl H, Ratajski E, Stadlbauer M (2003) Flow as an effective promotor of nucleation in polymer melts: a quantitative evaluation. Rheol Acta 42:355–364CrossRefGoogle Scholar
  4. 4.
    Marand H, Xu J, Srinivas S (1998) Determination of the equilibrium melting temperature of polymer crystals: linear and non-linear Hoffman-Weeks extrapolation. Macromolecules 31:8219–8229CrossRefGoogle Scholar
  5. 5.
    Lijima M, Strobl G (2000) Isothermal crystallization and remelting of isotactic polypropylene analized by time- and temperature-dependent small angle X-ray scattering experiments. Macromolecules 33:5204–5214CrossRefGoogle Scholar
  6. 6.
    Tribaut C, Monasse B, Haudin JM (1996) Experimental study of shear induced crystallization of an impact polypropylene copolymer. Colloid & Polymer Sci 274:197–208CrossRefGoogle Scholar
  7. 7.
    Janeschitz-Kriegl H, Eder G, Stadlbauer M, Ratajski E (2005) A thermodynamic frame for the kinetics of polymer crystallization under process conditions. Monatshefte für Chemie (in English) 136:1119–1137CrossRefGoogle Scholar
  8. 8.
    Olsen AP, Flagan RC, Kornfield JA (2006) Manipulation of athermal nuclei in aqueous solutions of poly(ethylene oxide) by scanning activity gravimetric analysis. Macromolecules 39:8419–8427CrossRefGoogle Scholar
  9. 9.
    Becker R, Döring W (1935) Kinetic treatment of nucleation in supersaturated vapor. Ann Phys 5(24):719–752CrossRefGoogle Scholar
  10. 10.
    Larson MA, Garside J (1986) Solute clustering in supersaturated solutions. Chem Engng Sci 41:1285–1289CrossRefGoogle Scholar
  11. 11.
    Tolman RC (1949) The effect of droplet size on the surface tension. J Chem Phys 17:331–337Google Scholar
  12. 12.
    Janeschitz-Kriegl H (2003) How to understand nucleation in crystallizing polymer melts under real processing conditions. Colloid Polym Sci 281:1157–1171CrossRefGoogle Scholar
  13. 13.
    Keller A (1957) Single crystals in polymers: evidence of folded chain configuration. Phil Mag 2:1171–1175CrossRefGoogle Scholar
  14. 14.
    Blundell DJ, Keller A, Kovacs AJ (1966) A new self-nucleation phenomenon and its application to the growing of polymer crystals from solution. Polym Lett 4:481–486CrossRefGoogle Scholar
  15. 15.
    Eder G, Janeschitz-Kriegl H, Liedauer S (1990) Crystallization processes in quiescent and moving polymer melts under heat transfer conditions. Progr Polym Sci 15:629–714CrossRefGoogle Scholar
  16. 16.
    Janeschitz-Kriegl H, Eder G (2007) Shear induced crystallization, a relaxation process in polymer melts: a recollection. J Macromol Sci B Phys 46:1–11CrossRefGoogle Scholar
  17. 17.
    Alfonso GC (1999) Formation of cylindric morphology in melt-sheared it-polybutene-1. Polym Mat Sci Engng 81:330–331Google Scholar
  18. 18.
    Schultz JM, Petermann J (1984) Transmission electron microscope observations of fibrillar-lamellar transformation in melt-drawn polymers-I. Isotactic polypropylene Colloid & Polymer Sci 262:294–305CrossRefGoogle Scholar
  19. 19.
    Braun J, Wippel H, Eder G, Janeschitz-kriegl H (2003) Industrial solidification processes in polybutene-1. Part II. Influence of shear flow. Polym Engng Sci 43:188–203CrossRefGoogle Scholar
  20. 20.
    Janeschitz-Kriegl H (1983) Polymer melt rheology and flow birefringence. Springer, New York, pp. 93 and 108Google Scholar
  21. 21.
    Eder G, Janeschitz-Kriegl H, Ratajski E (2006) Towards the prediction of structure development in injection molded semicrystalline polymers. In: Greener J, Wimberger-Friedl R (eds) Precision injection molding. Carl Hanser, Munich, pp 137–152Google Scholar
  22. 22.
    Stadlbauer M, Janeschitz-Kriegl H, Eder G, Ratajski E (2004) New extensional rheometer for creep flow at high tensile stress. Part II Flow induced nucleation for the crystallization of iPP J Rheol 48:631–639Google Scholar
  23. 23.
    Kimata S, Sakurai T, Nozue Y, Kasahara T, Yamaguchi N, Karino T, Shibayama M, Kornfield JA (2007) Molecular basis of the Shish-Kebab morphology in polymer crystallization. Science 316:1014–1017CrossRefGoogle Scholar
  24. 24.
    Liedauer S, Eder G, Janeschitz-Kriegl H, Jerschow P, Geymayer W, Ingolic E (1993) On the kinetics of shear induced crystallization in polypropylene. Intern Polym Proc 8:236–244Google Scholar
  25. 25.
    Janeschitz-Kriegl H, Ratajski E (2005) Kinetics of polymer crystallization under processing conditions: transformation of dormant nuclei by the action of flow. Polymer 46:3856–3870CrossRefGoogle Scholar
  26. 26.
    Scelsi L, Mackley MR, Klein H, Olmsted PD, Graham RS, Harlen OG, McLeish TCB (2009) Experimental observations and matching viscoelastic specific work predictions of flow induced crystallization for molten polyethylene within two flow geometries. J Rheol 53:859–876CrossRefGoogle Scholar
  27. 27.
    Mykhaylyk OO, Chambon P, Graham RS, Patric J, Fairclough A, Olmsted PD, Ryan J (2008) Specific work of flow as a criterion for orientation in polymer crystallization. Macromolecules 41:1901–1904CrossRefGoogle Scholar
  28. 28.
    Doi M, Edwards SF (1986) The Theory of Polymer Dynamics, Oxford.Google Scholar
  29. 29.
    Hadinata C, Gabriel C, Ruellmann M, Laun HM (2005) Comparison of shear-induced crystallization behavior of PB-1 samples with different molecular weight distributions. J Rheol 49:327–349CrossRefGoogle Scholar
  30. 30.
    Hadinata C, Gabriel C, Ruellmann M, Kao N, Laun HM (2006) Shear-induced crystallization of PB-1 up to processing relevant shear rates. Rheol Acta 45:539–546CrossRefGoogle Scholar
  31. 31.
    Gortemaker FH, Hanssen MG, De Cindio B, Laun HM, Janeschitz-Kriegl H (1976) Flow birefringence of polymer melts: application to the investigation of time dependent rheological properties. Rheol Acta 15:256–267CrossRefGoogle Scholar
  32. 32.
    Lodge AS (1964) Elastic liquids. Academic, LondonGoogle Scholar
  33. 33.
    Wales JLS (1976) The application of flow birefringence to rheological studies of polymer melts. Doctoral Thesis, Delft University PressGoogle Scholar

Copyright information

© Springer-Verlag 2010

Authors and Affiliations

  1. 1.Institute of Polymer ScienceJohannes Kepler UniversityLinzAustria

Personalised recommendations