Colloid and Polymer Science

, Volume 284, Issue 12, pp 1387–1393 | Cite as

Mechanism of the oxidation of d-glucose onto colloidal MnO2 surface in the absence and presence of TX-100 micelles

  • Kabir-ud-Din
  • Neelam Hazoor Zaidi
  • Mohd Akram
  • Zaheer Khan
Original contributions
First Online:
Received:
Accepted:

Abstract

Aqueous colloidal manganese dioxide (MnO2) was prepared via titration by using potassium permanganate and sodium thiosulphate in aqueous neutral medium. The kinetics of oxidation of d-glucose onto the surface of colloidal MnO2 have been studied spectrophotometrically. The results show that the rate of initial stage (nonautocatalytic path) increases with increasing the [d-glucose], [H+], and temperature and also upon addition of nonionic surfactant Triton X-100 (TX-100), which indicates that the surfactant enhances the concentration of d-glucose at the surface of the colloidal MnO2. Hydrogen bonding interaction seemingly arises between –OH groups of d-glucose and oxygen of the ether linkages of polyoxyethylene chain of TX-100. A possible mechanism of the oxidative degradation of d-glucose is discussed in terms of d-glucose/TX-100 and colloidal MnO2 interaction.

Keywords

Colloidal MnO2 Oxidation d-Glucose TX-100 
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Copyright information

© Springer-Verlag 2006

Authors and Affiliations

  • Kabir-ud-Din
    • 1
  • Neelam Hazoor Zaidi
    • 1
  • Mohd Akram
    • 1
  • Zaheer Khan
    • 2
  1. 1.Department of ChemistryAligarh Muslim UniversityAligarhIndia
  2. 2.Department of ChemistryJamia Millia IslamiaNew DelhiIndia

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