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Applied Physics B

, 122:194 | Cite as

Open-path cavity ring-down spectroscopy sensor for atmospheric ammonia

  • Soran Shadman
  • Charles Rose
  • Azer P. YalinEmail author
Article

Abstract

An open-path cavity ring-down spectroscopy (CRDS) sensor has been developed for measurement of atmospheric ammonia (NH3) and represents the first use of open-path CRDS in the mid-infrared region. The sensor uses a continuous-wave distributed feedback quantum cascade laser at 10.33 μm to target strong absorption features. The optical cavity is constructed with two high-reflectivity mirrors (R = 0.9995). The open-path configuration removes inlet effects, which are very challenging for closed-path instruments, and can be enabling for compact, low-power designs. Sensor performance was validated in the laboratory by measuring known concentrations in a closed-path configuration. The open-path configuration was validated by comparison against a commercial closed-path CRDS instrument for outdoor measurements at a small feed lot. Ammonia concentrations from the two instruments showed good agreement with slope of 0.990 (R 2 = 0.92), for 5-min averages. The precision of the open-path instrument was found from Allan variance studies as 1.2 ppb (2-σ) for 3-s measurement durations.

Keywords

Quantum Cascade Laser Differential Optical Absorption Spectroscopy Wavelength Modulation Spectroscopy Trigger Circuit Optical Sensitivity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

The authors acknowledge funding from the National Robotics Initiative via USDA-NIFA Award 2012-67021-19978 and from the USDA Award 2016-67021-24456. The authors also acknowledge assistance from Kira Shonkwiler and Jay Ham for the use and operation of the commercial ring-down sensor, and Kevin Kirkham for the loan and donation of a mid-infrared beam profiler.

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Copyright information

© Springer-Verlag Berlin Heidelberg (outside the USA) 2016

Authors and Affiliations

  1. 1.Department of Mechanical EngineeringColorado State UniversityFort CollinsUSA

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