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Applied Physics B

, Volume 109, Issue 2, pp 333–343 | Cite as

A DFG-based cavity ring-down spectrometer for trace gas sensing in the mid-infrared

  • K. E. Whittaker
  • L. Ciaffoni
  • G. Hancock
  • R. Peverall
  • G. A. D. RitchieEmail author
Article

Abstract

Continuing studies into an all-diode laser-based 3.3 μm difference frequency generation cavity ring-down spectroscopy system are presented. Light from a 1,560 nm diode laser, amplified by an erbium-doped fibre amplifier, was mixed with 1,064 nm diode laser radiation in a bulk periodically poled lithium niobate crystal to generate 16 μW of mid-IR light at 3,346 nm with a conversion efficiency of \(0.05\,\%\,{\text{W}}^{-1}\,{\text{cm}}^{-1}\). This radiation was coupled into a 77 cm long linear cavity with average mirror reflectivities of 0.9996, and a measured baseline ring-down time of \(6.07\pm 0.03\,\upmu{\rm s}\). The potential of such a spectrometer was illustrated by investigating the \(P(3)\) transition in the fundamental \(\nu_{3}(F_{2})\) band of \({\text{CH}}_4\) both in a 7.5 ppmv calibrated mixture of \({\text{CH}}_4\) in air and in breath samples from methane and non-methane producers under conditions where the minimum detectable absorption coefficient (\(\alpha_{\rm min}\)) was \(2.8 \times 10^{-8}\,{\rm cm}^{-1}\) over 6 s using a ring-down time acquisition rate of 20 Hz. Allan variance measurements indicated an optimum \(\alpha_{\rm min}\) of \(2.9\times 10^{-9}\,{\rm cm}^{-1}\) over 44 s.

Keywords

Cavity Mode Periodically Pole Lithium Niobate Difference Frequency Generation Quasi Phase Match Periodically Pole Lithium Niobate Crystal 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

The authors are grateful to the EPSRC for providing a Doctoral Training Award for this project (KEW) and financial support through the grant EP/E019765/1.

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Copyright information

© Springer-Verlag 2012

Authors and Affiliations

  • K. E. Whittaker
    • 1
  • L. Ciaffoni
    • 1
  • G. Hancock
    • 1
  • R. Peverall
    • 1
  • G. A. D. Ritchie
    • 1
    Email author
  1. 1.Department of Chemistry, Physical and Theoretical Chemistry LaboratoryUniversity of OxfordOxfordUK

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