Applied Physics B

, Volume 97, Issue 1, pp 243–248 | Cite as

Laser-induced breakdown spectroscopy with laser irradiation on mid-infrared hydride stretch transitions: polystyrene

Article

Abstract

An investigation of laser-induced breakdown spectroscopy (LIBS) of a polymer (polystyrene) with laser irradiation in the mid-infrared (mid-IR) spectral region is presented. A particular goal of this study is to determine whether the LIBS signals are enhanced when the laser wavelength is tuned to that of a vibrational transition of the polymer. Significant enhancements were indeed observed upon irradiation on the C–H stretch fundamental vibrational transitions. In addition, mode-specific effects were observed; the signals were stronger, compared to the relative intensities in the one-photon absorption spectrum, for irradiation on the aromatic (phenyl) C–H stretch transitions, rather than those involving aliphatic (backbone) C–H modes. The applicability of mid-IR resonance enhanced LIBS for detection of residues on surfaces is discussed.

PACS

42.62.-b 52.50.Jm 52.70.Kz 

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Copyright information

© Springer-Verlag 2009

Authors and Affiliations

  1. 1.Department of ChemistryThe Johns Hopkins UniversityBaltimoreUSA

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