Applied Physics B

, Volume 90, Issue 3–4, pp 547–556

Nonlinear optical characteristics of self-assembled films of ZnO

  • Litty Irimpan
  • A. Deepthy
  • Bindu Krishnan
  • V.P.N. Nampoori
  • P. Radhakrishnan


In the present work, we have investigated the nonlinear optical properties of self-assembled films formed from ZnO colloidal spheres by z-scan technique. The sign of the nonlinear component of refractive index of the material remains the same; however, a switching from reverse saturable absorption to saturable absorption has been observed as the material changes from colloid to self-assembled film. These different nonlinear characteristics can be mainly attributed to ZnO defect states and electronic effects when the colloidal solution is transformed into self-assembled monolayers. We investigated the intensity, wavelength and size dependence of saturable and reverse saturable absorption of ZnO self-assembled films and colloids. Values of the imaginary part of third-order susceptibility are calculated for particles of size in the range 20–300 nm at different intensity levels ranging from 40 to 325 MW/cm2 within the wavelength range of 450–650 nm.


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  1. 1.
    O. Painter, R.K. Lee, A. Scherer, A. Yariv, J.D. O’Brien, P.D. Dapkus, I. Kim, Science 284, 1819 (1999)CrossRefGoogle Scholar
  2. 2.
    H.B. Sun, S. Matsuo, H. Misawa, Appl. Phys. Lett. 74, 786 (1999)CrossRefADSGoogle Scholar
  3. 3.
    E.W. Seelig, B. Tang, A. Yamilov, H. Cao, R.P.H. Chang, Mater. Chem. Phys. 9712, 1 (2002)Google Scholar
  4. 4.
    S.H. Park, Y.N. Xia, Langmuir 15, 266 (1999)CrossRefGoogle Scholar
  5. 5.
    S.G. Romanov, T. Maka, C.M.S. Torres, M. Muller, R. Zentel, Appl. Phys. Lett. 79, 731 (2001)CrossRefADSGoogle Scholar
  6. 6.
    K.P. Velikov, A. van Blaaderen, Langmuir 17, 4779 (2001)CrossRefGoogle Scholar
  7. 7.
    H. Cao, J.Y. Xu, D.Z. Zhang, S.H. Chang, S.T. Ho, E.W. Seelig, X. Liu, R.P.H. Chang, Phys. Rev. Lett. 84, 5584 (2000)CrossRefADSGoogle Scholar
  8. 8.
    N. Fujimura, T. Nishihara, S. Goto, J. Xu, T. Ito, J. Cryst. Growth 130, 269 (1993)CrossRefADSGoogle Scholar
  9. 9.
    L. Vayssieres, K. Keis, S.-E. Lindquist, A. Hagfeldt, J. Phys. Chem. B 105, 3350 (2001)CrossRefGoogle Scholar
  10. 10.
    R.L. Sutherland, Handbook of Nonlinear Optics (Marcel Dekker, New York, 1996), Chapt. 9Google Scholar
  11. 11.
    Y.X. Fan, J.L. He, Y.G. Wang, S. Liu, H.T. Wang, X.Y. Ma, Appl. Phys. Lett. 86, 101103 (2005)CrossRefADSGoogle Scholar
  12. 12.
    M.S. Bahae, A.A. Said, T.H. Wei, D.J. Hagan, E.W. Van Stryland, IEEE J. Quantum Electron. QE-26, 760 (1990)CrossRefADSGoogle Scholar
  13. 13.
    B. Gu, J. Wang, J. Chen, Y.X. Fan, J.P. Ding, H.T. Wang, Opt. Express 13, 9230 (2005)CrossRefADSGoogle Scholar
  14. 14.
    J. He, W. Ji, G.H. Ma, S.H. Tang, H.I. Elim, W.X. Sun, Z.H. Zhang, W.S. Chin, J. Appl. Phys. 95, 6381 (2004)CrossRefADSGoogle Scholar
  15. 15.
    M.S. Bahae, A.A. Said, E.W. van Stryland, Opt. Lett. 14, 955 (1989)ADSGoogle Scholar
  16. 16.
    D.L. Moreno, E.D. Rosa-Cruz, F.J. Cuevas, L.E. Regalado, P. Salas, R. Rodriguez, V.M. Castano, Opt. Mater. 19, 275 (2002)CrossRefADSGoogle Scholar
  17. 17.
    S. Sapra, D.D. Sarma, Phys. Rev. B 69, 125304 (2004)CrossRefADSGoogle Scholar
  18. 18.
    L. Guo, S. Yang, C. Yang, P. Yu, J. Wang, W. Ge, G.K.L. Wong, Appl. Phys. Lett. 76, 2901 (2000)CrossRefADSGoogle Scholar
  19. 19.
    J.G.E. Gardeniers, Z.M. Rittersm, G.J. Burger, J. Appl. Phys. 83, 7844 (1998)CrossRefADSGoogle Scholar
  20. 20.
    A. Kuroyanagi, Japan. J. Appl. Phys. 28, 219 (1989)CrossRefADSGoogle Scholar
  21. 21.
    R. Rojo, S. Yamada, H. Matsuda, J. Opt. Soc. Am. B 15, 2937 (1998)ADSCrossRefGoogle Scholar
  22. 22.
    L.E. Brus, J. Chem. Phys. 80, 4403 (1984)CrossRefADSGoogle Scholar
  23. 23.
    H.L. Cao, X.F. Qian, Q. Gong, W.M. Du, X.D. Ma, Z.K. Zhu, Nanotechnology 17, 3632 (2006)CrossRefADSGoogle Scholar
  24. 24.
    E. Hanamura, Phys. Rev. B 37, 1273 (1988)CrossRefADSGoogle Scholar
  25. 25.
    A. Nakamura, H. Yamada, T. Tokizaki, Phys. Rev. B 40, 8585 (1989)CrossRefADSGoogle Scholar
  26. 26.
    Y.B. Band, D.J. Harter, R. Bavli, Chem. Phys. Lett. 126, 280 (1986)CrossRefADSGoogle Scholar
  27. 27.
    J.-H. Lin, Y.-J. Chen, H.-Y. Lin, W.-F. Hsieh, J. Appl. Phys. 97, 033526 (2005)CrossRefADSGoogle Scholar
  28. 28.
    F.Z. Henari, J. Callaghan, W.J. Blau, P. Haisch, M. Hanack, Pure Appl. Opt. 6, 741 (1997)CrossRefADSGoogle Scholar
  29. 29.
    T.H. Wei, D.J. Hagan, M.J. Sence, E.W. Stryland, J.W. Perry, D.R. Coulter, Appl. Phys. B 54, 46 (1992)CrossRefADSGoogle Scholar
  30. 30.
    M.J. Weber (Ed.), CRC Handbook of Laser Science and Technology: Optical Materials (CRC Press, Boca Raton, 1997)Google Scholar
  31. 31.
    G. Wang, G.T. Kiehne, G.K.L. Wong, J.B. Ketterson, X. Liu, R.P.H. Chang, Appl. Phys. Lett. 80, 401 (2002)CrossRefADSGoogle Scholar
  32. 32.
    X.J. Zhang, W. Ji, S.H. Tang, J. Opt. Soc. Am. B 14, 1951 (1997)ADSGoogle Scholar
  33. 33.
    P.J. Gonalves, I.E. Borissevitch, L. de Boni, N.M. Barbosa Neto, J.J. Rodrigues Jr., S.C. Zlio, XXVI Encontro Nacional de Física da Matétia Condensada, 2003 Caxambu. XXVI ENFMC-Annals of Optics, Vol. V5 (2003)Google Scholar
  34. 34.
    H.P. Li, B. Liu, C.H. Kam, Y.L. Lam, W.X. Que, L.M. Gan, C.H. Chew, G.Q. Xu, Opt. Mater. 14, 321 (2000)CrossRefADSGoogle Scholar
  35. 35.
    S. Shi, W. Ji, S.H. Tang, J. Am. Chem. Soc. 116, 3615 (1994)CrossRefGoogle Scholar
  36. 36.
    A. Maeda, M. Ono, H. Kishida, T. Manako, A. Sawa, M. Kawasaki, Y. Tokura, H. Okamoto, Phys. Rev. B 70, 125117 (2004)CrossRefADSGoogle Scholar
  37. 37.
    M.Y. Han, W. Huang, C.H. Chew, L.M. Gan, X.J. Zhang, W. Ji, J. Phys. Chem. B 102, 1884 (1998)CrossRefGoogle Scholar
  38. 38.
    W. Zhang, H. Wang, K.S. Wong, Z.K. Tang, G.K.L. Wong, J. Ravinder, Appl. Phys. Lett. 75, 3321 (1999)CrossRefADSGoogle Scholar
  39. 39.
    R. Adair, L.L. Chase, S.A. Payne, Phys. Rev. B 39, 3337 (1989)CrossRefADSGoogle Scholar

Copyright information

© Springer-Verlag 2008

Authors and Affiliations

  • Litty Irimpan
    • 1
  • A. Deepthy
    • 2
  • Bindu Krishnan
    • 3
  • V.P.N. Nampoori
    • 1
  • P. Radhakrishnan
    • 1
  1. 1.International School of PhotonicsCochin University of Science and TechnologyCochinIndia
  2. 2.Amrita Institute of Medical SciencesCochinIndia
  3. 3.Centre for Materials for Electronics TechnologyThrissurIndia

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