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Applied Physics A

, 125:672 | Cite as

Structural, stoichiometric and optical constants of crystalline undoped lead iodide films prepared by the flash-evaporation method

  • Mousa M. Abdul-Gader JafarEmail author
  • Mahmoud H. Saleh
  • Tariq M. Al-Daraghmeh
  • Mais Jamil A. Ahmad
  • Maryam A. AbuEid
  • Nidal M. Ershaidat
  • Basim N. Bulos
Article
  • 43 Downloads

Abstract

The flash-evaporation method was used to deposit several thin films (1, 1.2, and 1.35 µm thick) of undoped lead iodide on glass slides held at \(150\) °C and \(200\) °C. Their X-ray diffraction patterns, scanning electron microscope micrographs, and energy-dispersive spectroscopy spectra revealed crystalline hexagonal 2H-polytypic structure and high stoichiometry (\({\text{PbI}}_{x} ;x \cong 1.9\)). Their as-measured normal-incidence transmittance \(T_{\text{exp}} (\lambda)\)–wavelength \(\lambda\) curves exhibited above a specific wavelength \(\lambda_{{\text{c}}} \approx 520{\text{ nm}}\) and many well-resolved interference-fringe maxima and minima, indicating good film uniformity. Below \(\lambda_{{\text{c}}}\), these \(T_{\text{exp}} (\lambda) - \lambda\) curves declined sharply toward \(T_{\text{exp}} (\lambda) \cong 0\), signifying high film crystallinity. The \(\lambda\) dependency of optical constants \(n(\lambda)\) and \(\kappa (\lambda)\) retrieved from numeric iterative curve fitting of \(T_{\text{exp}} (\lambda) - \lambda\) data to theoretical \(T_{{{\text{theor}}}} (\lambda)\) formula describe an air-supported {film/substrate} structure, combined with O’Leary–Johnson–Lim (OJL) interband transition dispersion model and a set of harmonic-like oscillator dispersion formulas. The retrieved bandgap energy \(E_{{\text{g}}}^{{{\text{opt}}}}\) and band-tail breadth \(\gamma\) were around \(2.4\,{\text{ eV}}\) and \(100\,{\text{ meV}}\), respectively. The determined \(n(\lambda) - \lambda\) data gave best curve fits to the Wemple–DiDomenico (WDD) equation with reasonable bandgap energy parameter \(E_{{\text{o}}} \cong 3.8\,{\text{ eV}} \cong 1.6\,E_{{\text{g}}}^{{{\text{opt}}}}\), single-oscillator energy strength \(E_{{\text{d}}} \cong 18\,{\text{ eV}}\) and static index of refraction \(n_{{\text{o}}} \cong 2.4\). The calculated optical absorption coefficient \(\alpha (\lambda) = 4{\uppi }\kappa (\lambda)/\lambda\) was found to obey the direct interband transition with bandgap energy \(E_{{\text{g}}} \cong 2.45\,{\text{ eV}}\) in the absorption edge region, near which the curve fits of \(\alpha (\lambda)\) to Urbach formula gave an Urbach tail parameter \({\Gamma }_{{\text{U}}}\) of \(45\,{\text{ meV}}\), consistent with the results of numerical analysis of \(T_{\text{exp}} (\lambda) - \lambda\) curves. The film thickness and substrate temperature had a slight effect on the determined optical parameters.

Notes

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Mousa M. Abdul-Gader Jafar
    • 1
    Email author
  • Mahmoud H. Saleh
    • 2
  • Tariq M. Al-Daraghmeh
    • 3
  • Mais Jamil A. Ahmad
    • 4
  • Maryam A. AbuEid
    • 5
  • Nidal M. Ershaidat
    • 1
  • Basim N. Bulos
    • 1
  1. 1.Department of Physics, School of ScienceThe University of JordanAmmanJordan
  2. 2.Department of Physics, Faculty of ScienceAl-Balqa Applied UniversityAl-SaltJordan
  3. 3.Department of Basic Science, Faculty of Arts and ScienceMiddle East UniversityAmmanJordan
  4. 4.Leibniz Institute für Analytische Wissenschaften-ISAS e.V.DortmundGermany
  5. 5.Department of Basic SciencesPrincess Sumaya University for TechnologyAmmanJordan

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