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Applied Physics A

, 125:19 | Cite as

Double-layer VO2 thin film patterned by SiO2 spheres with improved thermochromic properties for smart windows

  • Liwei Zhou
  • Ming Hu
  • Xiaolong Song
  • Xiaoyong Qiang
  • Jiran LiangEmail author
Article
  • 97 Downloads

Abstract

The double-layer vanadium dioxide (VO2) thin film patterned by SiO2 spheres has been fabricated to enhance luminous transmittance (Tlum) without severely expense of solar modulation ability (ΔTsol) for the thermochromic smart windows. The first layer of vanadium thin film was deposited on the substrate with self-assembly SiO2 spheres and then the SiO2 spheres was removed by ultrasonic oscillation. The orderly perforated vanadium thin film with regular pores formed. Afterwards, the second layer of vanadium thin film was deposited on the perforated vanadium thin film. The semi-perforated double layer of vanadium thin film formed and was rapid thermal annealed forming the semi-perforated double VO2 thin films. Compared with continuous VO2 thin film(Tlum, 8.8%, ΔTsol, 5.9%), the semi-perforated double VO2 layer possesses orderly-patterned crater, which facilitate Tlum (42.6%) and only slightly attenuate the ΔTsol (5.5%). The phase transition temperatures for continuous VO2 thin film and the optimized semi-perforated VO2 double layer thin film were 58 °C and 52 °C, respectively, far below 68 °C of bulky VO2. This structure should be very meaningful for the real application of VO2-based smart window in the future.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 61471264, 61271070, 60771019, 61101055) and the Natural Science Foundation of Tianjin (Grant No. 15JCYBJC46800).

References

  1. 1.
    F.J. Morin, Phys. Rev. Lett. 3(1), 34 (1959)CrossRefADSGoogle Scholar
  2. 2.
    J. Zheng, S. Bao, P. Jin, Nano Energy 11, 136 (2015)CrossRefGoogle Scholar
  3. 3.
    P. Jin, G. Xu, M. Tazawa, K. Yoshimura, Appl. Phys. A 77(3), 455 (2003)ADSGoogle Scholar
  4. 4.
    X. Qian, N. Wang, Y. Li, J. Zhang, Z. Xu, Y. Long, Langmuir 30(35), 10766 (2014)CrossRefGoogle Scholar
  5. 5.
    L. Zhou, J. Liang, M. Hu, P. Li, X. Song, Y. Zhao, X. Qiang, Appl. Phys. Lett. 110 (19) (2017)Google Scholar
  6. 6.
    X. Cao, N. Wang, J.Y. Law, S.C.J. Loo, S. Magdassi, Y. Long, Langmuir 30(6), 1710 (2014)CrossRefGoogle Scholar
  7. 7.
    L. Kang, Y. Gao, H. Luo, Z. Chen, J. Du, Z. Zhang, ACS Appl. Mater. Interfaces. 3(2), 135 (2011)CrossRefGoogle Scholar
  8. 8.
    M. Zhou, J. Bao, M. Tao, R. Zhu, Y. Lin, X. Zhang, Y. Xie, Chem. Commun. 49(54), 6021 (2013)CrossRefGoogle Scholar
  9. 9.
    G. Xu, P. Jin, M. Tazawa, K. Yoshimura, Appl. Surf. Sci. 244(1–4), 449 (2005)CrossRefADSGoogle Scholar
  10. 10.
    H. Poirazis, EBD-R–04/3 37, 1114 (2004)Google Scholar
  11. 11.
    Y. Ke, X. Wen, D. Zhao, R. Che, Q. Xiong, Y. Long, ACS Nano 11(7), 7542 (2017)CrossRefGoogle Scholar
  12. 12.
    Y. Cui, Y. Ke, C. Liu, Z. Chen, N. Wang, L. Zhang, Y. Zhou, S. Wang, Y. Gao, Y. Long, Joule 2(9), 1707 (2018)CrossRefGoogle Scholar
  13. 13.
    Y. Ke, I. Balin, N. Wang, Q. Lu, A.I.Y. Tok, T.J. White, S. Magdassi, I. Abdulhalim, Y. Long, ACS Appl. Mater. Interfaces. 8(48), 33112 (2016)CrossRefGoogle Scholar
  14. 14.
    Z. Cao, Y. Lu, X. Xiao, Y. Zhan, H. Cheng, G. Xu, Mater. Lett. 209 (Supplement C), 609 (2017)CrossRefGoogle Scholar
  15. 15.
    S. Wang, M. Liu, L. Kong, Y. Long, Xuchuan Jiang, and Aibing Yu. Prog. Mater Sci. 81, 1 (2016)CrossRefGoogle Scholar
  16. 16.
    M. Hada, D. Zhang, A. Casandruc, R.J.D. Miller, Y. Hontani, J. Matsuo, R.E. Marvel, R.F. Haglund, Phys. Rev. B 86(13), 134101 (2012)CrossRefADSGoogle Scholar
  17. 17.
    J. Liang, J. Li, L. Hou, X. Liu, ECS J. Solid State Sci. Technol. 5(5), P293 (2016)CrossRefGoogle Scholar
  18. 18.
    S. Wang, G. Liu, P. Hu, Y. Zhou, Y. Ke, C. Li, J. Chen, T. Cao, Y. Long, Adv. Mater. Interfaces 5(21), 1801063 (2018)CrossRefGoogle Scholar
  19. 19.
    Y. Ke, S. Wang, G. Liu, M. Li, T.J. White, Y. Long, Small 14(39), 1870178 (2018)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Liwei Zhou
    • 1
  • Ming Hu
    • 1
  • Xiaolong Song
    • 1
  • Xiaoyong Qiang
    • 1
  • Jiran Liang
    • 1
    Email author
  1. 1.School of MicroelectronicsTianjin UniversityTianjinPeople’s Republic of China

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