Effects of selenium concentration in the precursor solution on the material properties of cadmium selenide flower-like nanoparticles
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CdSe flower-like nanorods (NRs) were successfully synthesized by Sol–gel technique where a simple aqueous technique was applied. The effects of different selenium (Se) concentration in the precursor solution on the material properties were studied. The X-ray diffraction (XRD) analyses show that a cubic zinc blende crystal structure was formed. Variation in the crystallite sizes were observed for different amounts of Se used in the precursor. The sizes estimated from various techniques were in the range 3–5 nm. The XRD peak intensity reached an optimum when 8 mL of 0.5 M of reduced selenium was used. The surface topography obtained from the scanning electron microscope showed densely packed and uniformly distributed flower-like rod/blade-like shaped CdSe NRs. The Fourier transform infrared spectrophotometer gave the stretching vibrations of the CdSe NRs with some bands belonging to the capping agent and the solvent. Thermal analysis conducted portrayed the 8 mL sample to be more stable than other samples at various temperatures. The photoluminescence (PL) studies displayed a red shift in the emission peaks (550–575 nm) as the selenium concentration was increased from 4 to 12 mL. This was then followed by an increase in the PL peak intensity which reached a maximum at 8 mL of Se used during the synthesis. The band gap energies calculated from the absorption spectra decreased from 3.27 to 2.79 eV with an increase in the Se concentration. The percentage transmittance of CdSe NRs varied with different amounts of Se in the precursor solution.
The authors wish to acknowledge the financial support for this project from University of the Free State directorate of research fund and University of the Western Cape senate research fund.
- 18.L.I. Berger, Semiconductor Materials. (CRC Press, Boca Raton, 1996), pp. 202Google Scholar
- 20.B.D. Cullity, Elements of X-ray diffraction, 3rd edn. (A.W.P.C., Massachusetts, 1967), pp. 188–190Google Scholar
- 21.C.S. Barret, T.B. Massalski, Structure of Metals (Pergamon Press, Oxford, 1980), p. 204Google Scholar
- 22.Joint Committee on Powder Diffraction Standards, International Centre for diffraction data, USA file no: 19-0191, 143 (1984)Google Scholar
- 23.J. Sakaliuniene, J. Cyviene, B. Abakeviciene, J. Dudonis, Investigation of structural and optical properties of GDC thin films deposited by reactive magnetron sputtering. VIII international conference (2010), p 141Google Scholar
- 26.H.N. Aliya, M.R. Johan, Optical and FTIR studies of CdSe quantum dots. In Nanoelectronics conference (INEC), 2010 3rd international, IEEE (2010), pp. 887–887Google Scholar
- 27.B. Stuart, Infrared Spectroscopy. (Wiley, New York, 2005)Google Scholar
- 37.R. Koole, E. Groeneveld, D. Van maekelbergh, A. Meijerink, in Nanoparticles, ed. by C. de Mello Donega, Size Effects of Semiconductor Nanoparticles (Springer, Berlin, 2014), pp. 13–51Google Scholar
- 39.A.M. Maroof, Hegazy, A. El-Hameed, Characterization of CdSe-nanocrystals used in semiconductors for aerospace applications: production and optical properties. Astron. Geophys. 3(1), 82–87 (2014)Google Scholar