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Applied Physics A

, 124:758 | Cite as

Synthesis of graphitic carbon nitride via direct polymerization using different precursors and its application in lithium–sulfur batteries

  • Shanshan YaoEmail author
  • Sikang Xue
  • Sihuang Peng
  • Ruiduo Guo
  • Zongzhen Wu
  • Xiangqian Shen
  • Tianbao Li
  • Li Wang
Article
  • 227 Downloads

Abstract

The graphitic carbon nitride (g-C3N4) materials were prepared via direct polymerization of urea, melamine, thiourea, and dicyandiamide at the same conditions, respectively. The samples were tested by various characterization tools, so that to study the influences of precursors on the physical and electrochemical properties of g-C3N4. The results showed that the as-prepared U-CN (from urea), M-CN (from melamine), T-CN (from thiourea), and D-CN (from dicyandiamide) exhibited significantly different microstructures. The synthesized g-C3N4 powders were used as sulfur matrixes for lithium–sulfur batteries. The electrochemical properties revealed that urea-derived C3N4 showed the highest initial capacity of 1207 mAh g−1. Furthermore, it possesses excellent cycling stability for 500 cycles and remains capacity of 517 mAh g−1 at 0.37 mA cm−2. This work could provide a new perspective for the selection of proper precursors and the in-depth study of the electrochemical behaviors of the microstructure of g-C3N4.

Notes

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 51874146, 51504101), the China Postdoctoral Science Foundation (Grant Nos. 2018T110551, 2017M621640), the Six Talent Peaks Project of Jiangsu Province (XCL-125), the Natural Science Foundation of Jiangsu Province (Grant No. BK20150514), the Natural Science Foundation of Jiangsu Provincial Higher Education of China (Grant No. 15KJB430006), the Start-up Foundation of Jiangsu University for Senior Talents (Grant No. 15JDG014).

Supplementary material

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Supplementary material 1 (DOCX 784 KB)

Supplementary material 2 (AVI 1862 KB)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Shanshan Yao
    • 1
    Email author
  • Sikang Xue
    • 1
  • Sihuang Peng
    • 1
  • Ruiduo Guo
    • 1
  • Zongzhen Wu
    • 1
  • Xiangqian Shen
    • 1
    • 2
  • Tianbao Li
    • 2
  • Li Wang
    • 2
  1. 1.Institute for Advanced Materials, College of Materials Science and EngineeringJiangsu UniversityZhenjiangPeople’s Republic of China
  2. 2.Hunan Engineering Laboratory of Power Battery Cathode MaterialsChangsha Research Institute of Mining and MetallurgyChangshaPeople’s Republic of China

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