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Applied Physics A

, 123:727 | Cite as

Stabilized gold nanoparticles by laser ablation in ferric chloride solutions

  • M. I. Nouraddini
  • M. RanjbarEmail author
  • P. J. Dobson
  • H. Farrokhpour
  • C. Johnston
  • K. Jurkschat
Article

Abstract

In this study, laser ablation of gold was performed in different ferric chloride solutions and water as a reference. The ferric chloride solutions included hexachloro iron(III) and aquachloro iron(III) having low and high hydrolysis degree. Transmission electron microscope (TEM) images showed spherical gold nanoparticles (GNPs) in water, particles which are strongly agglomerated with intimate contact at their interfaces in hexachloro iron(III) and individual separated particles with a halo of an iron component in aquachloro iron(III). In addition, no combination of Au and Fe was found in HAADF analysis or X-ray diffraction (XRD) patterns. In optical investigations, it was observed that gold nanoparticles made in hexachloro iron(III) solutions have localized surface plasmon resonance (LSPR) peaks broader than in the case of water that are quenched after a few hours, while ablation in the aquachloro iron(III) solution provides narrow LSPR absorption with a long-term stability. According to X-ray photoelectron spectroscopy (XPS) there are metallic Au and Fe2+ states in the drop-casted samples. By comparison of cyclic voltammetry of solutions before and after laser ablation, strong agglomeration in hexachloro iron(III) was attributed to the reducing role of iron(III) creating an unstable gold surface in the chloride solution. In aquachloro iron(III), however, the observed stability was attributed to the formation of the halo of an iron compound around the particles.

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Copyright information

© Springer-Verlag GmbH Germany 2017

Authors and Affiliations

  • M. I. Nouraddini
    • 1
  • M. Ranjbar
    • 1
    Email author
  • P. J. Dobson
    • 2
  • H. Farrokhpour
    • 3
  • C. Johnston
    • 4
  • K. Jurkschat
    • 4
  1. 1.Department of PhysicsIsfahan University of TechnologyIsfahanIran
  2. 2.The Queen’s CollegeOxfordUK
  3. 3.Department of ChemistryIsfahan University of TechnologyIsfahanIran
  4. 4.Department of MaterialsOxford University, Begbroke Science ParkOxfordUK

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