Applied Physics A

, 122:838 | Cite as

Nondestructive Raman investigation on wall paintings at Sala Vaccarini in Catania (Sicily)

  • Germana Barone
  • Danilo Bersani
  • Alessia Coccato
  • Debbie Lauwers
  • Paolo Mazzoleni
  • Simona Raneri
  • Peter Vandenabeele
  • Davide Manzini
  • Giuseppe Agostino
  • Nicola Francesco Neri
Article
Part of the following topical collections:
  1. Innovation in Art Research and Technology

Abstract

In this work, the results of a Raman campaign for studying seventeenth-century Sicilian frescoes, by using two portable Raman systems, equipped with different excitation sources (785 and 1064 nm), are proposed. The measurements were performed with the aim to provide an in situ diagnostic analysis of the wall paintings (in terms of colorants and preparation layer) and to support the conservators in the framework of the ongoing restoration. The combined use of the two Raman spectrometers has given a complete overview on the artist palette and on the state of preservation of frescoes, also informing us about the technique employed by the painter. Natural pigments as hematite, vermillion, goethite, lead red, lead white and carbon-based black pigments have been identified. Additionally, the application of a transitional Romanesque–Renaissance frescoes method has been noticed by the systematic combined presence of calcite and gypsum in the substrate. Finally, the analyses have highlighted the presence of degradation products, mainly related to alteration of lead-based pigments.

Keywords

Raman Band Wall Painting PbSO4 Vermillion Raman Feature 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

The authors are very grateful to the Superintendence of Cultural Heritage of Catania for having allowing and supporting the measurement campaign carried out in April 2014 during the restoration works at Sala Vaccarini in Catania. The authors thank Ghent University for its financial support through the concerted research actions (GOA) program.

References

  1. 1.
    V. Librando, in Quattro progetti per il Monastero di, ed. by S. Nicolò l’Arena, Università degli Studi Catania (Catania, 1988), pp. 11–27Google Scholar
  2. 2.
    A. Perardi, L. Appolonia, P. Mirti, Anal. Chim. Acta 480, 317 (2003)CrossRefGoogle Scholar
  3. 3.
    P. Vandenabeele, J. Raman Spectrosc. 35, 607 (2004)ADSCrossRefGoogle Scholar
  4. 4.
    A. Deneckere, W. Schudel, M. Van Bos, H. Wouters, A. Bergmans, P. Vandenabeele, L. Moens, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 75, 511 (2010)ADSCrossRefGoogle Scholar
  5. 5.
    N. Buzgar, A. Buzatu, A. Apopei, V. Cotiugă, Vib. Spectrosc. 72, 142 (2014)CrossRefGoogle Scholar
  6. 6.
    D. Lauwers, A.G. Hutado, V. Tanevska, L. Moens, D. Bersani, P. Vandenabeele, Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 118, 294 (2013)ADSCrossRefGoogle Scholar
  7. 7.
    A. Zoppi, C. Lofrumento, E.M. Castellucci, P. Sciau, J. Raman Spectrosc. 39, 40 (2008)ADSCrossRefGoogle Scholar
  8. 8.
    A.M. Correia, M.J.V. Oliveira, R.J.H. Clark, M.I. Ribeiro, M.L. Duarte, Anal. Chem. 80, 1482 (2008)CrossRefGoogle Scholar
  9. 9.
    L. Burgio, R.J. ClarkSpectrochim, Acta A Mol. Biomol. Spectrosc. 57, 1491 (2001)CrossRefGoogle Scholar
  10. 10.
    S. Daniilia, D. Bikiaris, L. Burgio, P. Gavala, R.J.H. Clark, Y. Chryssoulakis, J. Raman Spectrosc. 33, 807 (2002)ADSCrossRefGoogle Scholar
  11. 11.
    M. Pérez-Alonso, K. Castro, I. Martinez-Arkarazo, M. Angulo, M.A. Olazabal, J.M. Madariaga, Anal. Bioanal. Chem. 379, 42 (2004)CrossRefGoogle Scholar
  12. 12.
    S. Aze, J.M. Vallet, A. Baronnet, O. Grauby, Eur. J. Mineral. 18, 835 (2006)CrossRefGoogle Scholar
  13. 13.
    S. Aze, J.M. Vallet, V. Detalle, O. Grauby, A. Baronnet, Phase Transit. 81, 145 (2008)CrossRefGoogle Scholar
  14. 14.
    S. Daniilia, E. Minopoulou, Fr.D. Demosthenous, G. Karagiannis, J. Archaeol. Sci. 35, 1695 (2008)CrossRefGoogle Scholar
  15. 15.
    E. Kotulanova, P. Bezdicka, D. Hradil, J. Hradilovà, S. Svarcova, T. Grygar, J. Cultural Herit 10, 367 (2009)CrossRefGoogle Scholar
  16. 16.
    G. Bertolotti, D. Bersani, P.P. Lottici, M. Alesiani, T. Malcherek, J. Schlueter, Anal. Bioanal. Chem. 402, 1451 (2012)CrossRefGoogle Scholar
  17. 17.
    R.L. Frost, W. Martens, J.T. Kloprogge, P.A. Williams, J. Raman Spectrosc. 33, 801 (2002)ADSCrossRefGoogle Scholar
  18. 18.
    R.L. Frost, M.L. Weier, J. Raman Spectrosc. 34, 776 (2003)ADSCrossRefGoogle Scholar
  19. 19.
    H.G.M. Edwards, D.W. Farwell, J. Raman Spectrosc. 39, 985 (2008)ADSCrossRefGoogle Scholar
  20. 20.
    D. Chiriu, P.C. Ricci, A. Polcaro, P. Braconi, D. Lanzi, D. Nadali, J. Spectrosc 14, 1 (2014)CrossRefGoogle Scholar
  21. 21.
    H.G.M. Edwards, D.W. Farwell, D.L.A. de Faria, A.M.F. Monteiro, M.C. Afonso, P. De Blasis, S. Eggers, J. Raman Spectrosc. 32, 17 (2001)ADSCrossRefGoogle Scholar
  22. 22.
    A. Aminzadeh, Spectrochim. Acta, Part A 53, 693 (1997)ADSCrossRefGoogle Scholar
  23. 23.
    H.G.M. Edwards, S.E.J. Villar, J. Jehlicka, T. Munshi, Spectrochimica Acta Part A 61, 2273 (2005)ADSCrossRefGoogle Scholar
  24. 24.
    S. Bruni, F. Cariati, P. Fermo, A. Pozzi, L. Toniolo, Thermochim. Acta 321, 161 (1998)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Germana Barone
    • 1
  • Danilo Bersani
    • 2
  • Alessia Coccato
    • 3
  • Debbie Lauwers
    • 4
  • Paolo Mazzoleni
    • 1
  • Simona Raneri
    • 1
  • Peter Vandenabeele
    • 3
  • Davide Manzini
    • 5
  • Giuseppe Agostino
    • 6
  • Nicola Francesco Neri
    • 6
  1. 1.Department of Biological, Geological and Environment SciencesUniversity of CataniaCataniaItaly
  2. 2.Physics and Earth Science DepartmentUniversity of ParmaParmaItaly
  3. 3.Department of ArchaeologyGhent UniversityGhentBelgium
  4. 4.Department of Analytical ChemistryGhent UniversityGhentBelgium
  5. 5.MadatecS.r.l.Pessano Con BornagoItaly
  6. 6.Superintendence of Cultural Heritage of CataniaCataniaItaly

Personalised recommendations