Integrating Al with NiO nano honeycomb to realize an energetic material on silicon substrate
Nano energetic materials offer improved performance in energy release, ignition, and mechanical properties compared to their bulk or micro counterparts. In this study, the authors propose an approach to synthesize an Al/NiO based nano energetic material which is fully compatible with a microsystem. A two-dimensional NiO nano honeycomb is first realized by thermal oxidation of a Ni thin film deposited onto a silicon substrate by thermal evaporation. Then the NiO nano honeycomb is integrated with an Al that is deposited by thermal evaporation to realize an Al/NiO based nano energetic material. This approach has several advantages over previous investigations, such as lower ignition temperature, enhanced interfacial contact area, reduced impurities and Al oxidation, tailored dimensions, and easier integration into a microsystem to realize functional devices. The synthesized Al/NiO based nano energetic material is characterized by scanning electron microscopy, X-ray diffraction, differential thermal analysis, and differential scanning calorimetry.
PACS62.23.Pq 68.35.-p 65.80.+n 81.70.Pg 85.85.+j
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- 1.A.W. Miziolek, Nanoenergetics: an emerging technology area of national importance. AMPTIAC 6(1), 43–48 (2002) Google Scholar
- 10.A. Hofmann, H. Laucht, D. Kovalev, V.Y. Timoshenko, J. Diener, N. Kunzner, E. Gross, Explosive composition and its use. US Patent 6 984 274, Jan. 10, 2006 Google Scholar
- 13.S. Apperson, R.V. Shende, S. Subramanian, D. Tappmeyer, S. Gangopadhyay, Z. Chen, K. Gangopadhyay, P. Redner, S. Nicholich, D. Kapoor, Generation of fast propagating combustion and shock waves with copper oxide/aluminum nanothermite composites. Appl. Phys. Lett. 91, 243109 (2007) CrossRefADSGoogle Scholar
- 16.O.B. Kubaschewski, C.B. Alcock, P.J. Spencer, Materials Thermochemistry, 6th edn. (Pergamon, Elmsford, 1993) Google Scholar
- 17.K. Zhang, C. Rossi, P. Alphonse, C. Tenailleau, NiO nano honeycomb realized by annealing Ni film deposited on silicon. J. Nanosci. Nanotech. (Accepted on Nov. 22, 2007) Google Scholar
- 18.T.W. Barbee, R.L. Simpson, A.E. Gash, J.H. Satcher, Nano-laminate-based ignitors. US Patent WO 2005 016850 A2, Feb. 24, 2005 Google Scholar