Applied Physics A

, Volume 86, Issue 4, pp 421–425 | Cite as

Preparation, structural, and calorimetric characterization of bicomponent metallic photonic crystals

  • M.E. Kozlov
  • N.S. Murthy
  • I. Udod
  • I.I. Khayrullin
  • R.H. Baughman
  • A.A. Zakhidov
Invited paper


We report preparation and characterization of novel bicomponent metal-based photonic crystals having submicron three-dimensional (3D) periodicity. Fabricated photonic crystals include SiO2 sphere lattices infiltrated interstitially with metals, carbon inverse lattices filled with metal or metal alloy spheres, Sb inverse lattices, and Sb inverse lattices filled with Bi spheres. Starting from a face centered SiO2 lattice template, these materials were obtained by sequences of either templating and template extraction or templating, template extraction, and retemplating. Surprising high fidelity was obtained for all templating and template extraction steps. Scanning electron microscopy (SEM), small angle X-ray scattering (SAXS) and differential scanning calorimetry (DSC) were used to characterize the structure and the effects of the structure on calorimetric properties. To the best of our knowledge, SAXS data on metallic photonic crystals were collected for first time.


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  1. 1.
    D. Cassagne, Ann. Phys. 23, 1 (1998)CrossRefGoogle Scholar
  2. 2.
    C.M. Soukoulis, Nanotechnology 13, 420 (2002)CrossRefADSGoogle Scholar
  3. 3.
    R. De La Rue, Nature Mater. 2, 74 (2003)CrossRefADSGoogle Scholar
  4. 4.
    A.A. Zakhidov, R.H. Baughman, Z. Iqbal, C. Cui, I. Khayrullin, O. Dantas, J. Marti, V.G. Ralchenko, Science 282, 897 (1998)CrossRefADSGoogle Scholar
  5. 5.
    L. Xu, W. Zhou, M.E. Kozlov, I.I. Khayrullin, I. Udod, A.A. Zakhidov, R.H. Baughman, J.B. Wiley, J. Am. Chem. Soc. 123, 763 (2001)CrossRefGoogle Scholar
  6. 6.
    L. Xu, L.D. Tung, L. Spinu, J.B. Wiley, A.A. Zakhidov, R.H. Baughman, Adv. Mater. 15, 1562 (2003)CrossRefGoogle Scholar
  7. 7.
    P.B. Landon, J. Gutierrez, J.P. Ferraris, I.L. Martinez, R. Giridharagopal, Y.-C. Wu, S. Lee, K. Parikh, J. Gillespie, G. Ussery, B. Karimi, R.H. Baughman, A.A. Zakhidov, R. Glosser, Physica B 338, 165 (2003)CrossRefADSGoogle Scholar
  8. 8.
    A.A. Zakhidov, R.H. Baughman, I.I. Khayrullin, I. Udod, M. Kozlov, N. Eradat, V.Z. Vardeny, M. Sigalas, R. Biswas, Synth. Metals 116, 419 (2001)Google Scholar
  9. 9.
    L. Xu, J.B. Wiley, W.L. Zhou, C. Frommen, L. Malkinski, J.-Q. Wang, R.H. Baughman, A.A. Zakhidov, Chem. Commun. 12, 997 (2000)CrossRefGoogle Scholar
  10. 10.
    V. Kamaev, V. Kozhevnikov, Z.V. Vardeny, P.B. Landon, A.A. Zakhidov, J. Appl. Phys. 95, 2947 (2004)CrossRefADSGoogle Scholar
  11. 11.
    P.B. Landon, B.G. Kim, R.H. Baughman, R. Glosser, A.A. Zakhidov, V. Kamaev, V. Vardeny, NATO Sci. Ser. II (Organic Nanophotonics) 100, 483 (2003)Google Scholar
  12. 12.
    J.G. Fleming, S.Y. Lin, I. El-Kady, R. Biswas, K.M. Ho, Nature 417, 52 (2002)CrossRefADSGoogle Scholar
  13. 13.
    A. Christ, S.G. Tikhodeev, N.A. Gippius, J. Kuhl, H. Giessen, Phys. Rev. Lett. 91, 183901 (2003)CrossRefADSGoogle Scholar
  14. 14.
    B.H. Juarez, C. Lopez, C. Alonso, J. Phys. Chem. B 108, 16708 (2004)CrossRefGoogle Scholar
  15. 15.
    K. Kanaya, S. Okayama, J. Phys. D Appl. Phys. 5, 43 (1972)CrossRefADSGoogle Scholar
  16. 16.
    J.V. Sanders, Acta Cryst. A 24, 427 (1968)CrossRefGoogle Scholar
  17. 17.
    P.R. Couchman, W.A. Jesser, Nature 269, 481 (1977)CrossRefADSGoogle Scholar
  18. 18.
    M. Blackman, S.J. Peppiatt, J.R. Sambles, Nature 239, 61 (1972)ADSGoogle Scholar
  19. 19.
    V. Yannopapas, A. Moroz, J. Phys.: Condens. Matter 17, 3717 (2005)CrossRefADSGoogle Scholar

Copyright information

© Springer-Verlag 2007

Authors and Affiliations

  • M.E. Kozlov
    • 1
  • N.S. Murthy
    • 2
  • I. Udod
    • 3
  • I.I. Khayrullin
    • 4
  • R.H. Baughman
    • 1
  • A.A. Zakhidov
    • 1
  1. 1.NanoTech InstituteThe University of Texas at DallasRichardsonUSA
  2. 2.Department of PhysicsUniversity of VermontBurlingtonUSA
  3. 3.Teva Pharmaceuticals USAFairfieldUSA
  4. 4.eMagin CorporationHopewell JunctionUSA

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