Polymer Bulletin

, Volume 46, Issue 2–3, pp 165–174 | Cite as

The study of the vapor-liquid interfacial polycondensation of the cyclohexylphosphonic dichloride with bisphenol A The influence of temperature, reaction time, base concentration and molar ratio on yield, inherent viscosity and molecular weight

The influence of temperature, reaction time, base concentration and molar ratio on yield, inherent viscosity and molecular weight
  • Smaranda Iliescu
  • Gheorghe Ilia
  • Adriana Popa
  • Gheorghe Dehelean
  • Lavinia Macarie
  • Liliana Pacureanu
  • Nicolae Hurduc

Summary

Polyphosphonate esters of molecular weights ∼ 104 were synthesized by base promoted liquid-vapor polycondensation of cyclohexylphosphonic dichloride with bisphenol A. The effect of temperature, reaction time, base concentration and molar ratio of reagents on yield, inherent viscosity and molecular weight of the obtained polymer was studied. A second order, central composite, rotatable experimental design was used to find domain experimental field for optimal yields and high inherent viscosities.

Keywords

Polymer Viscosity Ester Molecular Weight Reaction Time 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Copyright information

© Springer-Verlag Berlin Heidelberg 2001

Authors and Affiliations

  • Smaranda Iliescu
    • 1
  • Gheorghe Ilia
    • 1
  • Adriana Popa
    • 1
  • Gheorghe Dehelean
    • 1
  • Lavinia Macarie
    • 1
  • Liliana Pacureanu
    • 1
  • Nicolae Hurduc
    • 1
  1. 1.Romanian Academy, Institute of Chemistry Timisoara, 24 Mihai Viteazul Bd., RO-1900 Timisoara, Romania e-mail: smail@acad-tim.utt.ro, Fax: +40-56/191824RO

Personalised recommendations