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Composites of polyethylene and layered cobalt hydroxide salts as potential ultraviolet radiation absorbers

  • Neffer Arvey Gomez Gomez
  • Swami Arêa Maruyama
  • Andreas Leuteritz
  • Fernando WypychEmail author
Original Paper
  • 9 Downloads

Abstract

This paper describes the synthesis of cobalt hydroxide nitrate (CoHN) and cobalt hydroxide p-aminobenzoate (CoHAB), which were dispersed in polyethylene with the objective of protecting the polymer from ultraviolet (UV) radiation degradation. First, CoHN was synthesized by urea hydrolysis in the presence of Co(II) nitrate and the intercalation of p-aminobenzoate into CoHAB was performed under hydrothermal alkaline conditions. The structure and thermal stability of the CoHN and CoHAB were characterized by several instrumental techniques. Results indicated that both fillers were dispersed in polyethylene and absorb radiation in the whole UV range, modifying the behavior of the polymer degradation under artificial weathering conditions.

Graphical abstract

Keywords

Intercalation Layered hydroxide salts Composites p-Aminobenzoate Polyethylene Ultraviolet radiation Weathering 

Notes

Acknowledgements

We thank CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior), CNPq (Conselho Nacional de Desenvolvimento Cientifico e Tecnologico-Proc. 303846/2014-3 and 400117/2016-9) and FINEP (Financiadora de Estudos e Projetos) for financial support. N.A.G.G. and S.A.M. thank CAPES and CNPq for the PhD and postdoctoral scholarships, respectively.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Departamento de Quı́mica, Centro de Pesquisas em Quı́mica Aplicada, CEPESQUniversidade Federal do Paraná, UFPRCuritibaBrazil
  2. 2.Leibniz-Institut für Polymerforschung Dresden e.V.DresdenGermany

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