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Efficient removal of heavy metal ions from aqueous solution by a novel poly (1-vinylimidazole) chelate resin

  • Youning Chen
  • Wei Zhao
  • Xiaoling Yang
  • Yuhong Li
Original Paper
  • 67 Downloads

Abstract

Using SI-ATRP technique, 1-vinylimidazole (VI) monomer was directly modified onto the surface of CMPS resin to prepare a chelating resin (PVI-g-PS) with imidazole ring as functional group. The adsorption properties of Cd(II), Ni(II), Pb(II) and Cu(II) were studied. It was found that with the increase in ATRP time and the amount of VIM, the graft ratio of VIM increased linearly, which indicated that the density of imidazole ring on the surface of resin increased. Adsorption experiments showed that the resin has good adsorption properties for Cd(II), Ni(II), Pb(II) and Cu(II). At pH 5.0, the static saturated adsorption amount of PVIM-g-PS for Cd(II), Ni(II), Pb(II) and Cu(II) was 2.82, 1.77, 1.22 and 0.83 mmol g−1, respectively. The adsorption model could be described by Langmuir isothermal adsorption and the adsorption process accorded with quasi-first-order kinetic equation. In addition, the resin has good desorption rate and reusability. These findings suggest that the resin can be potentially applied to the efficient removal of heavy metal ions from wastewater.

Keywords

Surface-initiated ATRP Poly (1-vinylimidazole) chelate resin Heavy metal ions Adsorption 

Notes

Acknowledgements

This work was supported by Special Research Projects of Education Department of Shaanxi provincial Government (No. 15JK1782), “Cyanine Talent” of Xianyang Normal College (No. XSYQL201710), Horizontal Project of Xianyang Normal College (No. 2018XSYH014), Innovative Entrepreneurship Training Program for College Students of Shannxi Province (No. 2515), Innovative Entrepreneurship Training Program for College Students of Xianyang Normal College (No. 2017065) and University students innovation and entrepreneurship base team (Project) (No. XSYC201710).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Youning Chen
    • 1
  • Wei Zhao
    • 1
  • Xiaoling Yang
    • 1
  • Yuhong Li
    • 1
  1. 1.College of Chemistry and Chemical EngineeringXianyang Normal CollegeXianyangChina

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