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Polymer Bulletin

, Volume 76, Issue 2, pp 919–932 | Cite as

Synthesis of novel biodegradable elastomers based on poly[3-hydroxy butyrate] and poly[3-hydroxy octanoate] via transamidation reaction

  • Baki HazerEmail author
  • Elvan Akyol
  • Timur Şanal
  • Sophie Guillaume
  • Birten Çakmakli
  • Alexander Steinbuchel
Original Paper
  • 103 Downloads

Abstract

Poly(3-hydroxyalkanoate)s (PHAs) are a class of polymers receiving attention because of their potential as renewable, biodegradable and high-technology properties. Unlike most short chain length (scl) PHAs such as poly(3-hydroxybutyrate) (PHB), medium chain length (mcl) PHAs such as poly(3-hydroxyoctanoate) (PHO) exhibit low crystallinity and are elastomeric in character. PHB-b–PEG-b–PHO block copolymers can combine both properties in block copolymer matrix. In this study, we report the synthesis of the block copolymers combining the PHB and PHO blocks. Transamidation reactions of PHB with polyethylene glycol with primary amine yield equimolar amounts and PHB with amine ends. PHO reacts with the modified PHB containing the amine end to give PHB-b–PEG-b–PHO block copolymers. Structural analysis of the products was performed by using 1H–, 13C, heteronuclear single quantum coherence NMR techniques. Thermal and mechanical properties of the block polymers were also evaluated.

Keywords

Poly(3-hydroxyalkanoate) Poly(3-hydroxy butyrate) Poly(3-hydroxy octanoate) Poly(ethylene glycol) Transamidation 

Notes

Acknowledgements

This work was supported by the Bülent Ecevit University Research Funds (#BEU – 2013 – 72118496 - 02 and BEU - 2013 – 72118496 - 03). The authors thank to Prof. Dr. Mahmut Köse and Prof. Dr. İbrahim Demirtaş for their valuable discussion about the NMR spectra.

Supplementary material

289_2018_2410_MOESM1_ESM.docx (608 kb)
Supplementary material 1 (DOCX 608 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Baki Hazer
    • 1
    • 2
    • 3
    • 4
    Email author
  • Elvan Akyol
    • 1
  • Timur Şanal
    • 1
  • Sophie Guillaume
    • 5
  • Birten Çakmakli
    • 6
  • Alexander Steinbuchel
    • 7
    • 8
  1. 1.Department of Chemistry, Faculty of Arts and SciencesBülent Ecevit UniversityZonguldakTurkey
  2. 2.Department of Metallurgical and Materials Engineering, Faculty of EngineeringBülent Ecevit UniversityZonguldakTurkey
  3. 3.Department of Nano Technology EngineeringBülent Ecevit UniversityZonguldakTurkey
  4. 4.Department of Aircraft Airframe Engine MaintenanceKapadokya UniversityÜrgüpTurkey
  5. 5.Institute of Chemical Sciences of Rennes (ISCR), CNRS - University of RennesRennesFrance
  6. 6.Polymer Engineering Department, Faculty of Engineering and ArchitectureMehmet Akif Ersoy UniversityBurdurTurkey
  7. 7.Institute of Microbiology and BiotechnologyUniversity of MünsterMünsterGermany
  8. 8.Environmental Sciences DepartmentKing Abdulaziz UniversityJeddahSaudi Arabia

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