Synthesis and characterization of poly(styrene sulfonic acid-co-1-vinylimidazole-co-styrene) and its blends with poly(vinyl chloride) as proton conducting membranes
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The development of proton conducting membranes based on poly(styrene sulfonic acid-co-1-vinylimidazole-co-styrene) (PSSA-co-PVIm-co-PS)/poly(vinyl chloride) (PVC) blends is firstly reported. PSSA-co-PVIm-co-PS with three different terpolymer compositions were synthesized via conventional free radical polymerization by varying styrene feed. Successful syntheses were confirmed by 1H-nuclear magnetic resonance spectroscopy (1H-NMR), elemental analysis, and Fourier transform infrared spectroscopy (FTIR). Hydrolytically stable PSSA-co-PVIm-co-PS/PVC blend membranes were prepared via solution-cast method. Scanning electron microscopy (SEM) images along with two glass transition temperatures observed from differential scanning calorimetry (DSC) suggested immiscible polymer blends. Water uptake and ion exchange capacity (IEC) were found to decrease with increasing PS content in terpolymer. All blend membranes had high thermal decomposition onsets of 230 °C. The blends demonstrated high storage moduli at room temperature and high oxidative stability. Proton conductivity at 25 °C of membranes equilibrated with water vapor was found to depend on PS content, and a maximum conductivity of 7.8 × 10−5 S/cm was achieved from 1:1:4/PVC blend membrane. For dry membranes, the effect of PS amount on proton conduction was not clearly observed at elevated temperatures (100–120 °C).
KeywordsTerpolymerization Electrolyte Fuel cell Polymer blends
This work was supported by the Nanotechnology Center (NANOTEC), NSTDA, Ministry of Science and Technology, Thailand, through its program of Center of Excellence Network, National Research University Project of Thailand, Office of the Higher Education Commission, through the Advanced Functional Materials Cluster of Khon Kaen University (KKU), Integrated Nanotechnology Research Center at KKU, and the Center for Innovation in Chemistry (PERCH-CIC), Office of the Higher Education Commission, Ministry of Education. The authors gratefully acknowledge P. Thongbai for help with conductivity measurement.
- 2.Vinothkannan M, Kannan R, Kim AR, Kumar GG, Nahm KS, Yoo DJ (2016) Facile enhancement in proton conductivity of sulfonated poly (ether ether ketone) using functionalized graphene oxide—synthesis, characterization, and application towards proton exchange membrane fuel cells. Colloid Polym Sci 294(7):1197–1207. https://doi.org/10.1007/s00396-016-3877-8 CrossRefGoogle Scholar
- 11.Kreuer KD (1998) New proton conducting polymers for fuel cell applications. Solid state ionics: science and technology. World Science, SingaporeGoogle Scholar
- 30.Ahmad Z, Al-Awadi NA, Al-Sagheer F (2008) Thermal degradation studies in poly(vinyl chloride)/poly(methyl methacrylate) blends. Polym Degrad Stab 93(2):456–465. https://doi.org/10.1016/j.polymdegradstab.2007.11.019 CrossRefGoogle Scholar
- 31.Hartmann-Thompson C, Merrington A, Carver PI, Keeley DL, Rousseau JL, Hucul D, Bruza KJ, Thomas LS, Keinath SE, Nowak RM, Katona DM, Santurri PR (2008) Proton-conducting polyhedral oligosilsesquioxane nanoadditives for sulfonated polyphenylsulfone hydrogen fuel cell proton exchange membranes. J Appl Polym Sci 110(2):958–974. https://doi.org/10.1002/app.28665 CrossRefGoogle Scholar
- 32.Li J, Li H, Wu C, Ke Y, Wang D, Li Q, Zhang L, Hu Y (2009) Morphologies, crystallinity and dynamic mechanical characterizations of polypropylene/polystyrene blends compatibilized with PP-g-PS copolymer: effect of the side chain length. Eur Polym J 45(9):2619–2628. https://doi.org/10.1016/j.eurpolymj.2009.06.002 CrossRefGoogle Scholar
- 33.Boonrawd C, Uthailerd S, Pandhumas T, Panawong C, Youngme S, Martwiset S (2017) Imidazole-doped poly(styrene sulfonic acid-co-vinyl imidazole)/polyvinyl alcohol blends as proton conducting membranes. Chiang Mai J Sci (in press)Google Scholar