Polymer Bulletin

, Volume 73, Issue 2, pp 419–434 | Cite as

Properties and characterization of ethylene-vinyl acetate filled with carbon nanotube

  • Maziyar Sabet
  • Hassan Soleimani
  • Seyednooroldin Hosseini
Original Paper
First Online:
Received:
Revised:
Accepted:

Abstract

Ethylene-vinyl acetate (EVA) containing carbon nanotubes (CNTs) were prepared by melt blending. Morphological observation showed well dispersion of CNTs in EVA. Effect of CNTs on crystallization of EVA was studied by differential scanning calorimetry (DSC). The beginning and maximum crystallization temperatures for CNT/EVA composite resulted 10 and 5 °C higher than pure EVA, respectively, showing high nucleation capability of CNTs in EVA matrix. The morphologies were evaluated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and atomic force microscopy (AFM), whereas, flammability properties were assessed by thermogravimetric analysis (TGA), natural burning and cone calorimetry. It was resulted that when nanodimensional material was not well dispersed, degradation products were not changed significantly. Unlike, CNT/EVA nanocomposites gave reasonably good reductions in peak heat release even when well nano-dispersed has not been obtained due to formation of low permeable char containing graphitic carbon. It was noticeable that CNT addition to EVA reduced surface cracks of chars which improved barrier resistance to evolution of flammable volatiles and oxygen access to condensed phase. The CNTs declined heat release rates and mass loss rate by 50–60 %, prolonged combustion time to two times in CNT/EVA samples. The TGA data also displayed that CNTs increased thermal degradation temperatures and final charred residues of CNT/EVA samples. The experimental observations from the torque, morphological evolution tests, and SEM resulted that CNTs are utilized for (1) increase of melt viscosity due to network structure formation of CNTs in the EVA matrix; (2) the enhancement of thermoxidation stability as a result of the CNTs’ mechanical strength and integrity of the charred layers in the CNT/EVA nanocomposites; (3) the formation of compact charred layers promoted by CNTs acted as heat barrier and thermal insulation.

Keywords

Ethylene-vinyl acetate Carbon nanotube Nanocomposites 
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References

  1. 1.
    Thostenson ET, Chou TW (2003) On the elastic properties of carbon nanotube-based composites: modeling and characterization. J Phys D Appl Phys 36(573):82–90Google Scholar
  2. 2.
    Robertson J (2004) Realistic applications of CNTs. Mater Today 7(10):46–52CrossRefGoogle Scholar
  3. 3.
    Guadagno L, Vertuccio L, Sorrentino A, Raimondo M, Naddeo C, Vittoria V et al (2009) Mechanical and barrier properties of epoxy resin filled with multi-walled carbon nanotubes. Carbon 47(10):2419–2430CrossRefGoogle Scholar
  4. 4.
    Sabet M, Hassan A, Ratnam CT (2010) Mechanical, thermal and electrical properties of ethylene vinyl acetate irradiated by an electron-beam. Polym Plast Technol Eng 49(6):589–594CrossRefGoogle Scholar
  5. 5.
    Sabet M, Soleimani H, Hassan A, Ratnam CT (2015) Properties of ethylene-vinyl acetate filled with metal hydroxide. J Elastomers Plast 47:88–100CrossRefGoogle Scholar
  6. 6.
    Sabet M, Hassan A, Ratnam CT (2012) Electron beam irradiation of low density polyethylene/ethylene vinyl acetate filled with metal hydroxides for wire and cable applications. Polym Degrad Stab 97(8):1432–1437CrossRefGoogle Scholar
  7. 7.
    Sabet M, Soleimani H, Hassan A, Ratnam CT (2014) The effect of addition EVA and LDPE-g-MAH on irradiated LDPE filled with metal hydroxides. Polym Plast Technol Eng 53(8):775–783CrossRefGoogle Scholar
  8. 8.
    Sabet M, Hassan A, Ratnam CT (2013) Effect of zinc borate on flammability/thermal properties of ethylene vinyl acetate filled with metal hydroxides. J Reinf Plast Compos 32(15):1122–1128CrossRefGoogle Scholar
  9. 9.
    Giuliana Gorrasia G, Lietoa RD, Patimob G, Pasqualeb SD, Sorrentino A (2011) Structure–property relationships on uniaxially oriented carbon nanotube/polyethylene composites. Polymer 52:1124–1132CrossRefGoogle Scholar
  10. 10.
    Sandler JKW, Kirk JE, Kinloch IA, Shaffer MSP, Windle AH (2003) Ultra-low electrical percolation threshold in carbon-nanotube–epoxy composites. Polymer 44(19):5893–5899CrossRefGoogle Scholar
  11. 11.
    Bauhofer W, Kovacs JZ (2009) A review and analysis of electrical percolation in carbon nanotube polymer composites. Compos Sci Technol 69(10):1486–1498CrossRefGoogle Scholar
  12. 12.
    Xiao KQ, Zhang LC, Zarudi I (2007) Mechanical and rheological properties of carbon nanotube-reinforced polyethylene composites. Compos Sci Technol 67:177–182CrossRefGoogle Scholar
  13. 13.
    Cha SI, Kim KT, Arshad SN, Mo CB, Hong SH (2005) Extraordinary strengthening effect of carbon nanotubes in metal-matrix composites processed by molecular-level mixing. Adv Mater 17(11):1377–1381CrossRefGoogle Scholar
  14. 14.
    Cha SI, Kim KT, Lee KH, Mo CB, Hong SH (2005) Strengthening and toughening of carbon nanotube reinforced alumina composite fabricated by molecular level mixing process. Scripta Mater 53(7):793–797CrossRefGoogle Scholar
  15. 15.
    Liang GD, Tjong SC (2006) Electrical properties of low-density polyethylene/multiwalled carbon nanotube composites. Mater Chem Phys 100:132–137CrossRefGoogle Scholar
  16. 16.
    Singh BP, Prabha Parveen S et al (2011) Designing of multiwalled carbon nanotubes reinforced low density polyethylene composites for suppression of electromagnetic radiation. J Nanopart Res 13:7065–7074CrossRefGoogle Scholar
  17. 17.
    Dorigato A, Pegoretti AP (2010) Linear low-density polyethylene/silica micro- and nanocomposites: dynamic rheological measurements and modeling. eXPRESS. Polymer Letters 4:115–129CrossRefGoogle Scholar
  18. 18.
    Liang GD, Tjong SC (2006) Electrical properties of low-density polyethylene/multiwalled carbon nanotube nanocomposites. Mater Chem Phys 100:132–137CrossRefGoogle Scholar
  19. 19.
    Chen-Feng K, Hsu-Chiang K, Chen-Chi MM, Chia-Hsun C, Han-Lang W (2007) The preparation of carbon nanotube/linear low density polyethylene composites by a water-crosslinking reaction. Mater Lett 61:2744–2748CrossRefGoogle Scholar
  20. 20.
    Wenzhong T, Michael HS, Suresh GA (2003) Melt processing and mechanical property characterization of multi-walled carbon nanotube/high density polyethylene (MWNT/HDPE) composite films. Carbon 41:2779–2785CrossRefGoogle Scholar
  21. 21.
    Qinghua Z, Sanjay R, Dajun C, Dirk L, Piet JL (2006) Low percolation threshold in single-walled carbon nanotube/high density polyethylene composites prepared by melt processing technique. Carbon 44:778–785CrossRefGoogle Scholar
  22. 22.
    Tapas K, Saswata B, Chang E, Hong MEU, Partha K, Nam HK, Joong HL (2011) Preparation of functionalized graphene/linear low density polyethylene composites by a solution mixing method. Carbon 49:1033–1051CrossRefGoogle Scholar
  23. 23.
    Petra P, Tschke MAG, Ingo A, Sergej D, Dirk L (2004) Rheological and dielectrical characterization of melt mixed polycarbonate-multiwalled carbon nanotube composites. Polymer 45:8863–8870CrossRefGoogle Scholar
  24. 24.
    Tony M, Petra P, Tschke P, Halley MM, Steven EJB, Gerard P, Brennan DB, Patrick L, Darren M, John PQ (2005) Polyethylene multiwalled carbon nanotube composites. Polymer 46:8222–8232CrossRefGoogle Scholar
  25. 25.
    Marius CC, Matthew JHE, Manias GC, Alberto F, Gunter B, Rakesh KG, Charles AW (2007) The influence of carbon nanotubes, organically modified montmorillonites and layered double hydroxides on the thermal degradation and fire retardancy of polyethylene, ethylene vinyl acetate copolymer and polystyrene. Polymer 48:6532–6545CrossRefGoogle Scholar
  26. 26.
    Changchun W, Zhi-Xin G, Shoukuan F, Wei W, Daoben Z (2004) Polymers containing fullerene or carbon nanotube structures. Progress Polymer Science 29:1079–1141CrossRefGoogle Scholar
  27. 27.
    Zdenko S, Dimitrios T, Konstantinos P, Costas G (2010) Carbon nanotube–polymer composites: chemistry, processing, mechanical and electrical properties. Prog Polym Sci 35:357–401CrossRefGoogle Scholar
  28. 28.
    Sabet M, Soleimani H (2014) Mechanical and electrical properties of low density polyethylene filled with carbon nanotubes. IOP Conference Series. Mater Sci Eng 64(1):012001Google Scholar
  29. 29.
    Sabet M, Hassan A, Wahita MU, Ratnam TR (2010) Mechanical, thermal and electrical properties of ethylene vinyl acetate irradiated by an electron-beam. Polym Plast Technol Eng 49(6):589–594CrossRefGoogle Scholar
  30. 30.
    Li SN, Li ZM, Yang MB (2004) Carbon nanotubes induced nonisothermal crystallization of ethylene-vinyl acetate copolymer. Mater Lett 58:3967–3970CrossRefGoogle Scholar
  31. 31.
    Costache MC, Heidecker MJ (2007) The influence of carbon nanotubes organically modified montmorillonites and layered double hydroxides on the thermal degradation and fire retardancy of polyethylene, ethylene vinyl acetate copolymer and polystyrene. Polymer 48:6532–6545CrossRefGoogle Scholar
  32. 32.
    Huang CY, Wu JY (2011) The manufacture and investigation of multi-walled carbon nanotube/polypyrrole/EVA nano-polymeric composites for electromagnetic interference shielding. Thin Solid Films 519:4765–4773CrossRefGoogle Scholar
  33. 33.
    Gaoa F, Beyer G (2005) A mechanistic study of fire retardancy of carbon nanotube/ethylene vinyl acetate copolymers and their clay composites. Polym Degrad Stab 89:559–564CrossRefGoogle Scholar
  34. 34.
    Ye L, Wu Q, Qu B (2009) Synergistic effects and mechanism of multiwalled carbon nanotubes with magnesium hydroxide in halogen-free flame retardant EVA/MH/MWNT nanocomposites. Polym Degrad Stab 94:751–756CrossRefGoogle Scholar
  35. 35.
    Peeterbroeck S, Breugelmans L (2007) The influence of the matrix polarity on the morphology and properties of ethylene vinyl acetate copolymers–carbon nanotube nanocomposites. Composites Science and Technology 67:1659–1665CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • Maziyar Sabet
    • 1
  • Hassan Soleimani
    • 2
  • Seyednooroldin Hosseini
    • 3
  1. 1.Faculty of Engineering, Petroleum and Chemical EngineeringInstitut Teknologi Brunei (ITB)Bandar Seri BegawanBrunei Darussalam
  2. 2.Faculty of Science and Information Technology, Department of Fundamental and Applied SciencesUniversiti Teknologi PETRONAS (UTP)IpohMalaysia
  3. 3.Department of Petroleum EngineeringUniversiti Teknologi PETRONAS (UTP)IpohMalaysia

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