Polymer Bulletin

, Volume 69, Issue 6, pp 733–746 | Cite as

Preparation and properties of poly(butyl methacrylate/lauryl methacrylate) and its blend fiber

Original Paper

Abstract

The functionalized copolymers, based on butyl methacrylate (BMA), and lauryl methacrylate (LMA) with crosslinking agent HEMA (hydroxyethyl methacrylate) or DVB (divinyl benzene), have been innovatively synthesized by suspension polymerization for oil absorption. Further, the copolymers and polypropylene (PP) blend fiber were attained via melt spinning. Swelling behaviors were evaluated by equilibrium swelling experiment, oil absorbency test, gel fraction measurement, and optical observations in toluene. The thermal properties and morphologies of the blend fibers were analyzed by thermogravimetry (TGA) and a field-emission scanning electron microscope, respectively. The results show that the copolymers and their blend fibers have an impressive absorbency. PBMA/LMA/HEMA can be up to 35.18 g/g, showing the highest absorption in trichloroethylene. Optical images of swollen polymers in toluene depicted a colloidal translucence with gel structure. Thermogravimetric measurement demonstrates that the copolymer and PP are incompatible and PBMA/LMA/DVB component possesses more thermal stability. The micrographs of the blend fibers exhibit coarse surface and porous cross-section, which leads to the fibers being much more readily wetted by oil and provides a huge space for oil storage.

Keywords

Crosslink Swell Hydroxyethyl methacrylate Melt spinning Polypropylene Oil absorbency 

Notes

Acknowledgment

The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Grant nos.: 50673077 and 51103099).

References

  1. 1.
    Korhonen JT, Kettunen M, Ras RHA et al (2011) Hydrophobic nanocellulose aerogels as floating, sustainable, reusable, and recyclable oil absorbents. ACS Appl Mater Interfaces 3:1813–1816CrossRefGoogle Scholar
  2. 2.
    Atta AM, El-Ghazawy RAM, Farag RK et al (2006) Crosslinked reactive macromonomers based on polyisobutylene and octadecyl acrylate copolymers as crude oil sorbers. React Funct Polym 66:931–943CrossRefGoogle Scholar
  3. 3.
    Zhou M-H, Kim S-H, Park J-G et al (2000) Preparation and oil-absorptivity of crosslinked polymers containing stearylmethacrylate, 4-t-butylstyrene, and divinylbenzene. Polym Bull 44:17–24CrossRefGoogle Scholar
  4. 4.
    Jang J, Kim B-S (2000) Studies of crosslinked styrene-alkyl acrylate copolymers for oil absorbency application. II. Effects of polymerization conditions on oil absorbency. J Appl Polym Sci 77:914–920CrossRefGoogle Scholar
  5. 5.
    Ceylan D, Dogu S, Karacik B et al (2009) Evaluation of butyl rubber as sorbent material for the removal of oil and polycyclic aromatic hydrocarbons from seawater. Environ Sci Technol 43:3846–3852CrossRefGoogle Scholar
  6. 6.
    Atta AM, El-Ghazawy RAM, Farag RK et al (2006) Swelling and network parameters of oil sorbers based on alkyl acrylates and cinnamoyloxy ethyl methacrylate copolymers. J Polym Res 13:257–266CrossRefGoogle Scholar
  7. 7.
    Gammoun A, Tahiri S, Albizane A et al (2007) Separation of motor oils, oily wastes and hydrocarbons from contaminated water by sorption on chrome shavings. J Hazard Mater 145:148–153CrossRefGoogle Scholar
  8. 8.
    Rengasamy RS, Das D, Karan CP (2011) Study of oil sorption behavior of filled and structured fiber assemblies made from polypropylene, kapok and milkweed fibers. J Hazard Mater 186:526–532CrossRefGoogle Scholar
  9. 9.
    Bayat A, Aghamiri SF, Moheb A et al (2005) Oil spill cleanup from sea water by sorbent materials. Chem Eng Technol 28:1525–1528CrossRefGoogle Scholar
  10. 10.
    ASTM Standard D 792–07 (2007) Standard test method for density and specific gravity (relative density) of plastics by displacement. American Society for Testing and Materials, PhiladelphiaGoogle Scholar
  11. 11.
    Erandimala UK, Neckers DC (2010) Photoresponsive oil sorbers. J Polym Sci A 48:55–62CrossRefGoogle Scholar
  12. 12.
    Collins CD (2007) Methods in Biotechnology. In: Willey N (ed) Implementing phytoremediation of petroleum hydrocarbons phytoremediation, 1st edn. Humana Press, Totowa, pp 99–108Google Scholar
  13. 13.
    Feng Y, Xiao CF (2006) Research on butyl methacrylate-lauryl methacrylate copolymeric fibers for oil absorbency. J Appl Polym Sci 101:1248–1251CrossRefGoogle Scholar
  14. 14.
    Liu YP, Wu B, Zhou MH (2010) EPDM/tBS suspension copolymer for oil sorbency application. Mater Sci Technol 26:1288–1291CrossRefGoogle Scholar
  15. 15.
    Anslyn EV, Dougherty DA (2006) Modern physical organic chemistry. University Science, MissouriGoogle Scholar
  16. 16.
    Shriner RL (1980) The Systematic identification of organic compounds: a laboratory manual. Wiley, MinneapolisGoogle Scholar
  17. 17.
    Smallwood IMN (1996) Handbook of organic solvent properties. Arnold, New YorkGoogle Scholar
  18. 18.
    Singh R (2002) Adsorption chromatography. In: Bali N (ed) Chromatography, 1st edn. Mittal Publications, New Delhi, p 41Google Scholar
  19. 19.
    Xu NK, Xiao CF, Feng Y et al (2009) Study on absorptive property and structure of resin copolymerized by butyl methacrylate with hydroxyethyl methacrylate. Polym Plast Technol Eng 48:716–722CrossRefGoogle Scholar
  20. 20.
    Zhao J, Xiao CF, Xu NK et al (2011) Preparation and properties of oil-absorptive fiber based on polybutyl methacrylate-inter-polyhydroxyethyl methacrylate via wet spinning. Polym Plast Technol Eng 50:818–824CrossRefGoogle Scholar
  21. 21.
    Higaki Y, Otsuka H, Takahara A (2006) A thermodynamic polymer cross-linking system based on radically exchangeable covalent bonds. J Macromolecules 39:2121–2125CrossRefGoogle Scholar
  22. 22.
    Roy Choudhury N, Chaki TK, Bhowmick AK (1991) Thermal characterization of thermoplastic elastomeric natural rubber-polypropylene blends. Thermochim Acta 176:149–161CrossRefGoogle Scholar
  23. 23.
    Bismarck A, Mohanty AK, Aranberri-Askargorta I et al (2001) Surface characterization of natural fibers; surface properties and the water up-take behavior of modified sisal and coir fibers. Green Chem 3:100–107CrossRefGoogle Scholar
  24. 24.
    Liu PS, Liang KM (2001) Review Functional materials of porous metals made by P/M, electroplating and some other techniques. J Mater Sci 36:5059–5072CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 2012

Authors and Affiliations

  1. 1.School of TextileTianjin Polytechnic UniversityTianjinChina
  2. 2.School of Materials Science and EngineeringTianjin Polytechnic UniversityTianjinChina

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