Polymer Bulletin

, Volume 55, Issue 6, pp 437–445 | Cite as

Stability constants and thermodynamic parameters of some intermacromolecular complexes in relation to their specific interaction forces

  • B. Vasheghani F.Email author
  • F.H. Rajabi
  • M.H. Ahmadi
  • S. Nouhi


Intermacromolecular complexes of poly (acrylic acid) (PAA) with poly (ethylene oxide) (PEO), poly (ethylene imine) (PEI) and poly (vinyl pyrrolidon) (PVP) were prepared. The stability constants and thermodynamic parameters (e.g. ΔH0 and ΔS0) of these complexes were determined at several temperatures. The enthalpy and entropy changes of the systems with temperature have been interpreted in terms of various mode of interaction between the components and compared with each other.


Oxide Polymer Ethylene Entropy Enthalpy 
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Copyright information

© Springer-Verlag 2005

Authors and Affiliations

  • B. Vasheghani F.
    • 1
    Email author
  • F.H. Rajabi
    • 1
  • M.H. Ahmadi
    • 1
  • S. Nouhi
    • 1
  1. 1.Department of ChemistryFaculty of Science Imam Khomeini International UniversityQazvinI.R. Iran

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