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Physics and Chemistry of Minerals

, Volume 43, Issue 7, pp 459–480 | Cite as

Luminescence and tenebrescence of natural sodalites: a chemical and structural study

  • Teresa ZahoranskyEmail author
  • Henrik Friis
  • Michael A. W. Marks
Original Paper

Abstract

Sodalite (Na8Al6Si6O24Cl2) shows a wide range of colours and may exhibit a variety of optical properties including cathodoluminescence, photoluminescence and tenebrescence. These optical peculiarities are not yet fully understood but are of key interest for industry. We provide a detailed study on the photochromic properties of natural sodalite, and we show that S is crucially influencing luminescence of sodalites. A reduced intensity in cathodoluminescence was observed at high S contents for some samples, showing that S can act as cathodoluminescence quencher. Photoluminescent sodalites are generally enriched in S compared to non-photoluminescent samples, although few samples being very low in S still show photoluminescence. Additionally, S was found to enlarge the unit cell in natural sodalites which might have a crucial impact on their photochromic properties. The most efficient tenebrescent samples were found to be low in Fe, Mn and S. They showed the smallest unit-cell dimensions, and a strong link between the atomic structure and the formation of F-centres is proposed. Tenebrescence in natural sodalites appears to be enhanced (1) by S but saturated at too high S concentrations and (2) by a stoichiometry and structure close to the ideal sodalite composition. In contrast to the term self-quenching for luminescence, we propose a saturation of F-centres to explain tenebrescence at different S contents.

Keywords

Sodalite Luminescence Tenebrescence Sulphur species Structure Raman spectroscopy Self-quenching F-centres 

Notes

Acknowledgments

This work was part of the MSc thesis of the first author. Funding for fieldwork and travelling was provided by the Dr. Eberhard Kornbeck-Stiftung Tübingen, Germany, and by the Universitätsbund Tübingen, Germany, respectively. We wish to thank Thomas Wenzel for his help with EPMA analyses and Annette Flicker who helped with Raman spectroscopy. Tom Andersen and Siri Lene Simonsen assisted with LA-ICP-MS measurements and Adrian Finch kindly made samples available for this study. This manuscript benefitted from the reviews of T.E. Warner and M. Gaft.

Supplementary material

269_2016_810_MOESM1_ESM.pdf (5.4 mb)
Supplementary material 1 (PDF 5537 kb)

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Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Teresa Zahoransky
    • 1
    • 2
    Email author
  • Henrik Friis
    • 2
  • Michael A. W. Marks
    • 1
  1. 1.Fachbereich Geowissenschaften, Mathematisch-Naturwissenschaftliche FakultätUniversität TübingenTübingenGermany
  2. 2.Natural History MuseumUniversity of OsloOsloNorway

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