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Physics and Chemistry of Minerals

, Volume 39, Issue 5, pp 375–383 | Cite as

Compression behaviors of distorted rutile-type hydrous phases, MOOH (M = Ga, In, Cr) and CrOOD

  • Asami Sano-FurukawaEmail author
  • Takehiko Yagi
  • Taku Okada
  • Hirotada Gotou
  • Takumi Kikegawa
Original Paper

Abstract

X-ray diffraction measurements of distorted rutile-type oxyhydroxides β-GaOOH, InOOH, β-CrOOH, and β-CrOOD were taken at a maximum pressure of up to 35 GPa under quasi-hydrostatic conditions, at ambient temperature. Anomalies in the evolution of the relative lattice constants and the axial ratios of β-GaOOH, InOOH, and β-CrOOD suggest anisotropic stiffening along the a- and/or b-axes where the hydrogen bond is formed. The changes were observed at 15 GPa in β-GaOOH and InOOH and at 4 GPa in β-CrOOD. The pressures were higher in oxyhydroxides that have longer O…O distances of the hydrogen bond at ambient pressure. In contrast, such stiffening behavior was not observed in CrOOH, which has a significant short O…O distance and strong hydrogen bond. The stiffening behaviors observed in the present study can be attributed to the symmetrization of the hydrogen bonds in oxyhydroxides, as was previously found in δ-AlOOH(D).

Keywords

Hydrous mineral High pressure Equation of state Hydrogen bond Symmetrization 

Notes

Acknowledgments

Experiments were performed at BL13A and ARNE1, at the Photon Factory, KEK. A.S. was supported by a Grant-in-Aid for Young Scientists (B) from the Japan Society for the Promotion of Science (JSPS). Comments by anonymous reviewers improved the manuscript.

Supplementary material

269_2012_487_MOESM1_ESM.doc (158 kb)
Supplementary material 1 (DOC 157 kb)

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Copyright information

© Springer-Verlag 2012

Authors and Affiliations

  • Asami Sano-Furukawa
    • 1
    • 2
    Email author
  • Takehiko Yagi
    • 2
  • Taku Okada
    • 2
  • Hirotada Gotou
    • 2
  • Takumi Kikegawa
    • 3
  1. 1.Quantum Beam Science DirectorateJapan Atomic Energy AgencyTokaiJapan
  2. 2.Institute for Solid State PhysicsThe University of TokyoChibaJapan
  3. 3.Photon FactoryKEKTsukubaJapan

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