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Distribution, Sources, and Health Risk Assessment of Volatile Organic Compounds in Hefei City

Abstract

Volatile organic compounds (VOCs) are involved in the formation of ozone formation, which plays a significant role in regional air contamination and poses a great threat to human health. The VOCs were collected from the urban area of Hefei city via an off-line sampling method (SUMMA canister) and determined by gas chromatography–mass spectrometer. The average concentrations of VOCs were 17.65 ± 28.36 ppbv, which were mainly contributed by aromatics (10.02 ± 13.37 ppbv), haloalkane (5.37 ± 8.90 ppbv), ally halide (1.25 ± 3.36 ppbv), and aryl halid (1.02 ± 2.73 ppbv). According to the principal component analysis, three major sources were identified, including solvent use, vehicle exhaust, and industrial release, accounting for 70.6% of the total variance of the data. Health risk assessment was utilized to evaluate the potential adverse health effects of the individual VOC. The total hazard ratio in the selected area was higher than 1, where could pose health threat to exposed population. The cancer risk for benzene, carbon tetrachloride, trichloromethane, and 1, 2-dichloroethane were 4.8 × 10−5, 4.5 × 10−5, 3.3 × 10−5, and 2.5 × 10−5, respectively, indicating definite health risks.

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References

  1. An J, Zhu B, Wang H, Li Y, Lin X, Yang H (2014) Characteristics and source apportionment of VOCs measured in an industrial area of Nanjing, Yangtze River Delta, China. Atmos Environ 97:206–214

  2. Andreae M, Merlet P (2001) Emission of trace gases and aerosols from biomass burning. Global Biogeochem Cycles 15(4):955–966

  3. Atkinson R (1995) Gas-phase tropospheric chemistry of organic compounds: a review. Atmos Environ Part A Gen Top 24(1):1–41

  4. Atkinson R (2000) Atmospheric chemistry of VOCs and NOx. Atmos Environ 34(12):2063–2101

  5. Bari M, Kindzierski W (2018) Ambient volatile organic compounds (VOCs) in Calgary, Alberta: sources and screening health risk assessment. Sci Total Environ 631:627–640

  6. Barletta B, Meinardi S, Sherwood Rowland F, Chan CY, Wang X, Zou S, Chan LY, Blake DR (2005) Volatile organic compounds in 43 Chinese cities. Atmos Environ 39(32):5979–5990

  7. Batterman SA, Peng CY, Braun J (2002) Levels and composition of volatile organic compounds on commuting routes in Detroit, Michigan. Atmos Environ 36(39):6015–6030

  8. Borbon A, Locoge N, Veillerot M, Galloo JC, Guillermo R (2002) Characterisation of NMHCs in a French urban atmosphere: overview of the main sources. Sci Total Environ 292(3):177–191

  9. Brocco D, Fratarcangeli R, Lepore L, Petricca M, Ventrone I (1997) Determination of aromatic hydrocarbons in urban air of Rome. Atmos Environ 31(4):557–566

  10. Cai C, Geng F, Tie X, Yu Q, An J (2010) Characteristics and source apportionment of VOCs measured in Shanghai. China Atmos Environ 44(38):5005–5014

  11. Carter WPL (1994) Development of ozone reactivity scales for volatile organic compounds. J Air Waste Manag Assoc 44:881–899

  12. Cetin E, Odabasi M, Seyfioglu R (2003) Ambient volatile organic compound (VOC) concentrations around a petrochemical complex and a petroleum refinery. Sci Total Environ 312(1):103–112

  13. Chan L, Chu K, Zou S, Chan C, Wang X, Barletta B, Blake D, Hui G, Tsai W (2006) Characteristics of nonmethane hydrocarbons (NMHCs) in industrial, industrial-urban, and industrial-suburban atmospheres of the Pearl River Delta (PRD) region of south China. J Geophys Res Atmos 111:D11304

  14. Chen CH, Chuang YC, Hsieh CC, Lee CS (2019) VOC characteristics and source apportionment at a PAMS site near an industrial complex in central Taiwan. Atmos Pollut Res 10(4):1060–1074

  15. Choi E, Choi K, Yi SM (2011) Non-methane hydrocarbons in the atmosphere of a Metropolitan City and a background site in South Korea: sources and health risk potentials. Atmos Environ 45(40):7563–7573

  16. Dai H, Jing S, Wang H, Ma Y, Li L, Song W, Kan H (2017) VOC characteristics and inhalation health risks in newly renovated residences in Shanghai, China. Sci Total Environ 577:73–83

  17. Dumanoglu Y, Kara M, Altiok H, Odabasi M, Elbir T, Bayram A (2014) Spatial and seasonal variation and source apportionment of volatile organic compounds (VOCs) in a heavily industrialized region. Atmos Environ 98:168–178

  18. Elbir T, Cetin B, Cetin E, Bayram A, Odabasi M (2007) Characterization of volatile organic compounds (VOCs) and their sources in the air of Izmir, Turkey. Environ Monitor Assess 133(1–3):149

  19. Gariazzo C, Pelliccioni A, Filippo PD, Sallusti PD, Cecinato A (2005) Monitoring and analysis of volatile organic compounds around an oil refinery. Water Air Soil Pollut 167(1–4):17–38

  20. Geng F, Cai C, Tie X, Yu Q, An J, Peng L, Zhou GQ, Xu J (2009) Analysis of VOC emissions using PCA/APCS receptor model at city of Shanghai, China. Environ Sci 62(3):229–247

  21. Gu Y, Yu X, Yang W, Tian Z, Li M, Cheng P (2018) Characteristics and source apportionment of volatile organic compounds in the rainy season of Guangzhou City. Environ Sci 39(6):2528–2537

  22. Guo H, Wang T, Louie PKK (2004a) Source apportionment of ambient non-methane hydrocarbons in Hong Kong: application of a principal component analysis/absolute principal component scores (PCA/APCS) receptor model. Environ Pollut 129(3):489–498

  23. Guo H, Lee SC, Louie PKK, Ho KF (2004b) Characterization of hydrocarbons, halocarbons and carbonyls in the atmosphere of Hong Kong. Chemosphere 57(10):1363–1372

  24. Guo H, Wang T, Blake DR, Simpson IJ, Kwok YH, Li YS (2006) Regional and local contributions to ambient non-methane volatile organic compounds at a polluted rural/coastal site in Pearl River Delta. China Atmos Environ 40(13):2345–2359

  25. Guo H, So KL, Simpson IJ, Barletta B, Meinardi S, Blake DR (2007) C1–C8 volatile organic compounds in the atmosphere of Hong Kong: overview of atmospheric processing and source apportionment. Atmos Environ 41(7):1456–1472

  26. Han D, Wang Z, Cheng J, Wang Q, Chen X, Wang H (2017) Volatile organic compounds (VOCs) during non-haze and haze days in Shanghai: characterization and secondary organic aerosol (SOA) formation. Environ Sci Pollut Res 24(22):18619–18629

  27. Ho K, Lee S, Guo H, Tsai W (2004) Seasonal and diurnal variations of volatile organic compounds (VOCs) in the atmosphere of Hong Kong. Sci Total Environ 322(1):155–166

  28. Huang C, Chen CH, Li L, Cheng Z, Wang HL, Huang HY, Streets DG, Wang YJ (2011) The study of emission inventory on anthropogenic air pollutants and VOC species in the Yangtze River Delta region, China. Atmos Chem Phys Discuss 11(1):951–983

  29. Hui L, Liu X, Tan Q, Feng M, An J, Qu Y (2018) Characteristics, source apportionment and contribution of VOCs to ozone formation in Wuhan, Central China. Atmos Environ 192:55–71

  30. Hui L, Liu X, Tan Q, Feng M, An J, Qu Y, Zhang Y, Cheng N (2019) VOC characteristics, sources and contributions to SOA formation during haze events in Wuhan, Central China. Sci Total Environ 650:2624–2639

  31. Kourtidis KA, Ziomas IC, Rappenglueck B, Proyou A, Balis D (1999) Evaporative traffic hydrocarbon emissions, traffic CO and speciated HC traffic emissions from the city of Athens. Atmos Environ 33(23):3831–3842

  32. Kourtidis KA, Ziomas I, Zerefos C, Kosmidis E, Symeonidis P, Christophilopoulos E, Karathanassis S, Mploutsos A (2002) Benzene, toluene, ozone, NO and SO measurements in an urban street canyon in Thessaloniki, Greece. J Atmos Environ 36(34):5355–5364

  33. Leuchner M, Rappenglück B (2010) VOC source–receptor relationships in Houston during TexAQS-II. Atmos Environ 44(33):4056–4067

  34. Lin T, Sree U, Tseng S, Kong H, Wu C, Lo J (2004) Volatile organic compound concentrations in ambient air of Kaohsiung petroleum refinery in Taiwan. Atmos Environ 38(25):4111–4122

  35. Ling Z, Guo H, Cheng H, Yu Y (2011) Sources of ambient volatile organic compounds and their contributions to photochemical ozone formation at a site in the Pearl River Delta, southern China. Environ Pollut 159(10):2310–2319

  36. Liu Y, Shao M, Zhang J, Fu L, Lu S (2005) Distributions and source apportionment of ambient volatile organic compounds in Beijing city, China. J Environ Sci Health 40(10):1843–1860

  37. Liu Y, Shao M, Lu S, Chang CC, Wang JL, Fu L (2008) Source apportionment of ambient volatile organic compounds in the Pearl River Delta, China: part II. Atmos Environ 42(25):6261–6274

  38. Nan S, Liang J, Zhang D, Zhang R, Jiang N, Kexin D, Zhang J, Technology (2015) VOCs in ambient air of Zhengzhou City: spatial distribution and source apportionment. Environ Sci 38(3):119–124

  39. Niu Z, Zhang H, Xu Y, Liao X, Xu L, Chen J (2012) Pollution characteristics of volatile organic compounds in the atmosphere of Haicang District in Xiamen City, Southeast China. J Environ Monitor 14(4):1145–1152

  40. Pankow JF, Luo W, Bender DA, Isabelle LM, Hollingsworth JS, Cai C, Asher WE, Zogorski JS (2003) Concentrations and co-occurrence correlations of 88 volatile organic compounds (VOCs) in the ambient air of 13 semi-rural to urban locations in the United States. Atmos Environ 37(36):5023–5046

  41. Parra MA, Elustondo D, Bermejo R, Santamaría JM (2009) Ambient air levels of volatile organic compounds (VOC) and nitrogen dioxide (NO2) in a medium size city in Northern Spain. Sci Total Environ 407(3):999–1009

  42. Pérez-Rial D, López-Mahía P, Tauler R (2010) Investigation of the source composition and temporal distribution of volatile organic compounds (VOCs) in a suburban area of the northwest of Spain using chemometric methods. Atmos Environ 44(39):5122–5132

  43. Perry LI (1995) Vehicle emissions in relation to fuel composition. Sci Total Environ 169(1–3):149–156

  44. Santos CYM, de Azevedo Almeida D, de Aquino Neto FR, Santos CYMD (2004) Atmospheric distribution of organic compounds from urban areas near a coal-fired power station. Atmos Environ 38(9):1247–1257

  45. Sauvage S, Plaisance H, Locoge N, Wroblewski A, Coddeville P, Galloo JC (2009) Long-term measurement and source apportionment of non-methane hydrocarbons in three French rural areas. Atmos Environ 43(15):2430–2441

  46. Scheff PA, Wadden RA (1993) Receptor modeling of volatile organic compounds. 1. Emission inventory and validation. Environ Sci Technol 27(4):617–625

  47. Schneidemesser EV, Monks PS, Plass-Duelmer C (2010) Global comparison of VOC and CO observations in urban areas. Atmos Environ 44(39):5053–5064

  48. Song Y, Shao M, Liu Y, Lu S, Kuster W, Goldan P, Xie S (2007) Source apportionment of ambient volatile organic compounds in Beijing. Environ Sci Technol 41(12):4348–4353

  49. Srivastava A, Joseph AE, Patil S, More A, Dixit RC, Prakash M (2005) Air toxics in ambient air of Delhi. Atmos Environ 39(1):59–71

  50. Stemmler K, Bugmann S, Buchmann B, Reimann S, Staehelin J (2005) Large decrease of VOC emissions of Switzerland’s car fleet during the past decade: results from a highway tunnel study. Atmos Environ 39(6):1009–1018

  51. Su J, Min S, Lu S, Xie Y (2011) Non-methane volatile organic compound emission inventories in Beijing during Olympic Games 2008. Atmos Environ 45(39):7046–7052

  52. Tang J, Chan L, Chan C, Li Y, Chang C, Liu S, Wu D, Li Y (2007) Characteristics and diurnal variations of NMHCs at urban, suburban, and rural sites in the Pearl River Delta and a remote site in South China. Atmos Environ 41(38):8620–8632

  53. USEPA (2009) Risk assessment guidance for superfund, vol 1: Human health evaluation manual (Part F, supplemental guidance for inhalation risk assessment). EPA/540/R-070/002. USEPA Office of Superfund Remediation and Technology Innovation Environmental Protection Agency, Washington, DC

  54. Wang G, Cheng S, Wei W, Zhou Y, Yao S, Zhang H (2016) Characteristics and source apportionment of VOCs in the suburban area of Beijing, China. Atmos Pollut Res 7(4):711–724

  55. Warneke C, De Gouw JA, Holloway JS, Peischl J, Ryerson TB, Atlas E, Blake D, Trainer M, Parrish DD (2012) Multiyear trends in volatile organic compounds in Los Angeles, California: five decades of decreasing emissions. J Geophys Res Atmos 117(D21):D00V17

  56. Wei W, Li Y, Wang Y, Cheng S, Wang L (2018) Characteristics of VOCs during haze and non-haze days in Beijing, China: concentration, chemical degradation and regional transport impact. Atmos Environ 194:134–145

  57. Wu F, Jie S, Ye Y, Tang G, Wang Y (2016) Variation characteristics and source analysis of atmospheric volatile organic compounds in Chang-bai Mountain station. Environ Sci 37(9):72–79

  58. Yang Y, Liu X, Zheng J, Tan Q, Feng M, Qu Y, An J, Cheng N (2019) Characteristics of one-year observation of VOCs, NOx, and O3 at an urban site in Wuhan, China. J Environ Sci 79:297–310

  59. Yuan Z, Lau AKH, Shao M, Louie PK, Liu SC, Zhu T (2009) Source analysis of volatile organic compounds by positive matrix factorization in urban and rural environments in Beijing. J Geophys Res Atmos 114:D00G15

  60. Zhai ZX, Zou KH, Wei-Fang LI, Wang G, Zhai YC (2013) Pollution characterization of volatile organic compounds in ambient air of Tianjin downtown. Environ Sci 34(12):4513–4518

  61. Zhang J, Yang S, Wu F, Jie S, Wang Y (2014) The characteristics, seasonal variation and source apportionment of VOCs at Gongga Mountain. China Atmos Environ 88(5):297–305

  62. Zheng J, Shao M, Che W, Zhang L, Zhang Y, Streets D (2009) Speciated VOC emission inventory and spatial patterns of ozone formation potential in the Pearl River Delta, China. Environ Sci Technol 43(22):8580–8586

  63. Zhou Y, Hao Z, Wang H (2011) Pollution and source of atmospheric volatile organic compounds in urban-rural juncture belt area in Beijing. Environ Sci 32(12):3560–3565

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Correspondence to Guijian Liu.

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Wang, X., Liu, G., Hu, R. et al. Distribution, Sources, and Health Risk Assessment of Volatile Organic Compounds in Hefei City. Arch Environ Contam Toxicol (2020) doi:10.1007/s00244-019-00704-y

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