Wood Science and Technology

, Volume 53, Issue 1, pp 227–248 | Cite as

Facile and low-cost heteroatom-doped activated biocarbons derived from fir bark for electrochemical capacitors

  • W. ZhaoEmail author
  • L. Luo
  • X. Wu
  • T. Chen
  • Z. Li
  • Z. Zhang
  • J. Rao
  • M. FanEmail author


Chinese fir bark was selected as a precursor, and a chemical activation method was used to prepare high surface area activated biocarbon materials with heteroatom doping. The impacts of the activation temperature on pore structure and chemical characteristics were studied. Activated biocarbon electrodes with heteroatoms of N (1.00–1.60%) and O (3.60–12.87%) were then fabricated for electrochemical performance analysis, and the relationships among the pore structure, chemical characters and specific capacitance were discussed. The results show that the specific capacitance of activated carbon electrodes from both the cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) tests obviously increased with increasing activation temperature in the range of 500 °C to 700 °C. The electrode fabricated with the activated carbon prepared at 700 °C exhibited the highest specific capacitance of 320 F/g at a scan rate of 2 mV/S by CV test and 342 F/g at a current density of 0.5 A/g by GCD test, which is comparable to or higher than that of most carbon-based capacitors. The favorable electrochemical performance may be attributed to the synergistic effect of the hierarchically suitable porous structure and dual doping of nitrogen and oxygen heteroatoms.



The present research was supported by the National Natural Science Foundation of China (31300488) and the Fujian Agriculture and Forestry University Fund for Distinguished Young Scholars (xjq201420).


  1. Babu B, Lashmi PG, Shaijumon MM (2016) Li-ion capacitor based on activated rice husk derived porous carbon with improved electrochemical performance. Electrochim Acta 211:289–296CrossRefGoogle Scholar
  2. Boyjoo Y, Cheng Y, Zhong H, Tian H, Pan J, Pareek VK, Jiang SP, Lamonier JF, Jaroniec M, Liu J (2017) From waste coca cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors. Carbon 116:490–499CrossRefGoogle Scholar
  3. Braghiroli FL, Fierro V, Szczurek A, Stein N, Parmentier J, Celzard A (2015a) Hydrothermally treated aminated tannin as precursor of N-doped carbon gels for supercapacitors. Carbon 90:63–74CrossRefGoogle Scholar
  4. Braghiroli FL, Fierro V, Szczurek A, Stein N, Parmentier J, Celzard A (2015b) Electrochemical performances of hydrothermal tannin-based carbons doped with nitrogen. Ind Crops Prod 70:332–340CrossRefGoogle Scholar
  5. Chang YM, Wu CY, Wu PW (2013) Synthesis of large surface area carbon xerogels for electrochemical double layer capacitors. J Power Sources 223(223):147–154CrossRefGoogle Scholar
  6. Chmiola J, Yushin G, Gogotsi Y, Porter C, Simon P, Taberna PL (2006) Anomalous increase in carbon capacitance at pore sizes less than 1 nanometer. Science 313(5794):1760–1763CrossRefGoogle Scholar
  7. Cordero-Lanzac T, Rosas JM, García-Mateos FJ, Ternero-Hidalgo JJ, Palomo J, Rodríguez-Mirasol J, Cordero T (2018) Role of different nitrogen functionalities on the electrochemical performance of activated carbons. Carbon 126:65–76CrossRefGoogle Scholar
  8. Diez N, Díaz P, Álvarez P, González Z, Granda M, Blanco C, Santamaría R, Menéndez R (2014) Activated carbon fibers prepared directly from stabilized fibers for use as electrodes in supercapacitors. Mater Lett 136(136):214–217CrossRefGoogle Scholar
  9. Dulyaseree P, Fujishige M, Yoshida I, Yumiko T, Banba Y, Tanaka Y, Aoyama T, Phonyiem M, Wongwiriyapan W, Takeuchi K, Endo M (2017) Nitrogen-rich green leaves of papaya and Coccinia grandis as precursors of activated carbon and their electrochemical properties. RSC Adv 7(67):42064–42072CrossRefGoogle Scholar
  10. Enterría M, Pereira MFR, Martins JI, Figueiredo JL (2015) Hydrothermal functionalization of ordered mesoporous carbons: the effect of boron on supercapacitor performance. Carbon 95:72–83CrossRefGoogle Scholar
  11. Fan L, Qiao S, Song W, Wu M, He X, Qu X (2013) Effects of the functional groups on the electrochemical properties of ordered porous carbon for supercapacitors. Electrochim Acta 105:299–304CrossRefGoogle Scholar
  12. Fasakin O, Dangbegnon JK, Momodu DY, Madito MJ, Oyedotun KO, Elerujaa MA, Manyala N (2018) Synthesis and characterization of porous carbon derived from activated banana peels with hierarchical porosity for improved electrochemical performance. Electrochim Acta 262:187–196CrossRefGoogle Scholar
  13. Feng S, Li W, Wang J, Song Y, Elzatahry AA, Xia Y, Zhao D (2014) Hydrothermal synthesis of ordered mesoporous carbons from a biomass-derived precursor for electrochemical capacitors. Nanoscale 6(24):14657CrossRefGoogle Scholar
  14. Frackowiak E, Beguin F (2001) Carbon materials for the electrochemical storage of energy in capacitors. Carbon 39(6):937–950CrossRefGoogle Scholar
  15. Gao S, Li L, Geng K, Wei X, Zhang S (2015) Recycling the biowaste to produce nitrogen and sulfur self-doped porous carbon as an efficient catalyst for oxygen reduction reaction. Nano Energy 16:408–418CrossRefGoogle Scholar
  16. Heo YJ, Park SJ (2015) Synthesis of activated carbon derived from rice husks for improving hydrogen storage capacity. J Ind Eng Chem 31:330–334CrossRefGoogle Scholar
  17. Hu B, Kong LB, Kang L, Yan K, Zhang T, Lia K, Luob YC (2017) Synthesis of a hierarchical nanoporous carbon material with controllable pore size and effective surface area for high-performance electrochemical capacitors. RSC Adv 7(24):14516–14527CrossRefGoogle Scholar
  18. Itoi H, Hayashi S, Matsufusa H, Ohzawa Y (2017) Electrochemical synthesis of polyaniline in the micropores of activated carbon for high-performance electrochemical capacitors. Chem Commun 53(22):3201–3204CrossRefGoogle Scholar
  19. Karnan M, Subramani K, Nagarajan S, Ilayaraja N, Sathish M (2016) Aloe vera derived activated high surface area carbon for flexible and high energy supercapacitors. ACS Appl Mater Interfaces 8(51):35191–35202CrossRefGoogle Scholar
  20. Karnan M, Subramani K, Srividhya PK, Sathish M (2017) Electrochemical studies on corncob derived activated porous carbon for supercapacitors application in aqueous and non-aqueous electrolytes. Electrochim Acta 228:586–596CrossRefGoogle Scholar
  21. Kongsuwan A, Patnukao P, Pavasant P (2009) Binary component sorption of Cu(ii) and Pb(ii) with activated carbon from eucalyptus camaldulensis Dehn bark. J Ind Eng Chem 15(4):465–470CrossRefGoogle Scholar
  22. Lee CW, Yoon SB, Kim HK, Youn HC, Han J, Roh K, Kim KB (2015) A two-dimensional highly ordered mesoporous carbon/graphene nanocomposite for electrochemical double layer capacitors: effects of electrical and ionic conduction pathways. J Mater Chem A 3(5):2314–2322CrossRefGoogle Scholar
  23. Lee HM, Kwac LK, An KH, Park SJ, Kim BJ (2016) Electrochemical behavior of pitch-based activated carbon fibers for electrochemical capacitors. Energy Convers Manag 125:347–352CrossRefGoogle Scholar
  24. Li Y, Li L, Zhu L, Gu L, Cao X (2016a) Interlocked multi-armed carbon for stable oxygen reduction. Chem Commun 52(32):5520–5522CrossRefGoogle Scholar
  25. Li Y, Wang G, Wei T, Fan Z, Yan P (2016b) Nitrogen and sulfur co-doped porous carbon nanosheets derived from willow catkin for supercapacitors. Nano Energy 19:165–175CrossRefGoogle Scholar
  26. Li W, Wumaier T, Chen M, Zhang J, Liu H, Yang LQ, Wang HJ (2016c) Effect of the gradient constant temperature on the electrochemical capacitance of cotton stalk-based activated carbon. J Solid State Electron 20(8):2315–2321CrossRefGoogle Scholar
  27. Li Y, Yan Z, Wang Q, Ye H, Li M, Zhu L, Cao X (2018) Ultrathin, highly branched carbon nanotube cluster with outstanding oxygen electrocatalytic performance. Electrochim Acta 282:224–232CrossRefGoogle Scholar
  28. Liu H, Song H, Chen X, Zhang S, Zhou J, Ma Z (2015) Effects of nitrogen-and oxygen-containing functional groups of activated carbon nanotubes on the electrochemical performance in supercapacitors. J Power Sources 285:303–309CrossRefGoogle Scholar
  29. Liu B, Zhou X, Chen H, Liu Y, Li H (2016) Promising porous carbons derived from lotus seedpods with outstanding supercapacitance performance. Electrochim Acta 208:55–63CrossRefGoogle Scholar
  30. Liu H, Zhang H, Xu H, Lou T, Sui Z, Zhang Y (2018) In situ self-sacrificed template synthesis of vanadium nitride/nitrogen-doped graphene nanocomposites for electrochemical capacitors. Nanoscale 10(11):5246–5253CrossRefGoogle Scholar
  31. Lu Q, Xu YY, Mu SJ, Li WC (2017) The effect of nitrogen and/or boron doping on the electrochemical performance of non-caking coal-derived activated carbons for use as supercapacitor electrodes. New Carbon Mater 32(5):442–450CrossRefGoogle Scholar
  32. Luo L, Chen T, Zhao W, Fan M (2017) Hydrothermal doping of nitrogen in bamboo-based super activated carbon for hydrogen storage. BioResources 12:6237–6250Google Scholar
  33. Luo L, Chen T, Li Z, Zhang Z, Zhao W, Fan M (2018) Heteroatom self-doped activated biocarbons from fir bark and their excellent performance for carbon dioxide adsorption. J CO2 Util 25:89–98CrossRefGoogle Scholar
  34. Marsh H, Rodríguez-Reinoso F (2005) Activated carbon. Elsevier, AmsterdamGoogle Scholar
  35. Milczarek G, Ciszewski A, Stepniak I (2011) Oxygen-doped activated carbon fiber cloth as electrode material for electrochemical capacitor. J Power Sources 196(18):7882–7885CrossRefGoogle Scholar
  36. Momodu D, Madito M, Barzegar F, Bello A, Khaleed A, Olaniyan O, Dangbegnon J, Manyala N (2017) Activated carbon derived from tree bark biomass with promising material properties for supercapacitors. J Solid State Electron 21:859–872CrossRefGoogle Scholar
  37. Ochai-Ejeh FO, Bello A, Dangbegnon J, Khaleed AA, Madito MJ, Bazegar F, Manyala N (2017) High electrochemical performance of hierarchical porous activated carbon derived from lightweight cork (Quercus suber). J Mater Sci 52(17):10600–10613CrossRefGoogle Scholar
  38. Rodríguez-Reinoso F (2002) Production and applications of activated carbons. In: Schüth F, Sing KSW, Weitkamp J (eds) Handbook of porous solids. Wiley-VCH, Weinheim, pp 1766–1827CrossRefGoogle Scholar
  39. Seman RNAR, Azam MA, Mohamad AA (2017) Systematic gap analysis of carbon nanotube-based lithium-ion batteries and electrochemical capacitors. Renew Sustain Energy Rev 75:644–659CrossRefGoogle Scholar
  40. Sevilla M, Mokaya R (2014) Energy storage applications of activated carbons: supercapacitors and hydrogen storage. Energy Environ Sci 7:1250–1280CrossRefGoogle Scholar
  41. Sharma P, Bhatti TS (2010) A review on electrochemical double-layer capacitors. Energy Convers Manag 51(12):2901–2912CrossRefGoogle Scholar
  42. Suliman W, Harsh JB, Abu-Lail NI, Fortuna AM, Dallmeyer I, Garcia-Perez M (2016) Influence of feedstock source and pyrolysis temperature on biochar bulk and surface properties. Biomass Bioenerg 84:37–48CrossRefGoogle Scholar
  43. Sun K, Leng CY, Jiang JC, Quan B, Lin GF, Lu XC, Zhu G (2017) Microporous activated carbons from coconut shells produced by self-activation using the pyrolysis gases produced from them, that have an excellent electric double layer performance. New Carbon Mater 32(5):451–459CrossRefGoogle Scholar
  44. Szczurek A, Jurewicz K, Amaral-Labat G, Fierro V, Pizzi A, Celzard A (2010) Structure and electrochemical capacitance of carbon cryogels derived from phenol-formaldehyde resins. Carbon 48(13):3874–3883CrossRefGoogle Scholar
  45. Veeramani V, Madhu R, Chen SM, Veerakumar P, Syu JJ, Liu SB (2015) Cajeput tree bark derived activated carbon for the practical electrochemical detection of vanillin. New J Chem 39(12):9109–9115CrossRefGoogle Scholar
  46. Wang Q, Li Y, Wang K, Zhou J, Zhu L, Gu L, Hu J, Cao X (2017) Mass production of porous biocarbon self-doped by phosphorus and nitrogen for cost-effective zinc–air batteries. Electrochim Acta 257:250–258CrossRefGoogle Scholar
  47. Wang Z, Tan Y, Yang Y, Zhao XN, Liu Y, Niu LY, Tichnell B, Kong LB, Kang L, Liu Z, Ran F (2018) Pomelo peels-derived porous activated carbon microsheets dual-doped with nitrogen and phosphorus for high performance electrochemical capacitors. J Power Sources 378:499–510CrossRefGoogle Scholar
  48. Wei H, Chen H, Fu N, Chen J, Lan G, Qian W, Liu YP, Lin HL, Han S (2017) Excellent electrochemical properties and large CO2 capture of nitrogen-doped activated porous carbon synthesised from waste longan shells. Electrochim Acta 231:403–411CrossRefGoogle Scholar
  49. Xiao Y, Dong H, Long C, Zheng M, Lei B, Zhang H, Liu Y (2014) Melaleuca bark based porous carbons for hydrogen storage. Int J Hydrog Energy 39(22):11661–11667CrossRefGoogle Scholar
  50. Zhang M, Li Y, Si H, Wang B, Song T (2017) Preparation and electrochemical performance of coconut shell activated carbon produced by the H3PO4 activation with rapid cooling method. Int J Electrochem Sci 12:7844–7852CrossRefGoogle Scholar
  51. Zhao W (2017) Hydrothermal doping of nitrogen in bamboo-based super activated carbon for hydrogen storage. BioResources 12(3):6237–6250Google Scholar
  52. Zhao W, Fierro V, Zlotea C, Aylon E, Izquierdo MT, Latroche M, Celzard A (2011) Optimization of activated carbons for hydrogen storage. Int J Hydrog Energy 36(18):11746–11751CrossRefGoogle Scholar
  53. Zhao W, Fierro V, Zlotea C, Izquierdo MT, Chevalier-César C, Latroche M, Celzard MA (2012) Activated carbons doped with Pd nanoparticles for hydrogen storage. Int J Hydrog Energy 37(6):5072–5080CrossRefGoogle Scholar
  54. Zhao W, Fierro V, Fernández-Huerta N, Izquierdo MT, Celzard A (2013) Hydrogen uptake of high surface area-activated carbons doped with nitrogen. Int J Hydrog Energy 38(25):10453–10460CrossRefGoogle Scholar
  55. Zhao W, Fan M, Gao H, Wang H (2016) Central composite design approach towards optimization of super activated carbons from bamboo for hydrogen storage. RSC Adv 6:46977–46983CrossRefGoogle Scholar
  56. Zhao M, Zhao Q, Li B, Xue H, Pang H, Chen C (2017) Recent progress in layered double hydroxide based materials for electrochemical capacitors: design, synthesis and performance. Nanoscale 9(40):15206–15225CrossRefGoogle Scholar
  57. Zhou X, Li H, Yang J (2016) Biomass-derived activated carbon materials with plentiful heteroatoms for high-performance electrochemical capacitor electrodes. J Energy Chem 25(1):35–40CrossRefGoogle Scholar
  58. Zhu XL, Wang PY, Peng C, Yang J, Yan XB (2014) Activated carbon produced from paulownia sawdust for high-performance CO2 sorbents. Chin Chem Lett 25(6):929–932CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Material EngineeringFujian Agriculture and Forestry UniversityFuzhouPeople’s Republic of China
  2. 2.College of Engineering Design and Physical SciencesBrunel UniversityUxbridgeUK

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