Analytical and Bioanalytical Chemistry

, Volume 402, Issue 6, pp 2221–2225 | Cite as

Nylon membrane as a fluorimetric probe for the herbicide bentazone

Technical Note
First Online:
Received:
Revised:
Accepted:

Abstract

The fluorimetric signal produced by bentazone retained in selected solid surfaces was investigated. Among the different tested supports, only a microporous nylon membrane produced the desired signal. The quantitative study was carried out by second-order calibration using parallel factor analysis, allowing the determination in a highly interfering medium. A detection limit of 0.4 ng mL−1, a prediction relative error of 8%, and a sample frequency of ten samples per hour were obtained in spiked natural waters using green analytical chemistry principles.

Keywords

Optical fluorimetric probe Nylon membrane Second-order calibration Bentazone 
This is a preview of subscription content, log in to check access.

Notes

Acknowledgments

The authors gratefully acknowledge the Universidad Nacional de Rosario, Consejo Nacional de Investigaciones Científicas y Técnicas (Project PIP 1950) and Agencia Nacional de Promoción Científica y Tecnológica (Project 2010-0084) for financially supporting this work.

References

  1. 1.
    Kuster M, de Alda MJ López, Barata C, Raldúa D, Barceló D (2008) Talanta 75:390–401CrossRefGoogle Scholar
  2. 2.
    World Health Organization (2004) Guidelines for drinking-water quality, 3rd edn, vol 1, GenevaGoogle Scholar
  3. 3.
    García Sánchez F, Navas Díaz A, Fernández Correa R (1992) Anal Chim Acta 259:61–66CrossRefGoogle Scholar
  4. 4.
    Mueller TC, Moorman TB, Locke MA (1992) Weed Sci 40:270–274Google Scholar
  5. 5.
    Porini JA, Escandar GM (2011) Anal Method 3:1494–1500CrossRefGoogle Scholar
  6. 6.
    Vilchez JL, Torres Bustos D, Blanc R, Navalón A (1996) J AOAC Int 79:567–570Google Scholar
  7. 7.
    Bro R (1997) Chemom Intell Lab Syst 38:149–171CrossRefGoogle Scholar
  8. 8.
    Ferreira Pinto GM, Jardim ICSF (1999) J Chromatogr A 846:369–374CrossRefGoogle Scholar
  9. 9.
    Piccirilli GN, Escandar GM (2010) Analyst 135:1299–1308CrossRefGoogle Scholar
  10. 10.
    http://www.models.kvl.dk/source/. Accessed 10 December 2011
  11. 11.
  12. 12.
    Booksh KS, Kowalski BR (1994) Anal Chem 66:782A–791ACrossRefGoogle Scholar
  13. 13.
    Bro R, Kiers HAL (2003) J Chemometr 17:274–286CrossRefGoogle Scholar
  14. 14.
    González AG, Herrador MA, Asuero AG (1999) Talanta 48:729–736CrossRefGoogle Scholar
  15. 15.
    Bortolato SA, Arancibia JA, Escandar GM (2008) Anal Chem 80:8276–8286CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 2012

Authors and Affiliations

  • Jessica P. Chiarandini
    • 1
  • Graciela M. Escandar
    • 1
  1. 1.Instituto de Química Rosario (CONICET-UNR), Facultad de Ciencias Bioquímicas y FarmacéuticasUniversidad Nacional de RosarioRosarioArgentina

Personalised recommendations