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Analytical and Bioanalytical Chemistry

, Volume 378, Issue 7, pp 1815–1827 | Cite as

An automated monitoring system for VOC ozone precursors in ambient air: development, implementation and data analysis

  • C. BadolEmail author
  • A. Borbon
  • N. Locoge
  • T. Léonardis
  • J.-C. Galloo
Original Paper

Abstract

An automated system for the monitoring of volatile organic compound (VOC) ozone precursors in ambient air is described. The measuring technique consists of subambient preconcentration on a cooled trap followed by thermal desorption and GC/FID analysis. First, the technical development, which permits detection limits below 0.05 ppbv to be reached, proceeded in two steps: (1) the determination of optimum sampling parameters (trap composition and conditioning, outlet split, desorption temperature); (2) the development of a reliable calibration method based on a highly accurate standard. Then, a 4-year field application of the hourly measuring chain was carried out at two urban sites. On the one hand, quality control procedures provided the best VOC identification (peak assignment) and quantification (reproducibility, blank system control). On the other hand, the success and performances of the routine experience (88% of the measurements covered more than 40 target compounds) indicated the high quality and suitability of the instrumentation which is actually applied in several French air quality monitoring networks. Finally, an example of data analysis is presented. Data handling identified important organic compound sources other than vehicle exhaust.

Keywords

NMHC analysis and sampling Gas chromatography (GC) QC procedure Concentrations Sources 

Notes

Acknowledgements

The authors wish to thank the French Ministry of Environment and the French Agency of Environment (ADEME) for their financial support to the laboratory within the framework of the French Central Laboratory of Air Quality Monitoring (LCSQA). We are also grateful to AREMA-LM (Lille air quality monitoring network) for placing their buildings at our disposal.

References

  1. 1.
    Clench-Aas J, Bartonona A, Bohler T, Gronskei KE, Sivertsen B, Larssen S (1999) J Environ Monit 1:313–319CrossRefPubMedGoogle Scholar
  2. 2.
    Farmer CT, Miine PJ, Riemer DD, Zika RG (1994) Environ Sci Technol 28:238–245Google Scholar
  3. 3.
    Oliver KD, Adams JR, Daughtrey EHJ, McLenny WA, Yoon MJ, Pardee MA (1996) Atmos Environ 30:2751–2757CrossRefGoogle Scholar
  4. 4.
    Durana N, Navazo M, Alonso L, Garcia JA, Ilardia JL, Carmen Gomez M, Gangoiti G (2002) J Air Waste Manage 52:174–185Google Scholar
  5. 5.
    Perez Ballesta P, Field R, De Saeger E (2001) Atmos Environ 35:5729–5740CrossRefGoogle Scholar
  6. 6.
    Apel EC, Calvert JG, Gilpin TM, Fehsenfeld FC, Parrish DD, Lonneman WA (1999) J Geophys Res 104:26,069–26,086CrossRefGoogle Scholar
  7. 7.
    Apel EC, Calvert JG, Fehsenfeld FC (1994) J Geophys Res 99:16,651–16,664Google Scholar
  8. 8.
    Kotzias D, Duane M, Munari F (1995) In: Proceedings of the 3rd international conference on air pollution, Porto Carras, Greece, pp 217–226Google Scholar
  9. 9.
    Veillerot M, Locoge N, Galloo J-C, Guillermo R (1998) Analusis 26:M38–M43Google Scholar
  10. 10.
    Boudries H, Toupance G, Dutot AL (1994) Atmos Environ 28:1095–1112Google Scholar
  11. 11.
    McLenny WA, Colon M (1998) J Chromatogr A 813:101–111CrossRefPubMedGoogle Scholar
  12. 12.
    Dewulf J, Van Lagenhove H (1999) J Chromatogr A 843:163–177CrossRefGoogle Scholar
  13. 13.
    Simon V, Riba ML, Waldhart A, Torres L (1995) J Chromatogr A 704:465–471CrossRefGoogle Scholar
  14. 14.
    Tranchant J, Gardais JF, Gorin P, Prévôt A, Serpinet J, Untz G (1982) In: Manuel pratique de chromatographie en phase gazeuse. Masson, ParisGoogle Scholar
  15. 15.
    Slemr J, Slemr F, Partridge R, D’Souza H, Schmidbauer N (2002) J Geophys Res 107:D19, 4409, doi:10.1029/2001JD001357Google Scholar
  16. 16.
    US Environmental Protection Agency (1998) National Exposure Research Laboratory, Human Exposure and Atmospheric Sciences Division, Research Triangle Park, NCGoogle Scholar
  17. 17.
    Gilbert RO (1987) Statistical methods for environmental pollution monitoring. Van Nostrand Reinhold, New YorkGoogle Scholar
  18. 18.
    Borbon A, Fontaine H, Veillerot M, Locoge N, Galloo J-C, Guillermo R (2001) Atmos Environ 35:3749–3760CrossRefGoogle Scholar
  19. 19.
    Borbon A, Locoge N, Veillerot M, Galloo J-C, Guillermo R (2002) Sci Total Environ 292:177–191CrossRefPubMedGoogle Scholar
  20. 20.
    Derwent RG, Davies TJ, Delaney M, Dollard G J, Field RA, Dumitrean P, Nason PD, Jones BMR, Pepler SA (2000) Atmos Environ 34:297–312CrossRefGoogle Scholar
  21. 21.
    Hassoun S, Pilling MJ, Bartle KD (1999) J Environ Monit 1:453–458CrossRefPubMedGoogle Scholar
  22. 22.
    Locoge N, Veillerot M, Galloo J-C, Guillermo R (1999) In: Sturm PJ (ed) Proceedings of the 8th international symposium on transport and air pollution, Graz, Austria, pp 549–559Google Scholar
  23. 23.
    Fontaine H (2000) PhD thesis, Ecole des Mines de Douai, University of CompiègneGoogle Scholar
  24. 24.
    McInnes G (ed) (1996) Joint EMEP/CORINAIR atmospheric emission inventory guidebook. European Environment Agency, CopenhagenGoogle Scholar
  25. 25.
    Whitby RA, Altwhicker ER (1978) Atmos Environ 12:1289–1296CrossRefGoogle Scholar
  26. 26.
    Guenther A, Hewitt CN, Erikson D, Fall R, Geron C, Graedel T, Harley P, Klinger L, Lerdau M, McKay WA, Pierce T, Scholes B, Steinbrecher R, Tallamraju R, Taylor J, Zimmerman P (1995) J Geophys Res 100:8873–8892Google Scholar
  27. 27.
    UK PORG: Fowler D, Coyle M, Anderson R, Ashmore MR, Bower JS, Burgess RA, Cape JN, Cox RA, Derwent RG (1997) Fourth report of the Photochemical Oxidants Review Group (PORG), LondonGoogle Scholar
  28. 28.
    Borbon A (2002) PhD thesis, Ecole des Mines de Douai, Science and Technology University of LilleGoogle Scholar

Copyright information

© Springer-Verlag 2004

Authors and Affiliations

  • C. Badol
    • 1
    Email author
  • A. Borbon
    • 1
  • N. Locoge
    • 1
  • T. Léonardis
    • 1
  • J.-C. Galloo
    • 1
  1. 1.Département Chimie et EnvironnementEcole des Mines de DouaiDouai CedexFrance

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