Theoretical Chemistry Accounts

, Volume 113, Issue 4, pp 238–247 | Cite as

Reduced–size polarized basis sets for calculations of molecular electric properties. III. Second–row atoms

  • Zuzana Benkova
  • Andrzej J. Sadlej
  • Roma E. Oakes
  • Steven E. J. Bell
Article

Abstract.

Reduced–size polarized (ZmPolX) basis sets are developed for the second–row atoms X = Si, P, S, and Cl. The generation of these basis sets follows from a simple physical model of the polarization effect of the external electric field which leads to highly compact polarization functions to be added to the chosen initial basis set. The performance of the ZmPolX sets has been investigated in calculations of molecular dipole moments and polarizabilities. Only a small deterioration of the quality of the calculated molecular electric properties has been found. Simultaneously the size of the present reduced–size ZmPolX basis sets is about one-third smaller than that of the usual polarized (PolX) sets. This reduction considerably widens the range of applications of the ZmPolX sets in calculations of molecular dipole moments, dipole polarizabilities, and related properties.

Keywords

ZmPolX basis sets Dipole moment and polarizability calculations Second–row atoms 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2005

Authors and Affiliations

  • Zuzana Benkova
    • 1
    • 3
  • Andrzej J. Sadlej
    • 1
  • Roma E. Oakes
    • 2
  • Steven E. J. Bell
    • 2
  1. 1.Department of Quantum Chemistry, Institute of ChemistryNicolaus Copernicus UniversityToruńPoland
  2. 2.School of ChemistryQueen’s UniversityBelfastN. Ireland, UK
  3. 3.Department of Organic Chemistry, Faculty of Natural SciencesComenius UniversityMlynska dolinaBratislavaSlovakia

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