Four commonly applied extraction techniques for organochlorine pesticides, microwave-assisted extraction (MAE), accelerated solvent extraction (ASE), quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction and ultrasonic solvent extraction, were applied on soil samples in order to evaluate their performances. The extracts were analyzed by GC–ECD and confirmed by GC–MS/MS. The MAE and QuEChERS extraction methods generally yielded higher results compared to the ultrasonication and ASE methods, while the lowest recovery (56.8 %) for o,p′-DDD was obtained using the QuEChERS method. The MAE method was further applied to six different soils from Beijing. In the soil samples only α-endosulfan and β-endosulfan were not detected. The ratios of α-HCH/γ-HCH and α-HCH/β-HCH indicated HCH residues likely originated from historical use of HCHs, and that technical HCHs were not likely being currently applied in Beijing.
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Barriada-Pereira M, González-Castro M, Muniategui-Lorenzo S, López-Mahía P, Prada-Rodríguez D, Fernández-Fernández E (2007) Comparison of pressurized liquid extraction and microwave assisted extraction for the determination of organochlorine pesticides in vegetables. Talanta 71(3):1345–1351
Chikuni O, Nhachi C, Nyazema N, Polder A, Nafstad I, Skaare J (1997) Assessment of environmental pollution by PCBs, DDT and its metabolites using human milk of mothers in Zimbabwe. Sci Total Environ 199(1):183–190
Ganzler K, Salgó A, Valkó K (1986) Microwave extraction: a novel sample preparation method for chromatography. J Chromatogr A 371:299–306
Gebbink WA, Sonne C, Dietz R, Kirkegaard M, Born EW, Muir DC et al (2007) Target tissue selectivity and burdens of diverse classes of brominated and chlorinated contaminants in polar bears (Ursus maritimus) from East Greenland. Environ Sci Technol 42(3):752–759
Jia Y, Molstad L, Frostegård Å, Aagaard P, Breedveld GD, Bakken LR (2007) Kinetics of microbial growth and degradation of organic substrates in subsoil as affected by an inhibitor, benzotriazole: model based analyses of experimental results. Soil Biol Biochem 39(7):1597–1608
Loganathan BG, Kannan K (1994) Global organochlorine contamination trends—an overview. Ambio 23(3):187–191
Parera J, Santos F, Galceran M (2004) Microwave-assisted extraction versus Soxhlet extraction for the analysis of short-chain chlorinated alkanes in sediments. J Chromatogr A 1046(1):19–26
Pino V, Ayala JH, Afonso AM, González V (2000) Determination of polycyclic aromatic hydrocarbons in marine sediments by high-performance liquid chromatography after microwave-assisted extraction with micellar media. J Chromatogr A 869(1):515–522
Pozo K, Harner T, Lee SC, Wania F, Muir DC, Jones KC (2008) Seasonally resolved concentrations of persistent organic pollutants in the global atmosphere from the first year of the GAPS study. Environ Sci Technol 43(3):796–803
Srivastava L, Kumar N, Gupta K, Raizada R (2006) Status of HCH residues in Indian medicinal plant materials. Bull Environ Toxicol Chem 76(5):782–790
Tao S, Xu F, Wang X, Liu W, Gong Z, Fang J et al (2005) Organochlorine pesticides in agricultural soil and vegetables from Tianjin, China. Environ Sci Technol 39(8):2494–2499
Tao S, Liu W, Li Y, Yang Y, Zuo Q, Li B et al (2008) Organochlorine pesticides contaminated surface soil as reemission source in the Haihe Plain, China. Environ Sci Technol 42(22):8395–8400
Zhang G, Parker A, House A, Mai B, Li X, Kang Y et al (2002) Sedimentary records of DDT and HCH in the Pearl River Delta, south China. Environ Sci Technol 36(17):3671–3677
Zhang A, Liu W, Yuan H, Zhou S, Su Y, Li YF (2011a) Spatial distribution of hexachlorocyclohexanes in agricultural soils in Zhejiang province, China, and correlations with elevation and temperature. Environ Sci Technol 45(15):6303–6308
Zhang N, Yang Y, Tao S, Liu Y, Shi KL (2011b) Sequestration of organochlorine pesticides in soils of distinct organic carbon content. Environ Pollut 159(3):700–705
Zhang Y, Yang J, Shi R, Su Q, Gao Y, Zhu X (2011c) Development of an analytical method based on accelerated aolvent extraction, solid-phase extraction clean-up, then GC–ECD for analysis of fourteen organochlorine pesticides in cereal crops. Chromatographia 73(3–4):385–391
Zhang A, Chen Z, Ahrens L, Liu W, Li YF (2012a) Concentrations of DDTs and enantiomeric fractions of chiral DDTs in agricultural soils from Zhejiang province, China, and correlations with total organic carbon and pH. J Agric Food Chem 60(34):8294–8301
Zhang W, Lv J, Shi R, Liao C (2012b) A rapid screening method for the determination of seventy pesticide residues in soil using microwave-assisted extraction coupled to gas chromatography and mass spectrometry. Soil Sediment Contam 21(4):407–418
Zhang F, He J, Yao Y, Hou D, Jiang C, Zhang X et al (2013) Spatial and seasonal variations of pesticide contamination in agricultural soils and crops sample from an intensive horticulture area of Hohhot, North-West China. Environ Monit Assess 185(8):6893–6908
Zhao Z, Xia L, Wang F, Jiang X, Gao Y (2012) Optimization of extractants, purifying packings, and eluents for analytical extraction of organochlorine pesticides in Hydragric Acrisols. Environ Monit Assess 184(8):5159–5171
Zhu Y, Liu H, Xi Z, Cheng H, Xu X (2005) Organochlorine pesticides (DDTs and HCHs) in soils from the outskirts of Beijing, China. Chemosphere 60(6):770–778
Zietz BP, Hoopmann M, Funcke M, Huppmann R, Suchenwirth R, Gierden E (2008) Long-term biomonitoring of polychlorinated biphenyls and organochlorine pesticides in human milk from mothers living in northern Germany. Int J Environ Health 211(5):624–638
This work was supported by funding from the National Natural Science Foundation of China (Contract Grant Number: 41201499) and National Science Foundation for Fostering Talents in Basic Research of China (No. J1210064).
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Di, S., Shi, S., Xu, P. et al. Comparison of Different Extraction Methods for Analysis of 10 Organochlorine Pesticides: Application of MAE–SPE Method in Soil from Beijing. Bull Environ Contam Toxicol 95, 67–72 (2015). https://doi.org/10.1007/s00128-015-1538-0
- Organochlorine pesticides
- Extraction methods
- Purification methods
- Methods comparison