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Assessment of Pesticide Residues in Karaboğaz Lake from Kızılırmak Delta, Turkey

  • Zeynep YurtkuranEmail author
  • Yasemin Saygı
Article

Abstract

Monitoring of pesticide residues in water and sediments was conducted for the coastal shallow Karaboğaz Lake, northern Turkey. During a one-year study period, eight pesticides (malathion, etofenprox, molinate, oxamyl, propamocarb hydrochloride, tebufenozide, linuron, piperonyl butoxide) were detected in water and in sediments, all at μg/L and μg/kg concentrations, respectively. Temporal variation in pesticide concentrations was observed. Highest pesticide concentrations in water and sediment were from tebufenozide and etofenprox, respectively. Aquatic risk assessments revealed that out of eight pesticides detected, three showed unaccaptable risk: malathion, oxamyl and etofenprox.

Keywords

Karaboğaz Lake Pesticide Quechers Water Sediment 

Notes

Acknowledgments

This study was funded by the Scientific and Technical Research Council of Turkey and Hacettepe University Scientific Research and Development Office under projects ÇAYDAG: 111Y158, BAP 011.D06.601.001.

References

  1. Allan RJ (1986) The role of particulate matter in the fate of contaminants in aquatic ecosystems. Inland Waters Directorate Science Series 142. Technical Report. National Water Research Institute, Burlington, ON, CanadaGoogle Scholar
  2. Añasco N, Uno S, Koyama J, Matsuoka T, Kuwahara N (2010) Assessment of pesticide residues in freshwater areas affected by rice paddy effluents in southern Japan. Environ Monit Assess 160:371–383CrossRefGoogle Scholar
  3. Brondi SHG, de Macedo AN, Vicente GHL, Nogueira ARA (2011) Evaluation of the QuEChERS method and gas chromatography–mass spectrometry for the analysis pesticide residues in water and sediment. Bull Environ Contam Toxicol 86:18–22CrossRefGoogle Scholar
  4. Comoretto L, Arfib B, Chiron S (2007) Pesticides in the Rhône River delta (France): basic data for a field-based exposure assessment. Sci Total Environ 380:124–132CrossRefGoogle Scholar
  5. Demirkalp FY, Saygı Y, Gündüz E, Çağlar SS, Yiğit S, Kılınç S (2010) Research on Karabogaz Lake in Kızılırmak Delta by limnological and ecological aspects. Scientific and Technological Research Council of Turkey (TUBITAK) Grant No: 108Y058Google Scholar
  6. EPA RED (1995a) Reregistration eligibility decision (RED), propamocarb hydrochloride. Prevention, pesticides and toxic substances. EPA document no: 738-F-95-031Google Scholar
  7. EPA RED (1995b) Reregistration eligibility decision (RED), Linuron. Prevention, pesticides and toxic substances. EPA document no: EPA 738-R-95-003Google Scholar
  8. EPA IRED (2000) Interim reregistration eligibility decision (IRED), oxamyl. Prevention, pesticides and toxic substances. EPA document no: 738-R-00-015Google Scholar
  9. European Commission (1999) Study on the prioritisation of substances dangerous to the aquatic environment. Office for Official Publications, LuxembourgGoogle Scholar
  10. Hela DG, Lambropoulou DA, Konstantinou IK, Albanis TA (2005) Environmental monitoring and ecological risk assessment for pesticide contamination and effects in Lake Pamvotis, northwestern Greece. Environ Toxicol Chem 24(6):1548–1556CrossRefGoogle Scholar
  11. Ji R, Zhu GY, Liu B (2010) Determination of ethofenprox residue in cabbage and soil by UPLC-MS. Chinese J Pest Sci 12:283–288Google Scholar
  12. Konstantinou IK, Zarkadis AK, Albanis TA (2001) Photodegradation of selected herbicides in various natural waters and soils under environmental conditions. J Environ Qual 30:121–130CrossRefGoogle Scholar
  13. Mabury SA, Cox JS, Crosby DG (1996) Environmental fate of rice pesticides in California. Rev Environ Contam Toxicol 147:71–117CrossRefGoogle Scholar
  14. Özesmi U (2003) The ecological economics of harvesting sharp-pointed rush (Juncus acutus) in the Kızılırmak Delta, Turkey. Hum Ecol 31:645–655CrossRefGoogle Scholar
  15. Readman JW, Albanis TA, Barcelo D, Galassi S, Tronczynski J, Gabrielides GP (1993) Herbicide contamination of Mediterranean estuarine waters: results from a Med Pol pilot survey. Marine Poll Bull 26:613–619CrossRefGoogle Scholar
  16. Sun D, Li L, Liang H, Li W, Ji R, Wu Y, Liu C (2012) The dissipation of ethofenprox in cabbage and soil under open conditions. Environ Mon Assess 184(9):5743–5747CrossRefGoogle Scholar
  17. Sundaram KMS (1997) Persistence of tebufenozide in aquatic ecosystems under laboratory and field conditions. Pestic Sci 51:7–20CrossRefGoogle Scholar
  18. Tomlin CDS (2003) The pesticide manual—A world compendium, 13th edn. Hampshire, British Crop Protection Council (BCPC)Google Scholar
  19. Vryzas Z, Vassiliou G, Alexoudis C, Galanis K, Papadopoulou-Mourkidou E (2009) Spatial and temporal distribution of pesticide residues in surface waters in northeastern Greece. Water Res 43:1–10CrossRefGoogle Scholar
  20. Warren N, Allan IJ, Carter JE, House WA, Parker A (2003) Pesticides and other micro-organic contaminants in freshwater sedimentary environments-a review. Appl Geochem 18:159–194CrossRefGoogle Scholar
  21. Weston DP, Amweg EL, Mekebri A, Ogle RS, Lydy MJ (2006) Aquatic effects of aerial spraying for mosquito control over urban area. Environ Sci Technol 40:5817–5822CrossRefGoogle Scholar
  22. Woudneh MB, Oros DB (2006a) Quantitative determination of pyrethroids, pyrethrins, and piperonyl butoxide in surface water by high-resolution gas chromatography/high- resolution mass spectrometry. J Agric Food Chem 54:6957–6962CrossRefGoogle Scholar
  23. Woudneh MB, Oros DB (2006b) Pyrethroids, pyrethrins, and piperonyl butoxide in sediments by high-resolution gas chromatography/high-resolution mass spectrometry. J Chromat A 1135:71–77CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  1. 1.Biology Department, Faculty of ScienceHacettepe UniversityAnkaraTurkey

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