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Two episodes of REE mineralization in the Qinling Orogenic Belt, Central China: in-situ U-Th-Pb dating of bastnäsite and monazite

  • Wei Zhang
  • Wei Terry ChenEmail author
  • Jian-Feng Gao
  • Hua-Kai Chen
  • Jing-Hui Li
Article
  • 143 Downloads

Abstract

Recent exploration revealed a number of rare earth element (REE) deposits that are distributed along the Qinling Orogenic Belt, Central China. These deposits have an estimated total reserve of about 2 Mt. REE2O3, thus making this belt a world-class REE metallogenic province. Understanding the metallogenesis of the belt requires direct dating of REE minerals. In this study, LA-ICP-MS U-Th-Pb dating on bastnäsite and monazite from the Huangshuian, Taipingzhen, and Miaoya deposits in different units of the belt was used to precisely determine the timing of the REE mineralization. The Huangshuian deposit in the north is a carbonatite-related Mo-(REE) deposit in which the REE minerals are closely associated with molybdenite. After correction for common Pb and excessed 206Pb decayed from 230Th, a weighted average 206Pb/238U age of 207 ± 4 Ma (n = 17; MSWD = 1.9) is obtained for bastnäsite grains from this deposit. Such an age is slightly younger than that of the final collision (peak at 230–220 Ma) of the Qinling Orogenic Belt, thus indicating that the Mo-REE mineralization is likely related to a post-collisional extension setting. The Taipingzhen REE deposit in the middle contains sheet-like ore bodies composed of veins where bastnäsite, the dominant REE mineral, is closely associated with quartz, fluorite, and barite. In situ bastnäsite U-Th-Pb dating shows that the REE mineralization in this deposit has formed at 421 ± 7 Ma (n = 17; MSWD = 1.5), synchronous with extension-related magmatism in the region. The Miaoya deposit in the south is the largest one in the belt, and it is essentially a REE-mineralized syenite-carbonatite complex. In this deposit, the monazite grains are closely associated with major minerals of the syenites or carbonatites (e.g., K-feldspar or calcite), but commonly exhibit complex internal textures. Different domains of monazite yield two groups of U-Pb ages at 414 ± 11 Ma (n = 5; MSWD = 0.91) and 231 ± 2 Ma (n = 21; MSWD = 3.1), whereas the bastnäsite has an age of 206 ± 4 Ma (n = 14; MSWD = 1.5). The early age of 414 Ma is obtained from homogenous monazite grains and in good agreement with zircon U-Pb ages of the Miaoya syenite-carbonatite complex, and thus is considered to represent the timing of the major REE mineralization in the deposit. The younger ages of 231–206 Ma are obtained from monazite grains with complex internal textures and bastnäsite in late veinlets, thus recording secondary, consecutive REE remobilization events likely related to the compression process during formation of the Qinling Orogenic Belt. Our new U-Th-Pb ages, in combination with previously geochronological data, demonstrate that there are two episodes of REE mineralization at 440–410 Ma and 220–200 Ma in the Qinling Orogenic Belt.

Keywords

Qinling REE deposit Bastnäsite Monazite U-Th-Pb age 

Notes

Acknowledgments

We thank Prof. Xin-Chun Zhang from the Institute of Geochemistry, Chinese Academy of Sciences and Li-Min Chang, Wei-Dong Zhang, and Wen-Hui Yang from Henan Nuclear Geological Bureau for their valuable assistance during the field investigations. We also thank Liang Li and Rang-Tian Wu from Nanjing FocuMS Technology Co. Ltd. for the help during LA-ICP-MS analyses. We are grateful to the official reviews by Xin-Fu Zhao and Donald Davis, and editorial handling by Bernd Lehmann and Robert Linnen

Funding information

This study is supported by the National Key R&D Program of China (2017YFC0602302) and Key Research Program of Frontier Sciences, CAS (QYZDB-SSW-DQC008).

Supplementary material

126_2019_875_MOESM1_ESM.xls (638 kb)
ESM 1 LA-ICP-MS U-Th-Pb isotopic results of the bastnäsite from the Huangshuian, Taipingzhen and Miaoya deposits
126_2019_875_MOESM2_ESM.xlsx (82 kb)
ESM 1 LA-ICP-MS U-Th-Pb dating results of the monazite in the Miaoya deposit

References

  1. Abdallsamed MIM, Wu YB, Zhang W, Zhou G, Hao W, Yang S (2017) Early Paleozoic high-Mg granodiorite from the Erlangping unit, North Qinling orogen, Central China: partial melting of metasomatic mantle during the initial back-arc opening. Lithos 288:282–294CrossRefGoogle Scholar
  2. Aleinikoff JN, Schenck WS, Plank MO, Srogi L, Fanning CM, Kamo SL, Bosbyshell H (2006) Deciphering igneous and metamorphic events in high-grade rocks of the Wilmington Complex, Delaware: morphology, cathodoluminescence and backscattered electron zoning, and SHRIMP U-Pb geochronology of zircon and monazite. Geol Soc Am Bull 118:39–64CrossRefGoogle Scholar
  3. Cao J, Ye H, Li H, Li Z, Zhang XK, He W, Li C (2014) Geological characteristics and molybdenite Re-Os isotopic dating of Huangshuian carbonatite vein-type Mo(Pb)deposit in Songxian County, Henan Province. Mineral Deposita 33:53–69 (in Chinese with English abstract)Google Scholar
  4. Cao J, Ye HS, Li Z, Zhang XK, Wang P, He W (2015) Geochronology, geochemistry and petrogenesis of the Mogou alkalic pluton in the East Qinling orogenci belt. Acta Petrol Min 34:665–684 (in Chinese with English abstract)Google Scholar
  5. Chen YJ, Santosh M (2014) Triassic tectonics and mineral systems in the Qinling Orogen, Central China. Geol J 49:338–358CrossRefGoogle Scholar
  6. Chen WT, Zhou MF (2015) Mineralogical and geochemical constraints on mobilization and mineralization of rare earth elements in the Lala Fe-Cu-(Mo, REE) deposit, SW China. Am J Sci 315:671–711CrossRefGoogle Scholar
  7. Chen WT, Zhou MF (2017) Hydrothermal alteration of magmatic zircon related to NaCl-rich brines: diffusion-reaction and dissolution-reprecipitation processes. Am J Sci 317:177–215CrossRefGoogle Scholar
  8. Chen H, Tian M, Wu GL, Hu JM (2014) The Early Paleozoic alkaline and mafic magmatic events in Southern Qinling Belt, Central China: evidences for the break-up of the Paleo-Tethyan Ocean. Geol Rev 60:1437–1452 (in Chinese with English abstract)Google Scholar
  9. Cimen O, Kuebler C, Monaco B, Simonetti SS, Corcoran L, Chen W, Simonetti A (2018) Boron, carbon, oxygen and radiogenic isotope investigation of carbonatite from the Miaoya complex, Central China: evidences for late-stage REE hydrothermal event and mantle source heterogeneity. Lithos 322:225–237CrossRefGoogle Scholar
  10. Ding LX, Ma CQ, Li JW, Robinson PT, Deng XD, Zhang C, Xu WC (2011) Timing and genesis of the adakitic and shoshonitic intrusions in the Laoniushan complex, southern margin of the North China Craton: implications for post-collisional magmatism associated with the Qinling Orogen. Lithos 126:212–232CrossRefGoogle Scholar
  11. Dong Y, Santosh M (2016) Tectonic architecture and multiple orogeny of the Qinling Orogenic Belt, Central China. Gondwana Res 29:1–40CrossRefGoogle Scholar
  12. Feng M (1996) Discussion on the genesis of uranium-producing pegmatite in Shangdan area. Uranium Geol 12:30–36 (in Chinese with English abstract)Google Scholar
  13. Gao C, Kang QQ, Jiang HJ, Zheng H, Peng LI, Zhang XM, Lei LI, Dong QQ, Ye XC, Hu XJ (2017) A unique uranium polymetallic deposit discovered in the Qinling orogenic belt: the Huayangchuan super-large U-Nb-Pb-REE deposit associated with pegmatites and carbonatites. Geochimica 46:446–455 (in Chinese with English abstract)Google Scholar
  14. Gong HJ, Zhu LM, Sun BY, Li B, Guo B (2009) Zircon U–Pb ages and Hf isotope characteristics and their geological significance of the Shahewan, Caoping and Zhashui granitic plutons in the South Qinling orogen. Acta Petrol Sin 25:248–264Google Scholar
  15. Grand'Homme A, Janots E, Seydoux-Guillaume AM, Guillaume D, Bosse V, Magnin V (2017) Partial resetting of the U-Th-Pb systems in experimentally altered monazite: nanoscale evidence of incomplete replacement. Geology 44:431–434CrossRefGoogle Scholar
  16. Gregory CJ, Rubatto D, Allen CM, Williams IS, Hermann J, Ireland T (2007) Allanite micro-geochronology: a LA-ICP-MS and SHRIMP U–Th–Pb study. Chem Geol 245:162–182CrossRefGoogle Scholar
  17. Harlov DE, Förster HJ (2003) Fluid-induced nucleation of (Y+REE)-phosphate minerals within apatite: nature and experiment. Part II. Fluorapatite. Am Mineral 87:1209–1229Google Scholar
  18. Harlov DE, Wirth R, Förster HJ (2005) An experimental study of dissolution–reprecipitation in fluorapatite: fluid infiltration and the formation of monazite. Contrib Mineral Petrol 150:268–286CrossRefGoogle Scholar
  19. Harlov DE, Wirth R, Hetherington CJ (2011) Fluid-mediated partial alteration in monazite: the role of coupled dissolution–reprecipitation in element redistribution and mass transfer. Contrib Mineral Petrol 162:329–348CrossRefGoogle Scholar
  20. Huang DH, Wu CY, Du AD, He HL (1995) Re-Os Isotope ages of molybdenum deposits in East Qinling and their significance. Chin J Geochem 14: 313-322.Google Scholar
  21. Huang DH, Hou ZQ, Yang ZM, Li ZQ, Xu DX (2009) Geological and geochemical characteristics, metallogenetic mechanism and tectonic setting of carbonatite vein-type Mo (Pb) deposits in the East Qinling molybdenum ore belt. Acta Geol Sin 83:1968–1984 (in Chinese with English abstract)Google Scholar
  22. Huang XL, Niu Y, Xu YG, Yang QJ, Zhong JW (2010) Geochemistry of TTG and TTG-like gneisses from Lushan-Taihua complex in the southern North China Craton: implications for late Archean crustal accretion. Precambrian Res 182:43–56CrossRefGoogle Scholar
  23. Kosler J, Tubrett MN, Sylvester PJ (2010) Application of laser ablation ICP-MS to U-Th-Pb dating of monazite. Geostand Geoanal Res 25:375–386CrossRefGoogle Scholar
  24. Kröner A, Compston W, Zhang GW, Guo AL, Todt W (1988) Age and tectonic setting of Late Archean greenstone-gneiss terrain in Henan Province, China, as revealed by single-grain zircon dating. Geology 16:211–215CrossRefGoogle Scholar
  25. Kynicky J, Smith MP, Xu C (2012) Diversity of rare earth deposits: the key example of China. Elements 8:361–367CrossRefGoogle Scholar
  26. Li JH (2014) Re-os isotopic dating of molybdenites from the Dashimengou molybdenum deposit in Songxian County, Henan Province, and its geological significance. Geol China 41:1364–1374 (in Chinese with English abstract)Google Scholar
  27. Li N, Pirajno F (2016) Early Mesozoic Mo mineralization in the Qinling Orogen: an overview. Ore Geol Rev 81:431–450CrossRefGoogle Scholar
  28. Li SZ, Kusky TM, Wang L, Zhang G, Lai S, Liu X, Dong S, Zhao G (2007) Collision leading to multiple-stage large-scale extrusion in the Qinling orogen: insights from the Mianlue suture. Gondwana Res 12:121–143CrossRefGoogle Scholar
  29. Li JH, Yin JW, Chen HK, Zhang TL (2008) Discussion on the genesis of cryptoexplosion breccia and Mo-Au metallization in Pangxiegou of Song county. Uranium Geol 24:85–89 (in Chinese with English abstract)Google Scholar
  30. Li CL, Yu XQ, Liu JL, Wang BY, Chen SQ, Dai YP (2012a) Geochronology of the indosinian Dongjikou pyroxene syenite from Xiaoqinling area and its tectonic implications. J Jilin U 42:1806–1816 (in Chinese with English abstract)Google Scholar
  31. Li HM, Wang DH, Wang XX, Zhang CQ, Li LX (2012b) The early Mesozoic syenogranite in Xiong’er mountain area, south margin of North China craton: SHRIMP zircon U-Pb dating, geochemistry and its significance. Acta Petrol Mineral 31:771–782 (in Chinese with English abstract)Google Scholar
  32. Li JH, Chen H, Zhang H, Zhang Y, Zhang T, Wen G, Zhang P (2017) Mineralization characteristics and ore genesis of the light rare earth deposit in Taiping town, western Henan. Geol China 44:288–300 (in Chinese with English abstract)Google Scholar
  33. Li Y, Liang W, Zhang G, Ran Y, Shen Q, Wang J, Jin C (2018) Granitoid emplacement during syn-convergent transtension: an example from the Huamenlou pluton in north Qinling, Central China. Geosci Front 9:191–205CrossRefGoogle Scholar
  34. Ling W, Ren B, Duan R, Liu X, Mao X, Peng L, Liu Z, Cheng J, Yang H (2008) Timing of the Wudangshan, Yaolinghe volcanic sequences and mafic sills in South Qinling: U-Pb zircon geochronology and tectonic implication. Chin Sci Bull 53:2192–2199CrossRefGoogle Scholar
  35. Ling X, Li Q, Liu Y, Yang YH, Liu Y, Tang G, Li XH (2016) In-situ SIMS Th–Pb dating of bastnaesite: constraint on the mineralization time of the Himalayan Mianning-Dechang rare earth element deposits. J Anal Atom Spectrom 31:1680–1687CrossRefGoogle Scholar
  36. Liu Y, Gao S, Hu Z, Gao C, Zong K, Wang D (2010) Continental and oceanic crust recycling-induced melt–peridotite interactions in the trans-North China Orogen: U–Pb dating, Hf isotopes and trace elements in zircons from mantle xenoliths. J Petrol 51:537–571CrossRefGoogle Scholar
  37. Liu L, Liao X, Wang Y, Wang C, Santosh M, Yang M, Zhang C, Chen D (2016) Early Paleozoic tectonic evolution of the North Qinling Orogenic Belt in Central China: insights on continental deep subduction and multiphase exhumation. Earth-Sci Rev 159:58–81CrossRefGoogle Scholar
  38. Lu J, Xu C, Ying Y, Chen W (2014) In-situ chemical, isotopic and geochronological investigation of the Shaxiongdong carbonatite complex. Goldschmidt Conference Abstracts, China, p 1897Google Scholar
  39. Ludwig KR (2003) Isoplot v. 3.0: a geochronological toolkit for Microsoft Excel. Berkeley Geochronology Center, Berkeley, CAGoogle Scholar
  40. Ma C, She Z, Xu P, Wang L (2005) Silurian A-type granitoids in the southern margin of the Tongbai-Dabieshan: evidence from SHRIMP zircon geochronology and geochemistry. Sci China 48:1134–1145CrossRefGoogle Scholar
  41. Mao JW, Pirajno F, Xiang JF, Gao JJ, Ye HS, Li YF, Guo BJ (2011) Mesozoic molybdenum deposits in the east Qinling–Dabie orogenic belt: characteristics and tectonic settings. Ore Geol Rev 43:264–293CrossRefGoogle Scholar
  42. Meng QR, Zhang GW (1999) Timing of collision of the North and South China blocks: controversy and reconciliation. Geology 27:123–126CrossRefGoogle Scholar
  43. Meng QR, Zhang GW (2000) Geologic framework and tectonic evolution of the Qinling orogen, Central China. Tectonophysics 323:183–196CrossRefGoogle Scholar
  44. Paquette JL, Tiepolo M (2007) High resolution (5 μm) U-Th-Pb isotope dating of monazite with excimer laser ablation (ELA)-ICPMS. Chem Geol 240:222–237CrossRefGoogle Scholar
  45. Parrish RR (1990) U–Pb dating of monazite and its application to geological problems. Can J Earth Sci 27:1431–1450CrossRefGoogle Scholar
  46. Poitrasson F, Chenery S, Shepherd TJ (2000) Electron microprobe and LA-ICP-MS study of monazite hydrothermal alteration: implications for U-Th-Pb geochronology and nuclear ceramics. Geochim Cosmochim Acta 64:3283–3297CrossRefGoogle Scholar
  47. Qian DD, Li JQ (1996) The discovering history of Chinese deposits: Hubei volume. Geological Publishing House, Beijing, p 177 (in Chinese)Google Scholar
  48. Qin JF, Lai SC, Li YF (2007) Genesis of the indosinian guangtoushan adakitic biotite plagiogranite in the Mianxian-Lueyang (Mianlue) suture, South Qinling, China, and its tectonic implications. Geol Bull China 26:466–471Google Scholar
  49. Rasmussen B, Muhling JR (2007) Monazite begets monazite: evidence for dissolution of detrital monazite and reprecipitation of syntectonic monazite during low-grade regional metamorphism. Contrib Mineral Petrol 154:675–689CrossRefGoogle Scholar
  50. Ratschbacher L, Hacker BR, Calvert A, Webb LE, Grimmer JC, Mcwilliams MO, Ireland T, Dong S, Hu J (2003) Tectonics of the Qinling (Central China): tectonostratigraphy, geochronology, and deformation history. Tectonophysics 366:1–53CrossRefGoogle Scholar
  51. Sal’nikova EB, Yakovleva SZ, Nikiforov AV, Kotov AB, Yarmolyuk VV, Anisimova IV, Sugorakova AM, Plotkina YV (2010) Bastnaesite: a promising U-Pb geochronological tool. Dokl Earth Sci 430:134–136CrossRefGoogle Scholar
  52. Schärer U (1984) The effect of initial 230Th disequilibrium on young U-Pb ages; the Makalu case, Himalaya. Earth Planet Sci Lett 67:191–204CrossRefGoogle Scholar
  53. Simonetti A, Heaman LM, Chacko T, Banerjee NR (2006) In situ petrographic thin section U-Pb dating of zircon, monazite, and titanite laser ablation-MC-ICP-MS. Int J Mass Spectrom 253:87–97CrossRefGoogle Scholar
  54. Smith M, Kynicky J, Xu C, Song W, Spratt J, Jeffries T, Brtnicky M, Kopriva A, Cangelosi D (2018) The origin of secondary heavy rare earth element enrichment in carbonatites: constraints from the evolution of the Huanglongpu district, China. Lithos 48:787–789Google Scholar
  55. Song W, Xu C, Qi L, Zhou L, Wang L, Kynicky J (2015) Genesis of Si-rich carbonatites in Huanglongpu Mo deposit, lesser Qinling orogen, China and significance for Mo mineralization. Ore Geol Rev 64:756–765CrossRefGoogle Scholar
  56. Song W, Xu C, Smith MP, Kynicky J, Huang K, Wei C, Zhou L, Shu Q (2016) Origin of unusual HREE-Mo-rich carbonatites in the Qinling orogen, China. Sci Rep-UK 6:1–9CrossRefGoogle Scholar
  57. Stacey JS, Kramers JD (1975) Approximation of terrestrial Pb isotope composition by a two-stage model. Earth Planet Sci Lett 26:207–222CrossRefGoogle Scholar
  58. Stein H (1997) Highly precise and accurate Re-Os ages for molybdenite from the East Qinling molybdenum belt, Shaanxi Province, China. Econ Geol 92:827–835CrossRefGoogle Scholar
  59. Tera F, Wasserburg GJ (1972a) U-Th-Pb systematics in lunar highland samples from the Luna 20 and Apollo 16 missions. Earth Planet Sci Lett 17:36–51CrossRefGoogle Scholar
  60. Tera F, Wasserburg GJ (1972b) U-Th-Pb systematics in three Apollo 14 basalts and the problem of initial Pb in lunar rocks. Earth Planet Sci Lett 14:281–304CrossRefGoogle Scholar
  61. Wan J, Gao LB, Wang LX (1992) Metallogenic environmental study and prospect assessment of the granite-pegmatite-type uranium deposit in Shangxian-Danfeng triangle area, Shanxi. Uranium Geol 8:257–263 (in Chinese with English abstract)Google Scholar
  62. Wan Y, Wilde SA, Liu D, Yang C, Song B, Yin X (2006) Further evidence for ∼1.85 Ga metamorphism in the central zone of the North China craton: SHRIMP U–Pb dating of zircon from metamorphic rocks in the Lushan area, Henan Province. Gondwana Res 9:189–197CrossRefGoogle Scholar
  63. Wan J, Liu C, Yang C, Liu W, Li X, Fu X, Liu X (2016) Geochemical characteristics and LA-ICP-MS zircon U-Pb age of the trachytic volcanic rocks in Zhushan area of Southern Qinling Mountains and their significance. Geol Bull China 35:1134–1143 (in Chinese with English abstract)Google Scholar
  64. Wang X, Wang T, Jahn BM, Nenggao HU, Chen W (2007) Tectonic significance of late Triassic post-collisional lamprophyre dikes from the Qinling Mountains, China. Geol Mag 144:837–848CrossRefGoogle Scholar
  65. Wang XX, Wang T, Zhang CL (2015) Granitoid magmatism in the Qinling orogen, Central China and its bearing on orogenic evolution. Sci China Earth Sci 58:1497–1512CrossRefGoogle Scholar
  66. Wang RR, Xu ZQ, Santosh M, Liang FH, Fu XH (2017) Petrogenesis and tectonic implications of the early Paleozoic intermediate and mafic intrusions in the south Qinling Belt, Central China: constraints from geochemistry, zircon U–Pb geochronology and Hf isotopes. Tectonophysics 712-713:270–288CrossRefGoogle Scholar
  67. Wang JC, Kang QQ, Cui HZ, Yuan F, Zhao JF, Sha YZ, Liu JJ, Zhang HY, Wang GW (2018) Ore-controlling factor and exploration direction of granite pegmatite uranium deposit in North Qinling region. Uranium Geol 34:209–215 (in Chinese with English abstract)Google Scholar
  68. Wetherill GW (1956) Discordant uranium-lead ages. Trans Am Geophys Union (AGU) 37:320–326CrossRefGoogle Scholar
  69. Williams ML, Jercinovic MJ, Harlov DE, Budzyń B, Hetherington CJ (2011) Resetting monazite ages during fluid-related alteration. Chem Geol 283:218–225CrossRefGoogle Scholar
  70. Wu YB, Zheng YF (2013) Tectonic evolution of a composite collision orogen: an overview on the Qinling–Tongbai–Hong’an–Dabie–Sulu orogenic belt in Central China. Gondwana Res 23:1402–1428CrossRefGoogle Scholar
  71. Wu CX, Fang X, Yan H (2015) Charactersitcis of niobium, rare earth deposit and prospecting direction of Wudang. Resour Environ Eng 29:270–298 (in Chinese with English abstract)Google Scholar
  72. Xu C, Campbell IH, Allen CM, Chen Y, Huang Z, Qi L, Zhang G, Yan Z (2008) U–Pb zircon age, geochemical and isotopic characteristics of carbonatite and syenite complexes from the Shaxiongdong, China. Lithos 105:118–128CrossRefGoogle Scholar
  73. Xu C, Kynicky J, Chakhmouradian AR, Qi L, Song W (2010) A unique Mo deposit associated with carbonatites in the Qinling orogenic belt, Central China. Lithos 118:50–60CrossRefGoogle Scholar
  74. Xu XY, Xia LQ, Xia ZC, Huang YH (2013) Geochemical characteristics and petrogenesis of the early Paleozoic akali lamprophyre complex from Langao County. Acta Geol Sin 22:55–60 (in Chinese with English abstract)Google Scholar
  75. Xu C, Chakhmouradian AR, Taylor RN, Kynicky J, Li W, Song W, Fletcher IR (2014) Origin of carbonatites in the south Qinling orogen: implications for crustal recycling and timing of collision between the south and North China blocks. Geochim Cosmochim Acta 143:189–206CrossRefGoogle Scholar
  76. Xu C, Kynicky J, Chakhmouradian AR, Li X, Song W (2015) A case example of the importance of multi-analytical approach in deciphering carbonatite petrogenesis in South Qinling orogen:Miaoya rare-metal deposit, central China. Lithos 227:107–121CrossRefGoogle Scholar
  77. Yang YH, Wu FY, Li R, Yang JH, Xie LW, Liu Y, Zhang YB, Huang C (2014) In situ U-Pb dating of bastnaesite by LA-ICPMS. J Anal Atom Spectrom 29:1017–1023CrossRefGoogle Scholar
  78. Ying Y, Chen W, Lu J, Jiang SY, Yang Y, Ying Y, Chen W, Lu J, Jiang SY, Yang Y (2017) In situ U-Th-Pb ages of the Miaoya carbonatite complex in the South Qinling orogenic belt, Central China. Lithos 290:159–171CrossRefGoogle Scholar
  79. Yuan F, Liu J, Guxian L, Sha Y, Zhang S, Zhai D, Wang G, Zhang H, Liu G, Yang S (2017) Zircon U-Pb geochronology, geochemistry and petrogenesis of the granites and pegmatites from the Guangshigou uranium deposit in the northern Qinling Orogen,China. Geosci Front 24:25–45 (in Chinese with English abstract)Google Scholar
  80. Yuan F, Liu J, Carranza EJM, Zhang S, Zhai DG, Liu G, Wang WG, Zhang HY, Sha YZ, Yang SS (2018) Zircon trace element and isotopic (Sr, Nd, Hf, Pb) effects of assimilation-fractional crystallization of pegmatite magma: a case study of the Guangshigou biotite pegmatites from the north Qinling Orogen, Central China. Lithos 302-303:20–36CrossRefGoogle Scholar
  81. Zhang ZQ, Liu DY, Fu GM (1994) Isotopic geochronology of metamorphic strata in north Qinling. Geological Publishing House, Beijing China, p 191 (in Chinese)Google Scholar
  82. Zhang GW, Zhang BR, Yuan XC, Xiao QH (2001a) Qingling Orogenic Belt and continent dynamics. Science Press, Beijing, p 855 (in Chinese)Google Scholar
  83. Zhang L, Wang LS, Zhou L (2001b) Subduction of back-arc basin and recycling of crustal substance in northern Qinling: geochemical evidence of Taoyuan intrusion and Huanggang intrusive complex. Earth Sci-J China Univ Geosci 26:18–24 (in Chinese with English abstract)Google Scholar
  84. Zhang CL, Gao S, Yuan HL, Zhang GW, Yan YX, Luo JL, Luo JH (2007) Sr-Nd-Pb isotopes of the early Paleozoic mafic-ultramafic dykes and basalts from south Qinling belt and their implications for mantle composition. Sci China Earth Sci 50:1293–1301CrossRefGoogle Scholar
  85. Zhang CL, Liu L, Wang T, Wang XX, Li L, Gong QF, Li XF (2013) Granitic magmatism related to early Paleozoic continental collision in north Qinling. Chin Sci Bull 58:4405–4410CrossRefGoogle Scholar
  86. Zhao T, Zhai M, Xia B, Huimin LI, Zhang Y, Wan Y (2004) Zircon U-Pb SHRIMP dating for the volcanic rocks of the Xiong'er group: constraints on the initial formation age of the cover of the North China craton. Chin Sci Bull 49:2495–2502CrossRefGoogle Scholar
  87. Zhao G, He Y, Sun M (2009) The Xiong'er volcanic belt at the southern margin of the North China craton: petrographic and geochemical evidence for its outboard position in the Paleo-Mesoproterozoic Columbia supercontinent. Gondwana Res 16:170–181CrossRefGoogle Scholar
  88. Zhu X, Chen F, Nie H, Siebel W, Yang Y, Xue Y, Zhai M (2014) Neoproterozoic tectonic evolution of South Qinling, China: evidence from zircon ages and geochemistry of the Yaolinghe volcanic rocks. Precambrian Res 245:115–130CrossRefGoogle Scholar
  89. Zhu HQ, Li WH, Hui ZP, Zhao RY, Wang JB, Gong QF (2015) Mineralization characteristics and metallogenesis of granitic pegmatite uranium and ther Rare Metals in the Danfeng triangle area,Shaanxi. Northwest Geol 48:172–178 (in Chinese with English abstract)Google Scholar
  90. Zhu J, Wang L, Peng S, Peng L, Wu C, Qiu X (2016) U-Pb zircon age, geochemical and isotopic characteristics of the Miaoya syenite and carbonatite complex, Central China. Geol J 52:938–954CrossRefGoogle Scholar
  91. Zhu J, Cheng CH, Wang LX, Peng SG, Peng LH, Ke X (2017) Some new knowledge concerning Silurian alkaline magmatism and related Nb-REE mineralization in the Zhushan region, South Qinling. Acta Petrol Min 29:681–690 (in Chinese with English abstract)Google Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Wei Zhang
    • 1
  • Wei Terry Chen
    • 1
    • 2
    Email author
  • Jian-Feng Gao
    • 1
  • Hua-Kai Chen
    • 3
  • Jing-Hui Li
    • 3
  1. 1.State Key Laboratory of Ore Deposit GeochemistryInstitute of Geochemistry Chinese Academy of SciencesGuiyangChina
  2. 2.University of Chinese Academy of SciencesBeijingChina
  3. 3.Henan Nuclear Geological BureauZhengzhouChina

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