Mineralogical, textural, sulfur and lead isotope constraints on the origin of Ag-Pb-Zn mineralization at Bianjiadayuan, Inner Mongolia, NE China

  • Degao Zhai
  • Jiajun Liu
  • Nigel J. Cook
  • Xilong Wang
  • Yongqiang Yang
  • Anli Zhang
  • Yingchun Jiao
Article
  • 115 Downloads

Abstract

The Bianjiadayuan Ag-Pb-Zn deposit (4.81 Mt. @157.4 g/t Ag and 3.94% Pb + Zn) is located in the Great Hinggan Range Pb-Zn-Ag-Cu-Mo-Sn-Fe polymetallic metallogenic belt, NE China. Vein type Pb-Zn-Ag ore bodies are primarily hosted by slate, adjacent to a Sn ± Cu ± Mo mineralized porphyry intrusion. The deposit is characterized by silver-rich ores with Ag grades up to 3000 g/t. Four primary paragenetic sequences are recognized: (I) arsenopyrite + pyrite + quartz, (II) main sulfide + quartz, (III) silver-bearing sulfosalt + quartz, and (IV) boulangerite + calcite. A subsequent supergene oxidation stage has also been identified. Hydrothermal alteration consists of an early episode of silicification, two intermediate episodes (propylitic and phyllic), and a late argillic episode. Silver mineralization primarily belongs to the late paragenetic sequence III. Freibergite is the dominant and most important Ag-mineral in the deposit. Detailed ore mineralogy of Bianjiadayuan freibergite reveals evidence of chemical heterogeneity down to the microscale. Silver-rich sulfosalts in the late paragenetic sequence III are largely derived from a series of retrograde and solid-state reactions that redistribute Ag via decomposition and exsolution during cooling, illustrating that documentation of post-mineralization processes is essential for understanding silver ore formation. Sulfur and lead isotope compositions of sulfides, and comparison with those of local various geological units, indicate that the ore-forming fluids, lead, and other metals have a magmatic origin, suggesting a close genetic association between the studied Ag-Pb-Zn veins and the local granitic intrusion. Fluid cooling coupled with decreases in fO2 and fS2 are the factors inferred to have led to a decrease of silver solubility in the hydrothermal fluid, and successively promoted extensive Ag deposition.

Keywords

Freibergite Sulfur isotopes Lead isotopes Ag-Pb-Zn deposit Bianjiadayuan NE China 

Notes

Acknowledgements

We thank Ed Ripley and Ben Underwood (Indiana University, Bloomington) for the sulfur isotope analyses, Chusi Li (Indiana University, Bloomington) and Zhenyu Chen (CAGS) for the EPMA analyses, and Dongjie Tang (CUGB) for the FESEM analyses. This research was supported financially by the National Natural Science Foundation of China (Grants 41672068, 41272110), the Fundamental Research Funds for the Central Universities (Grant 2652015045), the Open Research Funds for GPMR (Grant GPMR201513), and the Chinese “111” project (Grant B07011). Dr. Anthony E. Williams-Jones is thanked for final reading this paper. We thank Paul Spry and Antoine De Haller for their critical reviews, which considerably improved this paper. Associate Editor Robert Moritz and Editor-in-Chief Georges Beaudoin are thanked for their editorial help and useful suggestions.

Supplementary material

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References

  1. Akinfiev NN, Zotov AV (2001) Thermodynamic description of chloride, hydrosulfide, and hydroxo complexes of Ag(I), Cu(I), and Au(I) at temperatures of 25–500 °C and pressures of 1–2000 bar. Geochem Int 39:990–1006Google Scholar
  2. Akinfiev NN, Zotov AV (2010) Thermodynamic description of aqueous species in the system Cu–Ag–Au–S–O–H at temperatures of 0–600 °C and pressures of 1–3000 bar. Geochem Int 48:714–720CrossRefGoogle Scholar
  3. Balabin AI, Sack RO (2000) Thermodynamics of (Zn, Fe)S sphalerite: a CVM approach with large basis clusters. Mineral Mag 64:923–943CrossRefGoogle Scholar
  4. Barroso M, Figueiras J, Alves Lc, Mateus A (2003) Chemical nature of Ag-bearing tetrahedrites from the Enfermarias prospect (Moura, Portugal) revealed by EPMA and Micro-PIXE analysis. Abstract, http://webpages.fc.ul.pt, 50–52
  5. Barton PB Jr, Skinner BJ (1979) Sulfide mineral stabilities. In: Barnes HL (ed) Geochemistry of hydrothermal ore deposits, 2nd edn. Holt & Wiley, New York, pp 278–403Google Scholar
  6. Baumgartner R, Fontboté L, Spikings R, Ovtcharova M, Schaltegger U, Schneider J, Page L, Gutjahr M (2009) Bracketing the age of magmatic-hydrothermal activity at the Cerro de Pasco epithermal polymetallic deposit, central Peru: a U-Pb and 40Ar/39Ar study. Econ Geol 104(4):479–504CrossRefGoogle Scholar
  7. Beaudoin G, Sangster DF (1992) A descriptive model for silver-lead-zinc veins in clastic metasedimentary terranes. Econ Geol 87:1005–1021CrossRefGoogle Scholar
  8. Bendezú R, Fontboté L (2009) Cordilleran epithermal Cu-Zn-Pb-(Au-Ag) mineralization in the Colquijirca district, central Peru: deposit-scale mineralogical patterns. Econ Geol 104(7):905–944CrossRefGoogle Scholar
  9. Catchpole H, Kouzmanov K, Bendezú A, Ovtcharova M, Spikings R, Stein H, Fontboté L (2015) Timing of porphyry (Cu-Mo) and base metal (Zn-Pb-Ag-Cu) mineralisation in a magmatic-hydrothermal system—Morococha district, Peru. Mineral Deposita 50(8):895–922CrossRefGoogle Scholar
  10. Chen B, Jahn B (2001) Geochemical and isotopic studies of the sedimentary and granitic rocks of the Altai Orogen of NW China and their tectonic implications. Geol Mag 139:1–13Google Scholar
  11. Chen YJ, Chen HY, Zaw K, Pirajno F, Zhang ZJ (2007) Geodynamic settings and tectonic model of skarn gold deposits in China: an overview. Ore Geol Rev 31:139–169CrossRefGoogle Scholar
  12. Chutas NI, Kress VC, Ghiorso MS, Sack RO (2008) A solution model for high-temperature PbS-AgSbS2-AgBiS2 galena. Am Mineral 93(10):1630–1640CrossRefGoogle Scholar
  13. Einaudi MT (1981) Skarns associated with porphyry plutons: description of deposits, southwestern North America. II. General features and origin. Advances in Geology of the Porphyry Copper Deposits of Southwestern North America. University of Arizona Press, Tucson, pp 139–183Google Scholar
  14. Einaudi MT, Hedenquist JW, Inan EE (2003) Sulfidation state of fluids in active and extinct hydrothermal systems: transitions from porphyry to epithermal environments. Special Publication-Society of Economic Geologists 10:285–314Google Scholar
  15. Fontboté L, Bendezú R (2009) Cordilleran or butte-type veins and replacement bodies as a deposit class in porphyry systems. In: Williams et al., P.J. (ed) proceedings of the 10th biennial Society of Geology Applied to ore deposits meeting, Townsville, Australia, pp 521–523Google Scholar
  16. Gallego Hernández AN, Akasaka M (2010) Ag-rich tetrahedrite in the El Zancudo deposit, Colombia: occurrence, chemical compositions and genetic temperatures. Resour Geol 60(3):218–233CrossRefGoogle Scholar
  17. Gammons CH, Barnes HL (1989) The solubility of Ag2S in near-neutral aqueous sulfide solutions at 25 to 300 °C. Geochim Cosmochim Acta 53(2):279–290CrossRefGoogle Scholar
  18. Gammons CH, Williams-Jones AE (1995) Hydrothermal geochemistry of electrum; thermodynamic constraints. Econ Geol 90(2):420–432CrossRefGoogle Scholar
  19. George L, Cook NJ, Cristiana L, Wade BP (2015) Trace and minor elements in galena: a reconnaissance LA-ICP-MS study. Am Mineral 100(2–3):548–569CrossRefGoogle Scholar
  20. Guilbert JM, Park CF (1986) The geology of ore deposits. W. H. Freeman and Company, New York, pp 1–985Google Scholar
  21. Guo F, Fan W, Gao X, Li C, Miao L, Zhao L, Li H (2010) Sr–Nd–Pb isotope mapping of Mesozoic igneous rocks in NE China: constraints on tectonic framework and Phanerozoic crustal growth. Lithos 120:563–578CrossRefGoogle Scholar
  22. HBGMR (Heilongjiang Bureau of Geology and Mineral Resources) (1993) Regional geology of Heilongjiang Province, vol 347–418. Geological Publishing House, Beijing (in Chinese with English abstract)Google Scholar
  23. Hurtig NC, Williams-Jones AE (2014a) An experimental study of the transport of gold through hydration of AuCl in aqueous vapour and vapour-like fluids. Geochim Cosmochim Acta 127:305–325CrossRefGoogle Scholar
  24. Hurtig NC, Williams-Jones AE (2014b) An experimental study of the solubility of MoO3 in aqueous vapour and low to intermediate density supercritical fluids. Geochim Cosmochim Acta 136:169–193CrossRefGoogle Scholar
  25. Jahn BM (2004) The central Asian Orogenic Belt and growth of the continental crust in the Phanerozoic. In: Malpas, J., Fletcher, C.J.N., Ali, J.R., Aitchison, J.C. (Eds.), Aspects of the tectonic evolution of China: geological society, London, Special Publications 226:73–100Google Scholar
  26. Jahn BM, Wu F, Chen B (2000) Granitoids of the central Asian Orogenic Belt and continental growth in the Phanerozoic. Geol Soc Am Spec Pap 350:181–193Google Scholar
  27. Johnson JW, Oelkers EH, Helgeson HC (1992) SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species and reactions from 1 to 5000 bars and 0° to 1000°C. Comput Geosci 18:899–947CrossRefGoogle Scholar
  28. Kissin SA, Mango H (2014) Silver vein deposits. Treatise on geochemistry, 2nd edn. Elsevier, Oxford, pp 425–432CrossRefGoogle Scholar
  29. Li WB, Zhong RC, Xu C, Song B, Qu WJ (2012) U–Pb and re–Os geochronology of the Bainaimiao cu–Mo–au deposit, on the northern margin of the North China Craton, Central Asia Orogenic Belt: implications for ore genesis and geodynamic setting. Ore Geol Rev 48:139–150CrossRefGoogle Scholar
  30. Liu C, Bagas L, Wang F (2016a) Isotopic analysis of the super-large Shuangjianzishan Pb–Zn–Ag deposit in Inner Mongolia, China: constraints on magmatism, metallogenesis, and tectonic setting. Ore Geol Rev 75:252–267CrossRefGoogle Scholar
  31. Liu Y, Jiang S, Bagas L (2016b) The genesis of metal zonation in the Weilasituo and Bairendaba Ag–Zn–Pb–Cu–(Sn–W) deposits in the shallow part of a porphyry Sn–W–Rb system, Inner Mongolia, China. Ore Geol Rev 75:150–173CrossRefGoogle Scholar
  32. Lueth VW, Megaw PKM, Pingitore NE, Goodell PC (2000) Systematic variation in galena solid solution compositions at Santa Eulalia, Chihuahua, Mexico. Econ Geol 95:1673–1687Google Scholar
  33. Mao JW, Xie GQ, Zhang ZH, Li XF, Wang YT, Zhang CQ, Li YF (2005) Mesozoic large-scale metallogenic pluses in North China and corresponding geodynamic settings. Acta Petrol Sin 21:169–188 (in Chinese with English abstract)Google Scholar
  34. Migdisov AA, Williams-Jones AE (2013) A predictive model for metal transport of silver chloride by aqueous vapor in ore-forming magmatic-hydrothermal systems. Geochim Cosmochim Acta 104:123–135CrossRefGoogle Scholar
  35. Migdisov AA, Bychkov AY, Williams-Jones AE, Van Hinsberg VJ (2014) A predictive model for the transport of copper by HCl-bearing water vapour in ore-forming magmatic-hydrothermal systems: implications for copper porphyry ore formation. Geochim Cosmochim Acta 129:33–53CrossRefGoogle Scholar
  36. Muntean JL, Einaudi MT (2000) Porphyry gold deposits of the Refugio district, Maricunga belt, northern Chile. Econ Geol 95(7):1445–1472CrossRefGoogle Scholar
  37. Myers J, Eugster HP (1983) The system Fe-Si-O: oxygen buffer calibrations to 1,500 K. Contrib Mineral Petrol 82:76–90CrossRefGoogle Scholar
  38. Ouyang H, Mao J, Santosh M, Wu Y, Hou L, Wang X (2014) The early cretaceous Weilasituo Zn–Cu–Ag vein deposit in the southern great Xing'an range, northeast China: fluid inclusions, H, O, S, Pb isotope geochemistry and genetic implications. Ore Geol Rev 56:503–515CrossRefGoogle Scholar
  39. Ripley EM, Li C, Moore CH, Schmitt AK (2010) Micro-scale S isotope studies of the Kharaelakh intrusion, Noril’sk region, Siberia: constraints on the genesis of coexisting anhydrite and sulfide minerals. Geochim Cosmochim Acta 74(2):634–644CrossRefGoogle Scholar
  40. Ruan B, Lv X, Liu S, Yang W (2013) Genesis of Bianjiadayuan Pb-Zn-Ag deposit in Inner Mongolia: constraints from U-Pb dating of zircon and multi-isotope geochemistry. Mineral Deposits 32(3):501–514 (in Chinese with English abstract)Google Scholar
  41. Ruan B, Lv X, Yang W, Liu S, Yu Y, Wu C, Adam MMA (2015) Geology, geochemistry and fluid inclusions of the Bianjiadayuan Pb–Zn–Ag deposit, Inner Mongolia, NE China: implications for tectonic setting and metallogeny. Ore Geol Rev 71:121–137CrossRefGoogle Scholar
  42. Sack RO (2005) Internally consistent database for sulfides and sulfosalts in the system Ag2S-Cu2S-ZnS-FeS-Sb2S3-As2S3: update. Geochim Cosmochim Acta 69(5):1157–1164CrossRefGoogle Scholar
  43. Sack RO, Kuehner SM, Hardy LS (2002) Retrograde Ag-enrichment in fahlores from the Coeur d'Alene mining district, Idaho, USA. Miner Mag 66(1):215–229CrossRefGoogle Scholar
  44. Sack RO, Lynch JVG, Foit F (2003) Fahlore as a petrogenetic indicator: Keno Hill Ag-Pb-Zn District, Yukon, Canada. Miner Mag 67(5):1023–1038CrossRefGoogle Scholar
  45. Seal RR (2006) Sulfur isotope geochemistry of sulfide minerals. Rev Mineral and Geochem 61(1):633–677CrossRefGoogle Scholar
  46. Seward TM (1976) The stability of chloride complexes of silver in hydrothermal solutions up to 350 °C. Geochim Cosmochim Acta 40(11):1329–1341CrossRefGoogle Scholar
  47. Shao HM, Zhang LQ (2001) Major metallogenic districts and series in Inner Mongolia. Report, Inner Mongolia Geological Prospecting Bureau, pp 1–236 (in Chinese)Google Scholar
  48. Shen P, Hattori K, Pan H, Jackson S, Seitmuratova E (2015) Oxidation condition and metal fertility of granitic magmas: zircon trace-element data from porphyry Cu deposits in the central Asian Orogenic Belt. Econ Geol 110(7):1861–1878CrossRefGoogle Scholar
  49. Shi YR, Liu DY, Miao LC, Zhang FQ, Zhang W, Hou KJ, Xu JY (2010) Devonian A–type granitic magmatism on the northern margin of the North China Craton: SHRIMP U–Pb zircon dating and Hf-isotopes of the Hongshan granite at Chifeng, Inner Mongolia, China. Gondwana Res 17:632–641CrossRefGoogle Scholar
  50. Shu Q, Lai Y, Sun Y, Wang C, Meng S (2013) Ore genesis and hydrothermal evolution of the Baiyinnuo’er zinc-lead skarn deposit, northeast China: evidence from isotopes (S, Pb) and fluid inclusions. Econ Geol 108(4):835–860CrossRefGoogle Scholar
  51. Shu Q, Chang Z, Lai Y, Zhou Y, Sun Y, Yan C (2016) Regional metallogeny of Mo-bearing deposits in northeastern China, with new Re-Os dates of porphyry Mo deposits in the northern Xilamulun district. Econ Geol 111(7):1783–1798CrossRefGoogle Scholar
  52. Sillitoe RH (2010) Porphyry copper systems. Econ Geol 105:3–41CrossRefGoogle Scholar
  53. Sillitoe RH, Mortensen JK (2010) Longevity of porphyry copper formation at Quellaveco, Peru. Econ Geol 105(6):1157–1162CrossRefGoogle Scholar
  54. Stefansson A, Seward TM (2003) Experimental determination of the stability and stoichiometry of sulphide complexes of silver(I) in hydrothermal solutions to 400 °C at 500 bar. Geochim Cosmochim Acta 67:1395–1413CrossRefGoogle Scholar
  55. Valencia VA, Eastoe C, Ruiz J, Ochoa-Landin L, Gehrels G, González-Leon C, Barra F, Espinoza E (2008) Hydrothermal evolution of the porphyry copper deposit at La Caridad, Sonora, Mexico, and the relationship with a neighboring high-sulfidation epithermal deposit. Econ Geol 103(3):473–491CrossRefGoogle Scholar
  56. Wang X (2014) The study of the Metallogenic characteristics and genesis of the Bianjiadayuan Pb-Zn-Ag deposit in Inner Mongolia, China. China University of Geosciences Beijing, Master dissertation, pp 1–85 (in Chinese with English abstract)Google Scholar
  57. Wang F, Zhou XH, Zhang LC, Ying JF, Zhang YT, Wu FY (2006) Late Mesozoic volcanism in the great Xing'an range (NE China): timing and implications for the dynamic setting of NE Asia. Earth Planet Sci Lett 251:179–198CrossRefGoogle Scholar
  58. Wang X, Liu J, Zhai D, Yang Y, Wang J, Zhang Q, Zhang A, Wang X (2013) LA-ICP-MS zircon U-Pb dating, geochemistry of the intrusive rocks from the Bianjiadayuan Pb-Zn-Ag deposit, Inner Mongolia, China and tectonic implications. Geotecton Metallog 37(4):730–742 (in Chinese with English abstract)Google Scholar
  59. Wang X, Liu J, Zhai D, Yang Y, Wang J, Zhang Q, Zhang A, Li Y, Wang X, Yang Z (2014a) Mineral composition of Bianjiadayuan Pb-Zn-Ag polymetallic deposit in Inner Mongolia and its origin significance. Geoscience 28(1):73–86 (in Chinese with English abstract)Google Scholar
  60. Wang X, Liu J, Zhai D, Yang Y, Wang J, Zhang Q, Zhang A (2014b) U-Pb dating, geochemistry and tectonic implications of Bianjiadayuan quartz porphyry, Inner Mongolia, China. Bull Mineral, Petrol and Geochem 33(5):654–665 (in Chinese with English abstract)Google Scholar
  61. Wang X, Liu J, Zhai D, Wang J, Zhang Q, Zhang A (2014c) A study of isotope geochemistry and sources of ore-forming materials of the Bianjiadayuan silver polymetallic deposit in Linxi, Inner Mongolia. Geol in China 41(4):1288–1303 (in Chinese with English abstract)Google Scholar
  62. Wang Y, Cai T, Bao N, Li W, Nie T, Da Y, Sun Y (2014d) Geological characteristic and control factors in Bianjiadayuan Pb-Zn-Ag deposit, Inner Mongolia. J East China Institute of Tec (Natural Sci) 37(2):212–219 (in Chinese with English abstract)Google Scholar
  63. Wang C, Sun F, Sun G, Sun J, Li Y, Feng H (2016) Geochronology, geochemical and isotopic constraints on petrogenesis of intrusive complex associated with Bianjiadayuan polymetallic deposit on the southern margin of the Greater Khingan, China. Arab J Geosci 9(5):1–16Google Scholar
  64. Wei CS, Zhao ZF, Spicuzza MJ (2008) Zircon oxygen isotopic constraint on the sources of late Mesozoic A-type granites in eastern China. Chem Geol 250:1–15CrossRefGoogle Scholar
  65. Williams-Jones AE, Heinrich CA (2005) 100th anniversary special paper: vapor transport of metals and the formation of magmatic-hydrothermal ore deposits. Econ Geol 100(7):1287–1312CrossRefGoogle Scholar
  66. Williams-Jones AE, Migdisov AA (2014) Experimental constraints on the transport and deposition of metals in ore-forming hydrothermal systems. Society of Economic Geologists 18:77–96Google Scholar
  67. Wu FY, Jahn BM, Wilde SA, Lo CH, Yui TF, Lin Q, Ge WC, Sun DY (2003) Highly fractionated I-type granites in NE China (I): geochronology and petrogenesis. Lithos 66:241–273CrossRefGoogle Scholar
  68. Wu FY, Wilde SA, Sun DY, Zhang G (2004) Geochronology and petrogenesis of post-orogenic Cu, Ni-bearing mafic–ultramafic intrusions in Jilin, NE China. J Asian Earth Sci 23:781–797CrossRefGoogle Scholar
  69. Wu FY, Lin JQ, Wilde SA, Zhang XO, Yang JH (2005) Nature and significance of the early cretaceous giant igneous event in eastern China. Earth Planet Sci Lett 233:103–119CrossRefGoogle Scholar
  70. Wu H, Zhang L, Wan B, Chen Z, Xiang P, Pirajno F, Du A, Qu W (2011a) Re-Os and 40Ar/39Ar ages of the Jiguanshan porphyry Mo deposit, Xilamulun metallogenic belt, NE China, and constraints on mineralization events. Mineral Deposita 46:171–185CrossRefGoogle Scholar
  71. Wu H, Zhang L, Wan B, Chen Z, Zhang X, Xiang P (2011b) Geochronological geochemical constraints on Aolunhua porphyry Mo-Cu deposit, northeast China, its tectonic significance. Ore Geol Rev 43:78–91CrossRefGoogle Scholar
  72. Wu FY, Sun DY, Ge WC, Zhang YB, Grant ML, Wilde SA, Jahn BM (2011c) Geochronology of the Phanerozoic granitoids in northeastern China. J Asian Earth Sci 41:1–30CrossRefGoogle Scholar
  73. Xiao WJ, Zhang LC, Qin KZ, Sun S, Li JL (2004) Paleozoic accretionary and collisional tectonics of the eastern Tianshan China: implication for the continental growth of central Asia. Am J Sci 304:370–395CrossRefGoogle Scholar
  74. Xiao WJ, Kröner A, Windley BF (2009) Geodynamic evolution of Central Asia in the Paleozoic and Mesozoic. Int J Earth Sci 98:1185–1188CrossRefGoogle Scholar
  75. Yao MJ, Liu JJ, Zhai DG, Wang JP (2010) Sulfur and lead isotopic compositions of the polymetallic deposits in the southern great Xing'an range: some implications for metal sources. J Jilin Univ (Earth Sci Ed) 42:362–373 (in Chinese with English abstract)Google Scholar
  76. Zartman RE, Doe BR (1981) Plumbotectonics—the model. Tectonophysics 75:135–162CrossRefGoogle Scholar
  77. Zeng Q, Liu J, Zhang Z, Jia C, Yu C, Ye J, Liu H (2009) Geology and lead-isotope study of the Baiyinnuoer Zn-Pb-Ag deposit, south segment of the Da Hinggan Mountains, northeastern China. Resour Geol 59(2):170–180CrossRefGoogle Scholar
  78. Zeng QD, Liu JM, Zhang ZL, Chen WJ, Zhang WQ (2011) Geology geochronology of the Xilamulun molybdenum metallogenic belt in eastern Inner Mongolia, China. Int J Earth Sci 100:1791–1809CrossRefGoogle Scholar
  79. Zhai D, Liu J (2014) Gold-telluride-sulfide association in the Sandaowanzi epithermal Au-Ag-Te deposit, NE China: implications for phase equilibrium and physicochemical conditions. Miner Petrol 108:853–871CrossRefGoogle Scholar
  80. Zhai DG, Liu JJ, Wang JP, Yao MJ, Wu SH, Fu C, Liu ZJ, Wang SG, Li YX (2013) Fluid evolution of the Jiawula Ag-Pb-Zn deposit, Inner Mongolia: mineralogical, fluid inclusion, and stable isotopic evidence. Int Geol Rev 55:204–224CrossRefGoogle Scholar
  81. Zhai D, Liu J, Wang J, Yang Y, Zhang H, Wang X, Zhang Q, Wang G, Liu Z (2014a) Zircon U-Pb and molybdenite Re-Os geochronology, and whole-rock geochemistry of the Hashitu molybdenum deposit and host granitoids, Inner Mongolia, NE China. J Asian Earth Sci 79:144–160CrossRefGoogle Scholar
  82. Zhai D, Liu J, Zhang H, Yao M, Wang J, Yang Y (2014b) S-Pb isotopic geochemistry, U-Pb and Re-Os geochronology of the Huanggangliang Fe-Sn deposit, Inner Mongolia, NE China. Ore Geol Rev 59:109–122CrossRefGoogle Scholar
  83. Zhai D, Liu J, Zhang H, Wang J, Su L, Yang X, Wu S (2014c) Origin of oscillatory zoned garnets from the Xieertala Fe-Zn skarn deposit, northern China: in situ LA-ICP-MS evidence. Lithos 190:279–291CrossRefGoogle Scholar
  84. Zhai D, Liu J, Ripley EM, Wang J (2015) Geochronological and He–Ar–S isotopic constraints on the origin of the Sandaowanzi gold-telluride deposit, northeastern China. Lithos 212:338–352CrossRefGoogle Scholar
  85. Zhai D, Liu J, Zhang A, Sun Y (2017) U-Pb, Re-Os and 40Ar/39Ar geochronology of porphyry Sn ± Cu ± Mo and polymetallic (Ag-Pb-Zn-Cu) vein mineralization at Bianjiadayuan, Inner Mongolia, NE China: implications for discrete mineralization events. Econ Geol 112:2041–2059CrossRefGoogle Scholar
  86. Zhai D, Liu J, Tombros S, Williams-Jones AE (2018) The genesis of the Hashitu porphyry molybdenum deposit, Inner Mongolia, NE China: constraints from mineralogical, fluid inclusion, and multiple isotope (H, O, S, Mo, Pb) studies. Mineral Deposita 53:377–397CrossRefGoogle Scholar
  87. Zhang JH, Ge WC, Wu FY, Wilde SA, Yang JH, Liu XM (2008) Large-scale early cretaceous volcanic events in the northern great Xing’an range, northeastern China. Lithos 102:138–157CrossRefGoogle Scholar
  88. Zhang LC, Wu HY, Wan B, Chen ZG (2009) Ages and geodynamic settings of Xilamulun Mo–Cu metallogenic belt in the northern part of the North China Craton. Gondwana Res 16(2):243–254CrossRefGoogle Scholar
  89. Zhang JH, Gao S, Ge WC, Wu FY, Yang JH, Wilde SA, Li M (2010) Geochronology of the Mesozoic volcanic rocks in the great Xing’an range, northeastern China: implications for subduction-induced delamination. Chem Geol 276:144–165CrossRefGoogle Scholar
  90. Zhao YM, Zhang DQ (1997) Metallogeny and prospective evaluation of copper-polymetallic deposits in the Da Hinggan Mountains and its adjacent regions. Seismological Press, Beijing, pp 83–106 (in Chinese with English abstract)Google Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Degao Zhai
    • 1
    • 2
  • Jiajun Liu
    • 1
    • 2
  • Nigel J. Cook
    • 3
  • Xilong Wang
    • 4
  • Yongqiang Yang
    • 1
  • Anli Zhang
    • 5
  • Yingchun Jiao
    • 5
  1. 1.State Key Laboratory of Geological Processes and Mineral ResourcesChina University of GeosciencesBeijingChina
  2. 2.School of Earth Sciences and ResourcesChina University of GeosciencesBeijingChina
  3. 3.School of Chemical EngineeringUniversity of AdelaideAdelaideAustralia
  4. 4.Earthquake Administration of Liaoning ProvinceShenyangChina
  5. 5.Lituo Mining CompanyChifengChina

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