Mineralium Deposita

, Volume 52, Issue 5, pp 675–686 | Cite as

Cadmium isotope fractionation in the Fule Mississippi Valley-type deposit, Southwest China

  • Chuanwei Zhu
  • Hanjie Wen
  • Yuxu Zhang
  • Shaohong Fu
  • Haifeng Fan
  • Christophe Cloquet
Article

Abstract

High-precision cadmium (Cd) isotope compositions are reported for sphalerite, galena, and smithsonite from the Fule Zn–Pb–Cd deposit, a typical Mississippi Valley-type deposit in Southwest China. Dark sphalerite has lighter δ114/110Cd values (0.06 to 0.46 ‰) than light sphalerite (0.43 to 0.70 ‰), and the Cd in galena is primarily in the form of sphalerite micro-inclusions with δ114/110Cd of −0.35 to 0.39 ‰. From early to late stages, δ114/110Cd values of smithsonite regularly increase from 0.19 to 0.42 ‰, whereas Cd/Zn ratios decrease from 252 to 136; the δ114/110Cd variation pattern of supergene smithsonite reflects kinetic Rayleigh fractionation during low-temperature processes. From the bottom to the top of the orebody, the dark sphalerite has different patterns in δ114/110Cd values, Cd/Zn ratios, δ34S values, and Fe concentrations compared to the light sphalerite, indicating that dark and light sphalerite formed by different processes. The varying patterns of δ144/110Cd values and Cd/Zn ratios within light sphalerite are similar to those of layered smithsonite, and the δ144/110Cd values have a positive correlation with δ34S values, indicating that Cd isotope fractionation in the light sphalerite was due to kinetic Rayleigh fractionation. Instead, in dark sphalerite, the δ144/110Cd values have a negative correlation with δ34S values and a positive correlation with the Cd/Zn ratio. Thus, it can be concluded that dark sphalerite could be modeled in terms of two-component mixing (basement fluid and host-rock fluid), which is in agreement with previous explanations for the negative correlation between δ66Zn and δ34S in some typical Zn–Pb deposits. We propose that the significant variation in Cd isotope composition observed in the Fule Zn–Pb–Cd deposit confirms that Cd isotopes can be used for tracing fluid evolution and ore formation.

Keywords

Cadmium and sulfur isotopes Cd-bearing minerals Zn–Pb–Cd deposits Stable isotope fractionation 

References

  1. Belissont R, Boiron MC, Luais B, Cathelineau M (2014) LA-ICP-MS analyses of minor and trace elements and bulk Ge isotopes in zoned Ge-rich sphalerites from the Noailhac–Saint-Salvy deposit (France): insights on incorporation mechanisms and ore deposition processes. Geochim Cosmochim Acta 126:518–540CrossRefGoogle Scholar
  2. Bortnikov NS, Dobrovol’skaya MG, Genkin AD, Naumov VB, Shapenko VV (1995) Sphalerite-galena geothermometers; distribution of cadmium, manganese, and the fractionation of sulfur isotopes. Econ Geol 90:155–180CrossRefGoogle Scholar
  3. Claypool GE, Holser WT, Kaplan IR, Sakai H, Zak I (1980) The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation. Chem Geol 28:199–260CrossRefGoogle Scholar
  4. Clayton RN (1981) Isotopic thermometry. In: Newton RC, Navrotsky A, Wood BJ (eds) Thermodynamics of minerals and melts. Springer Verlag, New York, pp. 85–109Google Scholar
  5. Cloquet C, Rouxel O, Carignan J, Libourel G (2005) Natural cadmium isotopic variations in eight geological reference materials (NIST SRM 2711, BCR 176, GSS-1, GXR-1, GXR-2, GSD-12, Nod-P-1, Nod-A-1) and anthropogenic samples, measured by MC-ICP-MS. Geostandard Geoanal Res 29:95–106CrossRefGoogle Scholar
  6. Cloquet C, Carignan J, Libourel G, Sterckeman T, Perdrix E (2006) Tracing source pollution in soils using cadmium and lead isotopes. Environ Sci Technol 40:2525–2530CrossRefGoogle Scholar
  7. Cook NJ, Ciobanu CL, Pring A, Skinner W, Shimizu M, Danyushevsky L, Saini-Eidukat B, Melcher F (2009) Trace and minor elements in sphalerite: a LA-ICPMS study. Geochim Cosmochim Acta 73:4761–4791CrossRefGoogle Scholar
  8. Gagnevin D, Boyce AJ, Barrie CD, Menuge JF, Blakeman RJ (2012) Zn, Fe and S isotope fractionation in a large hydrothermal system. Geochim Cosmochim Acta 88:183–198CrossRefGoogle Scholar
  9. Han RS, Liu CQ, Huang ZL, Chen J, Ma DY, Lei L, Ma GS (2007) Geological features and origin of the Huize carbonate-hosted Zn–Pb–(Ag) district, Yunnan, South China. Ore Geol Rev 31:360–383CrossRefGoogle Scholar
  10. Horner TJ, Rickaby REM, Henderson GM (2011) Isotopic fractionation of cadmium into calcite. Earth Planet Sci Lett 312:243–253CrossRefGoogle Scholar
  11. Huang ZL, Chen J, Han RS, Li WB, Liu CQ, Zhang ZL, Ma DY, Gao DR, Yang ML (2004) Geochemistry and ore-formation of the Huize giant lead-zinc deposit, Yunnan Province, China: discussion on the relationship between Emeishan flood basalts and lead-zinc mineralization (in Chinese). Geological Publishing House, Beijing, pp. 50–146Google Scholar
  12. Lambelet M, Rehkämper M, Flierdt T, Xue ZC, Kreissig K, Coles B, Porcelli D, Andersson P (2013) Isotopic analysis of Cd in the mixing zone of Siberian rivers with the Arctic Ocean—new constraints on marine Cd cycling and the isotope composition of riverine Cd. Earth Planet Sci Lett 361:64–73CrossRefGoogle Scholar
  13. Leach DL, Sangster DF, Kelley KD, Large RR, Garven G, Allen CR, Gutzmer J, Walters S (2005) Sediment-hosted lead-zinc deposits: a global perspective. In: Hedenquist JW, Thompson JFH, Goldfarb RJ, Richards JP (eds) Economic geology 100th anniversary volume. Society of Economic Geologists, Littleton, pp. 561–607Google Scholar
  14. Liu J, Wen HJ, Zhang YX, Fan HF, Zhu CW (2016) Precise Mo isotope ratio measurements of low-Mo (ng g−1) geological samples using MC-ICP-MS. J Analyt Atomic Spectrom. doi:10.1039/C6JA00006A Google Scholar
  15. Metz S, Trefry JH (2000) Chemical and mineralogical influences on concentrations of trace metals in hydrothermal fluids. Geochim Cosmochim Acta 64:2267–2279CrossRefGoogle Scholar
  16. Palero-Fernández FJ, Martín-Izard A (2005) Trace element contents in galena and sphalerite from ore deposits of the Alcudia Valley mineral field (Eastern Sierra Morena, Spain). J Geochem Explor 86:1–25CrossRefGoogle Scholar
  17. Pallavicini N, Engstrom E, Baxter DC, Ohlander B, Ingri J, Rodushkin I (2014) Cadmium isotope ratio measurements in environmental matrices by MC-ICP-MS. J Analyt Atomic Spectrom 29:1570–1584CrossRefGoogle Scholar
  18. Ripperger S, Rehkämper M, Porcelli D, Halliday AN (2007) Cadmium isotope fractionation in seawater—a signature of biological activity. Earth Planet Sci Lett 261:670–684CrossRefGoogle Scholar
  19. Rudnick RL, Gao S (2003) Composition of the continental crust. Treatise Geochem 3:1–64CrossRefGoogle Scholar
  20. Rye RO, Ohmoto H (1974) Sulfur and carbon isotopes and ore genesis: a review. Econ Geol 69:826–842CrossRefGoogle Scholar
  21. Schmitt AD, Stephen JG, Abouchami W (2009) Mass-dependent cadmium isotopic variations in nature with emphasis on the marine environment. Earth Planet Sci Lett 277:262–272CrossRefGoogle Scholar
  22. Schwartz MO (2000) Cadmium in zinc deposits: economic geology of a polluting element. Int Geol Rev 42:445–469CrossRefGoogle Scholar
  23. Si RJ (2005) Ore deposit geochemistry of the Fule dispersed element-polymetallic deposit, Yunnan Province. A dissertation submitted to Chinese Academy of Sciences for a doctor degree. Guiyang (In Chinese with English abstract)Google Scholar
  24. Thiessen EJ, Gleeson SA, Bennett V, Creaser RA (2016) The Tiger deposit: a carbonate-hosted, magmatic-hydrothermal gold deposit, Central Yukon, Canada. Econ Geol 111:421–446CrossRefGoogle Scholar
  25. Tu GC, Gao ZM, Hu RZ, Zhang Q, Li CY, Zhao ZH, Zhang BG (2004) The geochemistry and deposit-forming mechanism of disperse elements. Geological Publishing House, Beijing, pp. 69–115 in ChineseGoogle Scholar
  26. Wen HJ, Zhang YX, Cloquet C, Zhu CW, Fan HF, Luo CG (2015) Tracing sources of pollution in soils from the Jinding Pb–Zn mining district in China using cadmium and lead isotopes. Appl Geochem 52:147–154CrossRefGoogle Scholar
  27. Wen HJ, Zhu CW, Zhang YX, Cloque C, Fan HF, Fu SH (2016) Zn/Cd ratios and cadmium isotope evidence for the classification of lead-zinc deposits. Sci Rep. doi:10.1038/srep25273 Google Scholar
  28. Wilkinson JJ, Weiss DJ, Mason TFD, Coles BJ (2005) Zinc isotope variation in hydrothermal systems: preliminary evidence from the Irish midlands ore field. Econ Geol 100:583–590CrossRefGoogle Scholar
  29. Wombacher F, Rehkämper M, Mezger K, Münker C (2003) Stable isotope compositions of cadmium in geological materials and meteorites determined by multiple-collector ICP-MS. Geochim Cosmochim Acta 23:4639–4654CrossRefGoogle Scholar
  30. Yang JL, Li YB, Liu SQ, Tian HQ, Chen CY, Liu JM, Shi YL (2014) Theoretical calculations of Cd isotope fractionation in hydrothermal fluids. Chem Geol 391:74–82CrossRefGoogle Scholar
  31. Ye L, Cook NJ, Ciobanu CL, Liu YP, Zhang Q, Liu TG, Gao W, Yang YL, Danyushevskiy L (2011) Trace and minor elements in sphalerite from base metal deposits in South China: a LA-ICPMS study. Ore Geol Rev 39:188–217CrossRefGoogle Scholar
  32. Zhang YX, Wen HJ, Zhu CW, Fan HF, Luo CG, Liu J, Cloquet C (2016) Cd isotope fractionation during simulated and natural weathering. Environ Pollut 216:9–17CrossRefGoogle Scholar
  33. Zheng YF, Hoefs J (1993) Effects of mineral precipitation on the sulfur isotope composition of hydrothermal solutions. Chem Geol 105:259–269CrossRefGoogle Scholar
  34. Zhou JX, Huang ZL, Zhou GF, Li XB, Ding W, Bao GP (2011) Trace elements and rare earth elements of sulfide minerals in the Tianqiao Pb-Zn ore deposit, Guizhou Province China. Acta Geol Sin (English Edition) 85:189–199CrossRefGoogle Scholar
  35. Zhou JX, Huang ZL, Zhou MF, Li XB, Jin ZG (2013) Constraints of C-O-S-Pb isotope compositions and Rb-Sr isotopic age on the origin of the Tianqiao carbonate–hosted Pb–Zn deposit, SW China. Ore Geol Rev 53:77–92CrossRefGoogle Scholar
  36. Zhou JX, Huang ZL, Zhou MF, Zhu XK, Muchez P (2014a) Zinc, sulfur and lead isotopic variations in carbonate-hosted Pb-Zn sulfide deposits, southwest China. Ore Geol Rev 58:41–54CrossRefGoogle Scholar
  37. Zhou JX, Huang ZL, Lv ZC, Zhu XK, Gao JG, Mirnejad H (2014b) Geology, isotope geochemistry and ore genesis of the Shanshulin carbonate-hosted Pb-Zn deposit, southwest China. Ore Geol Rev 63:209–225CrossRefGoogle Scholar
  38. Zhu CW, Wen HJ, Zhang YX, Fan HF, Fu SH, Xu J, Qin TR (2013) Characteristics of Cd isotopic compositions and their genetic significance in the lead-zinc deposits of SW China. Sci China Earth Sci 56:2056–2065CrossRefGoogle Scholar
  39. Zhu CW, Wen HJ, Zhang YX, Liu YZ, Wei RF (2015) Isotopic geochemistry of cadmium: a review. Acta Geol Sinica (English Edition) 89:2048–2057CrossRefGoogle Scholar
  40. Zhu CW, Wen HJ, Zhang YX, Fan HF (2016) Cadmium and sulfur isotopic compositions of the Tianbaoshan Zn-Pb-Cd deposit, Sichuan Province, China. Ore Geol Rev 76:152–162CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Chuanwei Zhu
    • 1
  • Hanjie Wen
    • 1
  • Yuxu Zhang
    • 1
  • Shaohong Fu
    • 1
  • Haifeng Fan
    • 1
  • Christophe Cloquet
    • 2
  1. 1.State Key Laboratory of Ore Deposit Geochemistry, Institute of GeochemistryChinese Academy of SciencesGuiyangChina
  2. 2.Centre de Recherches Petrographique et Geochimiques, CNRS/UMR 7358Vandoeuvre-les-Nancy CedexFrance

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