International Journal of Metalcasting

, Volume 9, Issue 4, pp 39–48 | Cite as

Effects of Zinc Oxide Addition on the Microstructure and Mechanical Properties of AZ91E Mg Alloy

  • Subrata Saha
  • Comondore Ravindran
Article
  • 62 Downloads

Abstract

Grain refinement is a well documented method to increase the mechanical properties of Mg alloys. This study is an ongoing quest towards improving Mg grain refinement, with cost effective approach. In this research, the influence of ZnO on the microstructure and mechanical properties of permanent mold cast AZ91E Mg alloy was investigated. With an addition of 0.5 wt.% ZnO, the average grain size of the alloy decreased from 133 μm to 79 μm. The maximum yield strength, ultimate tensile strength and elongation obtained were 15%, 15% and 80% respectively greater than that of the base alloy at different addition levels of ZnO. Cleavage type fracture was dominant in the base alloy while alloys refined with 0.5 wt.% ZnO showed more quasi-cleavage type fracture. With 3 wt.% ZnO addition, the Rockwell hardness and Vicker’s microhardness increased 14% and 24% respectively compared to the unrefined alloy

Keywords

gram refinement AZ91E ZnO microstructure mechanical properties fracture 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Reference

  1. 1.
    Celotto, S., “TEM Study of Continuous Precipitation in Mg-9wt.% Al-1 wt.% Zn Alloy,“ Acta Materialia, vol. 48, pp. 1775–1787 (2000).CrossRefGoogle Scholar
  2. 2.
    Chen, T.J., Wang, R.Q., Ma, Y., Hao, Y., “Grain Refinement of AZ9ID Magnesium Alloy by Al-Ti-B Master Alloy and Its Effect on Mechanical Properties”, Materials and Design, vol. 34, pp. 637–648 (2012).CrossRefGoogle Scholar
  3. 3.
    Vinotho, D., Raghukandan, K., Pillai, U. T. S., Pai, B. C. “Grain Refining Mechanisms in Magnesium Alloys-An Overview,“ Transactions of the Indian Institute of Metals, vol. 62, issue 6, pp. 521–532 (2009).CrossRefGoogle Scholar
  4. 4.
    Dieter, G.E. “Mechanical Metallurgy,“ McGraw-Hill, 3rd ed. (1986).Google Scholar
  5. 5.
    Dahle, A.K., Lee, Y.C., Nave, M.D., Schaffcr, P.L., StJohn, D.H., “Development of the As-Cast Micrestructure in Magnesium-Aluminum Alloys,“ Journal of Light Metals, vol. 1, pp. 61–72 (2001).CrossRefGoogle Scholar
  6. 6.
    Emley, EF., “Principles of Magnesium Technology,“ Pcrgamon Press, London (1966).Google Scholar
  7. 7.
    Nimityongskul, S., Jones, M., Choi, H., Lakes, R., Kou, S., Li, X., “Grain Refinement Mechanisms in Mg-Al Alloys with Al C.Microparticlcs,“ Materials Science and Engineering A, vol. 527, pp. 2104–2111 (2005)CrossRefGoogle Scholar
  8. 8.
    Lu, L., Dahle, A.K., StJohn, D.H., “Grain Refinement Efficiency and Mechanism of Aluminum Carbide in Mg-Al Alloys,“ Seripia Marenalia, vol. 53, pp. 517–522 (2005).Google Scholar
  9. 9.
    Shepelev, D., Klempf, J., Bamberger, M., Katsman, A., “Grain Refinement and Mechanical Enhancement of AZ9IE Alloy by Addition of Ceramic Particles,“ Journal of Materials Science, vol. 46, pp. 5798–5806 (2011).CrossRefGoogle Scholar
  10. 10.
    Easton, M.A., Schiffl, A., Yao, J.Y., Kaufmann, H., “Grain Refinement of Mg-AK(-Mn) Alloys by SiC Additions,“ Scripia Marenalia, vol. 55, pp. 379–382 (2006).Google Scholar
  11. 11.
    Chen, T.J., Jiang, X.D., Ma, Y., Wang, R.Q., Hao, Y., “Grain Refinement of AZ91D Magnesium Alloy by MgCO3,“ Materials Research, vol 14(1). pp. 124–133 (2011).Google Scholar
  12. 12.
    Gao, S.Y., Cui, J.Z., Li, Q.C., Zhang, Z.Q., “The Research on the Effect of MgCO; on Grain Refinement in AZ31 Magnesium Alloys,” Mat.-wiss.u. Werkstofftech, vol. 41, Issue 8, pp. 652–656 (2010).CrossRefGoogle Scholar
  13. 13.
    Zeng, X., Wang, Y., Ding, W., Luo, A.A., Sachdev, A.K., “Effect of Strontium on the Micrestructure. Mechanical Properties and Fracture Behavior of AZ31 Magnesium Alloys,“ Metallurgical and Materials Transactions A, vol. 37A, pp. 1333–1341 (2006).CrossRefGoogle Scholar
  14. 14.
    Liu, S.F., Liu, L.Y., Kang, L.G., “Refinement Role of Electromagnetic Stirring and Strontium in AZ91 Magnesium Alloys,“ Journal ofAlloys and Compounds, vol. 450, pp. 546–550 (2008).CrossRefGoogle Scholar
  15. 15.
    Surcsh, M., Srinivasan, A., Ravi, K.R., Pillai, U.T.S., Pai, B.C., “Influence of Boron Addition on the Grain Refinement and Mechanical Properties of AZ91 Mg Alloy,“ Materials Science and Engineering A, vol. 525, pp. 207–210 (2009).CrossRefGoogle Scholar
  16. 16.
    Fu, H.M., Zhang, M.X., Qiu, D., Kelly, P.M., Taylor, J. A., “Grain Refinement by AIN Particles in Mg-Al Based Alloys,“ Journal of Alloys and Compounds, vol. 478, pp 809–812 (2009).CrossRefGoogle Scholar
  17. 17.
    Lee. Y.C., Dahle, A.K., StJohn, D.H., “The Role of Solute in Grain Refinement of Magnesium.” Metallurgical and Materials Transactions A, vol. 31 A, pp. 2895–2906 (2000).CrossRefGoogle Scholar
  18. 18.
    Li, P., Tang, B., Kandalova, E.G., “Microstrueture and Properties of AZ91D Alloy with Ca Additions,“ Materials Letters, vol. 59, pp. 671–675 (2005).CrossRefGoogle Scholar
  19. 19.
    Elsayed, A., Lee, K., Ravindran, C, “Effect of Ca and Mb Additions on the Castability and Mechanical Properties of AZ91D Mg Alloy Pemianent Mold Castings,“ AFS Tiansaciions, vol. 117, pp. 659–672 (2009).Google Scholar
  20. 20.
    Cao, P., Qion, M., StJohn, D.H., “Effect of Manganese on Grain Refinement of Mg-Al Based Alloys,“ Scripia Materialia, vol. 54, pp. 1853–1858 (2006).CrossRefGoogle Scholar
  21. 21.
    Liu, S.F., Li, B., Wang, X.H., Su. W., Han, H., “Refinement Effcclof Cerium, Calcium and Strontium in AZ91 Magnesium Alloy,“ Journal of Material Processing Technology, vol. 209, pp. 3999–4004 (2009)CrossRefGoogle Scholar
  22. 22.
    Qiu, D., Zhang, MX, “Effect of Active Heterogeneous Nucleation Particles on the Grain Refining Efficiency in an Mg10 wt.% Y Cast Alloys,“ Journal of Alloys and Compounds, vol. 488, pp. 260–264 (2009).CrossRefGoogle Scholar
  23. 23.
    Zhao, Z., Chen, Q., Wang, Y., Shu, D.Y., “Microstructurcsond Mechanical Properties of AZ91D Alloys with Y Addition,“ Material Science and Engineering A, vol. 515, pp. 152–161 (2009).CrossRefGoogle Scholar
  24. 24.
    StJohn, D.H., Qian, M., Easlon, M.A., Cao, P., Hildcbrand, Z., “Grain Refinement of Magnesium Alloys,“ Metallurgical and Materials Transactions A, vol.36A. pp. 1669–1679 (2005).CrossRefGoogle Scholar
  25. 25.
    Fu, H.M., Qiu, D., Zhang, MX, Wang, H., Kelly, P.M., Taylor, J. A., “The Developments of a New Grain Refiner for Magnesium Alloys Using Edge-to-Edge Model,“ Journal of Alloys and Compounds, vol. 456, pp. 390–394 (2008).CrossRefGoogle Scholar
  26. 26.
    Lee, K., “A Study on Grain Refinement of AZ91E Magnesium Alloy with Al-5TiB2, Al-Al4C3 and ZnO Additions,“ Ryerson University-Toronto, M.A.Sc. Thesis (2011).Google Scholar
  27. 27.
    Sana, S., Ravindran, C, “Grain Refinement of AZ91E and Mg-9 wt.% Al Binary Alloys Using Zinc Oxide,“ International Journal of Metalcasting, vol. 9, issue 1, pp. 33–42 (2015).CrossRefGoogle Scholar
  28. 28.
    Eoston, M.A., StJohn, D.H., “A Model of Grain Refinement Incorporating Alloy Constitution and Potency of Heterogeneous Nuclcation Particles,“ Acta Materialia, vol. 49, pp. 1867–1878 (2001).CrossRefGoogle Scholar
  29. 29.
    Liu, Y., Liu, X., Xiufang, B., “Grain Refinement of Mg-Al Alloys with Al4C3-SiC/Al Master Alloy,“ Materials Letters, vol. 58, pp. 1282–1287 (2004).CrossRefGoogle Scholar
  30. 30.
    Zhang, M.X., Kelly, P.M, Qian, M., Taylor, J.A., “Crystallography of Grain Refinement in Mg-Al Based Alloys,“ Acta Materialia, vol. 53, pp. 3261–3270 (2005).CrossRefGoogle Scholar
  31. 31.
    Campbell, J., “Castings,“ Butterworth-Heinimann, Oxford (1993).Google Scholar
  32. 32.
    Pearson. W.B., “A Handbook of Lattice Spacings and Structures of Metals and Alloys.” Pergamon Press, Oxford, United Kingdom (1964).Google Scholar
  33. 33.
    Lu, Y.Z., Wang, Q.D., Ding, W.J., Zeng, X.Q., Zhu, Y.P., “Fracture Behavior of AZ91 Magnesium Alloy,“ Material Letters, vol. 44, pp. 265–268 (2000).CrossRefGoogle Scholar
  34. 34.
    Suresh, M., Srinivasan, A., Pillai, U.T.S., Pai, B.C. “The Effect of Charcoal Addition on the Grain Refinement and Ageing Response of Magnesium Alloy AZ91,” Material Science and Engineering A, vol. 528, pp. 8573–8578 (2011).CrossRefGoogle Scholar

Copyright information

© American Foundry Society 2015

Authors and Affiliations

  • Subrata Saha
    • 1
  • Comondore Ravindran
    • 1
  1. 1.Centre for Near-net-shape Processing of MaterialsRyerson UniversityTorontoCanada

Personalised recommendations