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Journal of the Iranian Chemical Society

, Volume 4, Issue 1, pp 114–125 | Cite as

Synthesis, physico-chemical and thermal characteristics of seven and ten coordinated complexes of trivalent lanthanides derived from 4[N-(cinnamalidene)amino]antipyrine semicarbazone and diphenyl sulfoxide

  • R. K. AgarwalEmail author
  • B. Prakash
  • V. Kumar
  • A. Aslam Khan
Article

Abstract

In present studies a new series of twenty four complexes of seven and ten coordinated compounds derived from 4[Ncinnamalidene) amino]antipyrine semicarbazone (CAAPS) as primary ligand and diphenyl sulfoxide (DPSO) as secondary ligand has been reported. All the complexes have the general composition LnX3.n(CAAPS).DPSO (Ln = La, Pr, Nd, Sm, Gd, Tb, Dy or Ho, X = NCS or ClO4, n = 2, X = NO3, n = 1). The compounds have been characterized by elemental analysis, molar conductance, magnetic susceptibility, infrared and electronic spectra. Thermal characteristics were also reported. Based on the data appropriate structures are assigned for these complexes.

Keywords

Lanthanide(III) Complexes 4[N-Cinnamalidene)amino]antipyrine semicarbazone Diphenyl sulfoxide 

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Copyright information

© Iranian Chemical Society 2007

Authors and Affiliations

  • R. K. Agarwal
    • 1
  • B. Prakash
    • 1
  • V. Kumar
    • 1
  • A. Aslam Khan
    • 1
  1. 1.Department of ChemistryLajpat Rai Postgraduate CollegeGhaziabadIndia

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