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Applied Magnetic Resonance

, 26:275 | Cite as

EPR studies of Cu2+-doped bis(saccharinato)bis(pyridine)zinc(II) single crystals

  • E. Bozkurt
  • I. Kartal
  • B. Karabulut
  • O. Z. Yeşilel
Article

Abstract

The electron paramagnetic resonance spectra of Cu2+ impurities in bis(saccharinato)bis(pyridine)zinc(II) single crystals have been studied at room temperature in three mutually perpendicular planes. The angular variation of the spectra indicates the substitution of the host Zn2+ with Cu2+. Two magnetically inequivalent sites for Cu2+ have been observed. The spectra were fitted to the rhombic spin Hamiltonian. The spin Hamiltonian parameters and the molecular orbital coefficients were evaluated for the two sites. The ground-state wave function of Cu2+ ion in the lattice has been constructed.

Keywords

Electron Paramagnetic Resonance Electron Paramagnetic Resonance Spectrum Saccharin Electron Paramagnetic Resonance Study Spin Hamiltonian Parameter 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer 2004

Authors and Affiliations

  • E. Bozkurt
    • 1
  • I. Kartal
    • 1
  • B. Karabulut
    • 1
  • O. Z. Yeşilel
    • 2
  1. 1.Department of Physics, Faculty of SciencesOndokuz Mayis UniversitySamsunTurkey
  2. 2.Department of Chemistry, Faculty of SciencesOndokuz Mayis UniversitySamsunTurkey

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