Applied Magnetic Resonance

, Volume 14, Issue 2–3, pp 357–366 | Cite as

Solvent-induced H/D isotope effect on129Xe chemical shifts

  • Yu. K. Grishin
  • R. K. Mazitov
  • A. N. Panov
Article
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Abstract

An effect of substitution of deuterium for protium in molecules of 17 solvents onl29Xe NMR shifts was studied. The variation range of solvent-induced isotope xenon shifts σ s i exceeds 5 ppm and lies in the range from −1.18 ppm (in CH3OD solution) to 3.92 ppm (in D2O) at 28°C. Experimental results agree with the concept that interaction of xenon atoms with solvent molecules is determined predominantly by dispersion forces. Correlations of σ s i with the isotope effect on polarizability, boiling point, and vapor pressure of solvents were established. Anomalous manifestation of properties of aqueous solution was detected.

Keywords

Xenon C6D6 Solvent Molecule Isotope Effect Isotopic Substitution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Springer 1998

Authors and Affiliations

  • Yu. K. Grishin
    • 1
  • R. K. Mazitov
    • 2
    • 3
  • A. N. Panov
    • 2
  1. 1.NMR Laboratory, Chemistry DepartmentMoscow State UniversityMoscowRussian Federation
  2. 2.Institute of General and Inorganic ChemistryMoscowRussian Federation
  3. 3.N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of SciencesMoscowRussian Federation

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