Acta Physica Hungarica

, 54:139 | Cite as

Investigation of anti-Stokes fluorescence in mixed rhodamine 6G—Malachite green systems

  • A. Bujko
  • C. Bojarski
  • R. Bujko
Fluids, Plasmas and Electric Discharges
  • 55 Downloads

Abstract

Concentrational changes of the fluorescence quantum yield and emission anisotropy were measured for rhodamine 6G (donor) in the presence of malachite green (acceptor) in glycerin—alcohol solutions, excited in the anti-Stokes and Stokes regions. Reduction of the nonradiative energy transfer efficiency in the case of anti-Stokes excitation was observed. The results of measurements proved to be in good agreement with the theory [10] which allows for a multistep mechanism from donor to acceptor energy transfer for Stokes as well as anti-Stokes excitation. However, in the latter case this agreement could have been obtained for a clearly lower value of the absolute donor fluorescence yield.

Reference

  1. 1.
    C. Bojarski, A. Bujko, J. Dudkiewicz and R. Twardowski, Z. Naturforsch.,30 a, 1091, 1975.ADSGoogle Scholar
  2. 2.
    C. Bojarski, A. Bujko, R. Bujko and R. Twardowski, Acta Phys. et Chem. Szeged,23, 93, 1977.Google Scholar
  3. 3.
    C. Bojarski, A. Bujko, R. Bujko and R. Twardowski, Acta Phys. Polon,A 54, 713, 1978.Google Scholar
  4. 4.
    G. Weber, Biochem. J.,75, 335, 1960.Google Scholar
  5. 5.
    S. R. Anderson and G. Weber, Biochemistry,8, 371, 1969.CrossRefGoogle Scholar
  6. 6.
    J. Eisinger, A. A. Lamola, J. W. Longworth and W. B. Gratzer, Nature,226, 113, 1970.CrossRefADSGoogle Scholar
  7. 7.
    C. Bojarski, G. Obermueller and J. Kuśba, Z. Nauk. Politechn. Gdańsk,181, 2, 1971 (in Polish).Google Scholar
  8. 8.
    J. Dudkiewicz, Z. Nauk. Politechn. Gdańsk,181, 121, 1971 (in Polish).Google Scholar
  9. 9.
    A. Budó and I. Ketskeméty, Acta Phys. Hung.,14, 167, 1962.CrossRefGoogle Scholar
  10. 10.
    C. Bojarski and J. Domsta, Acta Phys. Hung.,30, 145, 1971.CrossRefGoogle Scholar
  11. 11.
    J. P. Webb, W. C. Mc Colgin, O. G. Peterson, D. L. Stockman and J. H. Eberly, J. Chem. Phys.,53, 4227, 1970.CrossRefADSGoogle Scholar
  12. 12.
    Th. Förster, Ann. Physik, Leipzig,2, 55, 1948.MATHCrossRefGoogle Scholar
  13. 13.
    C. Bojarski and J. Dudkiewicz, Chem. Phys. Letters,67, 450, 1979.CrossRefADSGoogle Scholar
  14. 14.
    M. D. Galanin, Zh. Eksper. Theor. Phys. USSR,28, 485, 1955.Google Scholar
  15. 15.
    M. Z. Maksimov and I. M. Rozman, Opt. i Spektr.,12, 606, 1962.Google Scholar
  16. 16.
    C. Bojarski and E. Grabowska, Z. Naturforsch.,35 a, 1030, 1980.ADSGoogle Scholar
  17. 17.
    C. Bojarski, J. Luminescence,5, 413, 1972.CrossRefADSGoogle Scholar
  18. 18.
    C. Bojarski, J. Luminescence,9, 40, 1974.CrossRefADSGoogle Scholar
  19. 19.
    L. Szalay, B. Sárkány and E. Tombácz, Acta Phys. et Chem. Szeged,11, 21, 1965.Google Scholar
  20. 20.
    C. Bojarski and J. Dudkiewicz, Z. Naturforsch.,26 a, 1028, 1971.ADSGoogle Scholar
  21. 21.
    C. Bojarski and E. Grabowska, Acta Phys. Polon.,A 60, 397, 1981.Google Scholar
  22. 22.
    L. E. Erickson, J. Luminescence,5, 1, 1972.CrossRefADSGoogle Scholar
  23. 23.
    R. Beserman, G. Curie and D. Curie, J. Luminescence,8, 326, 1974.CrossRefADSGoogle Scholar
  24. 24.
    M. B. Huglin, Light Scattering from Polymer Solutions, Academic Press, London, New York, 1972.Google Scholar
  25. 25.
    L. Woliński, K. Witkowski and Z. Turzyński, Makrom. Chemie,180, 2399, 1979.CrossRefGoogle Scholar
  26. 26.
    S. I. Vavilov, Collected Papers Acad. Sci. USSR, Moscow-Leningrad, 1952, Vol. 2, p. 373.Google Scholar
  27. 27.
    L. Kozma, E. Farkas and M. Fekete, Acta Phys. et Chem. Szeged,16, 97, 1970.Google Scholar
  28. 28.
    I. Ketskeméty and L. Kozma, Acta Phys. Hung.,29, 331, 1970.CrossRefGoogle Scholar
  29. 29.
    J. N. Bodunov, J. V. Kolobkova and V. L. Ermolajev, Opt. i Spektr.,44, 2, 1978.Google Scholar
  30. 30.
    J. N. Bodunov and V. A. Malyshev, Opt. i Spektr.,46, 3, 1979.Google Scholar
  31. 31.
    J. N. Bodunov, V. A. Malyshev, S. V. Jakovlev, Zh. Prikl. Spektrosk.,32, 5, 1980.Google Scholar

Copyright information

© with the authors 1983

Authors and Affiliations

  • A. Bujko
    • 1
  • C. Bojarski
    • 1
  • R. Bujko
    • 1
  1. 1.Institute of PhysicsTechnical UniversityGdańskPoland

Personalised recommendations