Cyclic oxidation behavior of TiAl composites incorporated with TiB2 dispersoids
Abstract
TiAl alloys incorporated in (0,3,5,10) wt.% TiB2 dispersoids were manufactured via mechanical alloyingspark plasma sintering (MA-SPS), and their cyclic oxidation characteristics were studied at 800, 900 and 1000°C in air. The cyclic oxidation resistance of the prepared TiAl-TiB2 composites effectively increased with increases in TiB2 content. The oxide scale formed consisted of an outer TiO2 layer, an intermediate Al2O3 layer, and an inner (Al2O3+TiO2) mixed layer. The scale adherence was relatively good, and much thinner oxide scales, when compared to TiB2-free TiAl alloys, were formed on the prepared composites. The incorporated TiB2 dispersoids oxidized to TiO2 and B2O3 which evaporated during oxidation.
Keywords
TiAl intermetallics TiB2 dispersoid oxidationPreview
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References
- 1.Y. W. Kim,J. of Metals 41, 24 (1989).Google Scholar
- 2.Y. W. Kim,J. of Metals 46, 30 (1994).Google Scholar
- 3.D. B. Lee, J. H. Park, Y. H. Park and Y. J. Kim,Mater. Trans. JIM.38, 306 (1997).Google Scholar
- 4.J. Sorensen,Structural Intermetallics (eds., R. Darolia, J. J. Lewandowski, C. T. Liu, P. L. Martin, D. B. Miracle and M. V. Nathal), p. 717, TMS, PA (1993).Google Scholar
- 5.S. E. Hsu, H. Y. Chou, K. L. Wang, S. C. Yang, J. Y. Wang and C. I. Chen,Structural Iintermetallics (eds., R. Darolia, J. J. Lewandowski, C. T. Liu, P. L. Martin, D. B. Miracle and M. V. Nathal), p. 749, TMS, PA (1993).Google Scholar
- 6.D. E. Larsen, M. L. Adams, S. L. Kampe, L. Christodoulou and J. D. Bryant,Scripta metall. mater. 24, 851 (1990).CrossRefGoogle Scholar
- 7.M. Saqib, I. Weiss, G. M. Mehrotra, E. Clevenger, A. G. Jackson and H. A. Lipsitt,Metall. Trans. A 22, 1721 (1991).Google Scholar
- 8.K. T. Venkateswara Rao, G. R. Odette and R. O. Ritchie,Acta metall. 40, 353 (1992).CrossRefGoogle Scholar
- 9.S. A. Kekare, J. B. Toney and P. B. Aswath,Metall. Trans. A 26, 1835 (1995).CrossRefGoogle Scholar
- 10.S. Nourbakhsh, O. Sahin and H. Margolin,Acta metall. 43, 3035 (1995).CrossRefGoogle Scholar
- 11.L. Christodoulou, P. Parrish and C. R. Crowe,High Temperature/High Performance Composites (eds., F. D. Lemkey, S. G. Fishman, A. G. Evans and J. R. Strite), p. 29, Materials Research Society, PA (1988).Google Scholar
- 12.S. L. Kampe, J. D. Bryant and L. Christodoulou,Metall. Trans. A 22, 447 (1991).Google Scholar
- 13.A. Szaruga, L. Rothenflue, R. Srinivasan and H. A. Lipsitt,Scrip. metall. mater. 26, 1565 (1992).CrossRefGoogle Scholar
- 14.S. L. Kampe, P. Sadler, L. Christodoulou and D. E. Larsen,Metall. Mater. Trans. A 25, 2181 (1994).CrossRefGoogle Scholar
- 15.E. S. C. Chin, K. F. Ryan and R. R. Biederman,Gamma Titanium Aluminides (eds., Y. W. Kim, R. Wagner and M. Yamaguchi), p. 451, TMS, PA (1995).Google Scholar
- 16.E. S. C. Chin, T. Weerasooriya, P. Woolsey and R. R. Biederman,Gamma Titanium Aluminides (eds., Y. W. Kim, R. Wagner and M. Yamaguchi), p. 425, TMS, PA (1995).Google Scholar
- 17.D. B. Lee, M. H. Kim, C. W. Yang, S. H. Lee, M. Yang and Y. J. Kim,Oxid. Met. (2001) in press.Google Scholar
- 18.H. Hashimoto,Materia 38, 68 (1999).Google Scholar
- 19.J. H. Won, Y. J. Kim, S. W. An and D. B. Lee,J. Kor. Inst. Met. & Mater. 36, 546 (1998).Google Scholar
- 20.G. H. Meier,Oxidation of Intermetallics (eds., H. J. Grabke and M. Schütze), p. 15, Wiley-VCH, New York (1997).CrossRefGoogle Scholar
- 21.Y. Umakoshi, M. Yamaguchi, T. Sakagami and T. Yamane,J. Mater. Sci. 24, 1599 (1989).CrossRefADSGoogle Scholar
- 22.S. W. An and D. B. Lee,J. Kor. Inst. Met. & Mater. 36, 1671 (1998).Google Scholar
- 23.D. B. Lee,Bul. Kor. Inst. Met. & Mater. 10, 312 (1997).Google Scholar
- 24.S. C. Choi, H. J. Cho and D. B. Lee,J. Kor. Inst. Surf. Eng. 26, 235 (1993).Google Scholar
- 25.R. J. Irving and I. G. Worsley,J. Less-Common Met. 16, 103 (1968).CrossRefGoogle Scholar
- 26.M. G. Barandika, J. J. Echeberria, J. M. Sánchez and F. Castro,J. Mater. Chem. 8, 1851 (1998).CrossRefGoogle Scholar
- 27.H. Itoh, K. Sugiura and H. Iwahara,J. Ceram. Soc. Jpn. 103, 949 (1995).Google Scholar
- 28.B. Cockeram and R. A. Rapp,Oxid. Met. 45, 427 (1996).CrossRefGoogle Scholar