Abstract
The square root diffusivity matrix [r] and diffusivity matrix [D] have been measured for a Ni-4.0 at. pct Cr-6.3 at. pct Al-3.5 at. pct Mo quaternary alloy at 1100 °C. Using a constant diffusivity analysis, the diffusivities were obtained from three diffusion couples having small initial concentration differences of 5 at. pct or less. When elements of [r] were substituted into the error function solution of the diffusion equation, it was found that the predicted concentration profiles were accurate to within ±0.1 at. pct of measured values. Also, it was found that Mo tends to reduce the diffusion kinetics of Cr and Al in Ni-base alloys. These results suggest that these methods of analyzing diffusion data and predicting interdiffusion data can be applied to alloys containing more than four components.
Keywords
Metallurgical Transaction Diffusion Couple Sandia National Laboratory Diffusivity Matrix Ternary Diffusion CouplePreview
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