GC-MS analysis of dyes extracted from turmeric
Abstract
Standard extraction procedure for examining chromophoric substances of turmeric was investigated. Acetone and methanol were used as extracting solvents with different extraction procedures and pH levels. GC-MS analysis identified curcumene2 (6.7 min), feruloylmethane3 (8.3 min), coumaran4 (6.09 min), vanillin5 (6.2 min), and zingiberene6 (10.5 min) as the major products. Curcumin1 which has been known as the major chromophoric substance of turmeric was not detected in any samples. The maximum amount of curcumene2, which was used as the fingerprint product for turmeric dye, was obtained by utilizing presoaking and decanting step with methanol prior to actual extraction step using a waterbath shaker (WMM). The highest relative abundance of curcumene2 was detected in pH 6 sample followed by pH 5 indicating that the most appropriate pH level was in the range of pH 6–5.
Keywords
Turmeric Curcumin Curcumene Dye extraction GC-MSPreview
Unable to display preview. Download preview PDF.
References
- 1.C. Ahn and S. K. Obendorf,Text. Res. J.,74(11), 949 (2004).CrossRefGoogle Scholar
- 2.X. G. He, L. Z. Lin, L. Z. Lian, and M. Lindenmaier,Journal of Chromatography A,818, 127 (1998).CrossRefGoogle Scholar
- 3.“Color Index”, 3rd Ed., The Society of Dyers and Colourists, London, 1976.Google Scholar
- 4.CambridgeSoft, “The Merck Index”, Merck & Co., N.J., 2001.Google Scholar
- 5.K. I. Priyadarsini,Free Radical Biology & Medicine,23(6), 838 (1997).CrossRefGoogle Scholar
- 6.P. C. Crews,Studies in Conservation,32, 65 (1987).CrossRefGoogle Scholar
- 7.B. L. Ford,Studies in Conservation,37, 1 (1992).CrossRefGoogle Scholar
- 8.D. Grosjean, P. M. Whitmore, P. D. Moor, G. R. Cass, and J. R. Druzik,Environ. Science and Technology,22(11), 1357 (1988).CrossRefGoogle Scholar
- 9.S. Cho, H. Song, and B. Kim,Journal of the Korean Society of Clothing and Textiles,21(6), 1051 (1997).Google Scholar
- 10.Y. J. Chu and H. O. Soh,Journal of the Korean Society of Clothing and Textiles,20(3), 429 (1996).Google Scholar
- 11.S. W. Nam, “Natural Dyeing Class”, Laboratory of Natural Dyeing, Sungkyunkwan University, Suwon, 1999.Google Scholar
- 12.E. K. Hwang, M. S. Kim, D. S. Lee, and K. B. Kim,J. Korean Fiber Soc.,35(8), 490 (1998).Google Scholar
- 13.Y. C. Kim and K. S. Kim, “Proceedings of the 2002 Joint Conference of the Korean Fiber Society and the Korean Society of Clothing and Textiles”, pp.502–507, 2002.Google Scholar
- 14.J. S. Jung and J. H. Sul,Journal of the Korean Society of Clothing and Textiles,26(2), 325 (2002).Google Scholar
- 15.C. Ahn and S. K. Obendorf,Journal of the Korean Society of Clothing and Textiles,27(11), 1350 (2003).Google Scholar
- 16.Agilent Technologies, National Institute of Standards and Technology 98 Mass Spectral Libraries, NIST 98, Rev. D.02.00, 2000.Google Scholar
- 17.Y. J. Wang, M. H. Pan, A. L. Cheng, L. I. Lin, Y. S. Ho, C. Y. Hsieh, and J. K. Lin,Journal of Pharmaceutical and Biomedical Analysis,15, 1867 (1997).CrossRefGoogle Scholar
- 18.K. I. Priyadarsini, D. K. Maity, G. H. Naik, M. S. Kumar, M. K. Unnikrishnan, J. G. Satav, and H. Mohan,Free Radical Biology & Medicine,35(5), 475 (2003).CrossRefGoogle Scholar
- 19.R. Richmond and E. Pombo-Villar,Journal of Chromatography A,760, 303 (1997).CrossRefGoogle Scholar
- 20.P. S. Negi, G. K. Jayaprakasha, L. Jagan Mohan Rao, and K. K. Sakariah,J. Agric. Food Chem.,47, 4297 (1999).CrossRefGoogle Scholar
- 21.Y. H. Lee and H. D. Kim,Fibers and Polymers,5(4), 303 (2004).CrossRefGoogle Scholar