Journal of Phase Equilibria

, Volume 11, Issue 5, pp 468–480 | Cite as

The Mn-Si (Manganese-Silicon) system

  • A. B. Gokhale
  • R. Abbaschian
Alloy Phase Diagram Evaluations


Equi Diagram Alloy Phase Diagram Crys Structure Homogeneity Range Excess Entropy 
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Cited references

  1. 06Doe:.
    F. Doerinckel, “On the Compounds of Manganese with Silicon,”Z. Anorg. Chem., 50, 117–132 (1906) in German. (Equi Diagram; Experimental; #)CrossRefGoogle Scholar
  2. 25Wes:.
    A. Westgren and G. Phragmen, “On the Crystal Structure Forms of Manganese,”Z. Phys., 33, 787–788 (1925) in German. (Equi Diagram, Crys Structure; Experimental)ADSCrossRefGoogle Scholar
  3. 33Bor:.
    B. Boren, “X-ray Investigation of Alloys of Silicon with Chromium, Manganese, Cobolt, and Nickel,”Ark. Kern., Miner. Geol., 11A(10), 1–28 (1933) in German. (Equi Diagram, Crys Structure; Experimental)Google Scholar
  4. 33Vog:.
    R. Vogel and H. Bedarff, “The State Diagram of Manganese-Silicon,”Arch. Eisenhüttenwes., 7, 423–425 (1933-34) in German. (Equi Diagram; Experimental; #)Google Scholar
  5. 36Ama:.
    K Amark, B. Boren, and A. Westgren, “X-ray Analysis of the Manganese-Rich Side of the Manganese-Silicon Phase Diagram,”Metallwirtschaft, 15, 835–836 (1936) in German. (Equi Diagram, Crys Structure; Experimental)Google Scholar
  6. 60Aro:.
    B. Aronsson, “ANote on the Compositions and Crystal Structures of MnB2, Mn3Si, Mn5Si3, and FeSi2,”Acta Chem. Scand., 14, 1414–1418 (1960). (Crys Structure; Experimental)CrossRefGoogle Scholar
  7. 61Dav:.
    K.N. Davydov, FA Sidorenko, and P.V. Geld, “Martensitic Transformation in Mn3Si,”Fiz. Met. Metalloved., 12(3), 424–430 (1961) in Russian; TR:Phys. Met. Metallogr., 12, 108–113 (1961). (Equi Diagram, Meta Phases, Crys Structure; Experimental)Google Scholar
  8. 61Dud:.
    L.D. Dudkin and E.A. Kuznetsova, “An Investigation of the System Mn-Si in the Silicon-Rich Region,”Dokl. Akad. Nauk SSSR, 141(1), 94–97 (1961) in Russian; TR:Proc. Acad. Sci. USSR, Chem. Sect., 141, 1085–1088 (1961). (Equi Diagram; Experimental; #)Google Scholar
  9. 61Fuj:.
    Y. Fujino, D. Shinoda, S. Asanabe, and Y. Sasaki, “Phase Diagram of the Partial System MnSi-Si,”Jpn. J. Appl. Phys., 3, 431–435 (1961). (Equi Diagram, Crys Structure; Experimental; #)ADSCrossRefGoogle Scholar
  10. 61Kor:.
    V.A. Korshunov, FA Sidorenko, P.V. Geld, and K.N. Davydov, “Phase Components of the System MnSi-Si,”Fiz. Met. Metalloved., 12(2), 277–284 (1961) in Russian; TR:Phys. Met. Metallogr., 12, 101–107 (1961). (Equi Diagram; Experimental)Google Scholar
  11. 62Dud:.
    L.D. Dudkin and E.S. Kuznetsova, “Investigation of the Electrophysical Properties of Alloys Based on Semiconductor Disilicides of Chromium and Manganese,”Poroshk. Metall., 12(6), 20–31 (1962) in Russian; TR:Sov. Powder Metall. Met. Ceram., 6, 418–427 (1962). (Equi Diagram; Experimental)Google Scholar
  12. 62Kuz:.
    Yu.B. Kuzma, “β-Mn-Based Solid Solutions in the Mn-Co(Ni)-Si Ternary Systems,”Russ. J. Inorg. Chem., 7(6), 691–694 (1962). (Equi Diagram; Experimental)Google Scholar
  13. 64Gup:.
    KP. Gupta, “New Phases in the Manganese-Silicon and Iron-Manganese-Silicon Systems,”Trans. Metall. Soc. AIME, 230, 253–254 (1964). (Equi Diagram; Experimental)Google Scholar
  14. 64Kor:.
    V.A. Korshunov and P.V. Geld, “Nature of Defects in the Higher Manganese Silicide Lattice,”Fiz. Met. Metalloved., 17(2), 292–293 (1964) in Russian; TR:Phys. Met. Metallogr., 17(2), 125–126 (1964). (Equi Diagram, Crys Structure; Experimental; #)Google Scholar
  15. 64Euz:.
    Yu.B. Kuzma and E.I. Gladyshevskii, “The Co-Mn-Si System,”Russ. J. Inorg. Chem., 9(3), 373–377 (1964). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  16. 64Sch:.
    O. Schwomma, A Preisinger, H. Nowotny, and A Wittman, “The Crystal Structure of Mn11Si19 and Its Connection with Disilicide-Types,”Monatsh. Chem., 95(6), 1527–1537 (1964) in German. (Crys Structure; Experimental)CrossRefGoogle Scholar
  17. 64Sen:.
    J.P. Senateur and R. Fruchart, “On the Existence of the Silicide Mn5Si2 and Its Relation with Carbides Mn5C2 and Fe5C2,”Compt. Rend., 258, 1524–1525 (1964). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  18. 64Wie:.
    P.F. Wieser and W.D. Forgeng, “Phase Relationships in Manganese-Silicon Alloys Containing from 2 to 24 at.% Si,”Trans. Metall. Soc. AIME, 230, 1675–1681 (1964). (Equi Diagram; Experimental; #)Google Scholar
  19. 65Bar:.
    D.I. Bardos and P.A. Beck, “Notes on the Mn-Si Phase Diagram,”Trans. Metall. Soc. AIME, 233, 1446–1447 (1965). (Equi Diagram; Experimental; #)Google Scholar
  20. 65Gla:.
    E.I. Gladyshevskii, P.I. Kripyakevich, and Ya.P. Yarmolyuk, “Crystal Structures of the Compound Mn6Si,”Izv. Akad. Nauk SSSR, Neorg. Mater, 1(7), 1086–1089 (1965) in Russian; TR:Inorg. Mater, 1(7), 996–999 (1965). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  21. 65Let1:.
    S.M. Letun, P.V. Geld, and N.N. Serebrennikov, “The Thermochemistry of Mn3Si,”Ruas. Metall., 6, 97–103 (1965). (Equi Diagram, Thermo; Experimental)Google Scholar
  22. 65Let2:.
    S.M. Letun and P.V. Geld, “Some Thermodynamic Characteristics of Solid and Liquid Mn5Si3,”Teplofiz. Vys. Temp., 3(1), 47–56 (1965) in Russian; TR:High Temp., 3(1), 39–46 (1965). (Equi Diagram, Crys Structure, Thermo; Experimental)Google Scholar
  23. 66Gel:.
    P.V. Geld, S.M. Letun, and N.N. Serebrennikov, “Thermodynamics of MnSi1.70 Alloys,”Izv. V.U.Z. Chernaya Metall., 12, 5–13 (1966) in Russian. (Crys Structure, Thermo; Experimental)Google Scholar
  24. 66Mor:.
    M.A. Morkhovets, E.I. Elagina, and N.Kh. Abrikosov, “Phase Diagram of the System Mn-Si in the Region of the Higher Manganese Silicide,”zv. Akad. Nauk SSSR, Neorg. Mater., 2(4), 650–656 (1966) in Russian; TR:Inorg. Mater, 2(4), 561–565 (1966). (Equi Diagram; Experimental; #)Google Scholar
  25. 67Kno:.
    H.W. Knott, M.H. Mueller, and L. Heaton, “The Crystal Structure of Mn15Si26,”Acta Crystallogr, 23, 549–555 (1967). (Crys Structure; Experimental)CrossRefGoogle Scholar
  26. 67Lan:.
    G.H. Lander and P.J. Brown, “Electron Density Distribution in the Alloy Mn5Si3,”Philos. Mag., 16, 521–542 (1967). (Crys Structure; Experimental)ADSCrossRefGoogle Scholar
  27. 68Jan1:.
    M. Jancic and L.M. Radonjic, “Kinetics of Formation of New Phases in the System Silicon-Manganese,”Glas Hem. Drust., 33(5-6-7), 397–405 (1968). (Equi Diagram; Experimental)Google Scholar
  28. 68Jan2:.
    M. Jancic and L. Radonjic, “Mechanism of the Formation of New Phases in the Silicon-Manganese System,”Glas Hem. Drust., 33(5-6-7), 367–375 (1968). (Equi Diagram; Experimental)Google Scholar
  29. 69Aks:.
    Yu.N. Akshentsev, BA Baum, and P.V. Geld, “Microheterogeneities in Melts of the Mn-Si System,”Zh. Prikl. Khim., 42(1), 68–73 (1969) in Russian. (Thermo; Experimental)Google Scholar
  30. 70Cer:.
    D. Cerovic and B. Djuric, “Analysis of Diffusion Layers in the Si-Mn System,”Mikrochim. Acta, (Suppl. 4), 96–101 (1970) in German. (Equi Diagram; Experimental)Google Scholar
  31. 70Mag:.
    T. Mager and E. Wachtel, “On the Constitution of the Partial System MnSi-Si,”Z. Metallkd., 61(11), 853–856 (1970) in German. (Equi Diagram; Experimental; #)Google Scholar
  32. 70Nik:.
    E.N. Nikitin, A.F. Sidorov, V.I. Tarasov, and AI. Zaslavskii, “Alloying of Higher Manganese Silicide on the Basis of Microprobe-Analysis Results,”Izv. Akad. Nauk SSSR, Neorg. Mater, 6(3), 604–605 (1970) in Russian; TR:Inorg. Mater, 6(3), 537–538 (1970). (Equi Diagram; Experimental)Google Scholar
  33. 71Rid:.
    R. De Ridder and S. Amelinckx, “The Structure of Defect Manganese Silicides,”Mater. Res. Bull., 6, 1223–1234 (1971). (Equi Diagram, Crys Structure; Experimental)CrossRefGoogle Scholar
  34. 71Ros:.
    S.T. Rostovtsev, S.I. Kuitrik, B.I. Emlin, M.I. Gasik, and A.I. Pogrebnyak, “Activity of the Components in Binary Si-A1, Si-Mn, and Si-Cr Alloys,”Izv. V.U.Z. Chernaya Metall., 2, 61–63 (1971) in Russian. (Thermo; Experimental)Google Scholar
  35. 71Sho:.
    C.B. Shoemaker and D.P. Shoemaker “The Crystal Structure of the v Phase, Mn81.5Si18.5,”Acta Crystallogr B., 27, 227–235 (1971). (Crys Structure; Experimental)CrossRefGoogle Scholar
  36. 72Abr:.
    N.Kh. Abrikosov, L.D. Ivanova, and V.G. Muravev, “Preparation and Investigation of Single Crystals of Solid Solutions of Manganic Silicides with Ge and CrSi2,”Izv. Akad. Nauk SSSR, Neorg. Mater, 8(1), 1194–1200 (1972) in Russian; TR:Inorg. Mater., 8(1), 1049–1054 (1972). (Equi Diagram; Experimental)Google Scholar
  37. 72Bur:.
    B.P. Burylev, I.T. Sryvalin, and A.V. Stepanov, “Analysis of the Conservation Dependence of the Heats of Mixing of Iron and Manganese with Silicon,”Izv. V. U.Z. Chernaya Metall., 4, 9–11 (1972) in Russian. (Thermo; Experimental)Google Scholar
  38. 73Zwi:.
    G. Zwilling and H. Nowotny, “The Crystal Structure of the Defect Manganese Silicides, Mn27Si47,”Monatsh. Chem., 104, 668–675 (1973). (Crys Structure; Experimental)CrossRefGoogle Scholar
  39. 74Bab:.
    E.M. Babanova and Yu.A. Vereshchagin, “Homogeneity Region of a Trimanganese-Based Silicide,”Tr. Ural. Politekh. Inst., 231, 15–16 (1974) in Russian. (Equi Diagram, Crys Structure; Experimental)Google Scholar
  40. 74Bat:.
    G.I. Batalin and VS. Sudavtsova, “Thermodynamic Properties of Molten Manganese-Silicon Alloys,”Ukr. Khim. Zh., 40(5), 542–543 (1974) in Ukrainian; TR:Ukr. J. Chem., 40(5), 88–89 (1974). (Thermo; Experimental)Google Scholar
  41. 74Kal:.
    G.I. Kalishevich, YuA Vereshchagin, and P.V. Geld, “Low Temperature Phase Transformation in Mn3Si,”Sov. Phys. Solid State, 16(6), 1151 (1974). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  42. 74Pet:.
    M.S. Petrushevskii, Yu.O. Esin, and Yu.V. Gorbanov, “Enthalpy of Formation and Short Range Structure of Molten Alloys of Mn with Si, Ge, and Sn,”Dokl. Akad. Nauk SSSR, 217(5), 1114–1117 (1974) in Russian. (Thermo; Experimental)Google Scholar
  43. 74Pol:.
    A.F. Polesya and V.N. Gudzenko, “Metastable Phases in the Mn-Si System,”Izv. Akad. Nauk SSSR, Neorg. Mater., 10(6), 1011–1015 (1974) in Russian; TR:Inorg. Mater., 10(6), 869–872 (1974). (Meta Phases, Crys Structure; Experimental; #)Google Scholar
  44. 75Bat:.
    G.I. Batalin and VS. Sudavtsova, “Thermodynamic Properties of Melts of the System Mn-Si,”Izv. Akad. Nauk SSSR, Neorg. Mater, 11(10), 1782–1787 (1975) in Russian; TR:Inorg. Mater, 11(10), 1527–1531 (1975). (Thermo; Experimental)Google Scholar
  45. 75Esi:.
    Yu.O. Esin, Y.V. Gorbunov, M.S. Petruslievskii andP.V. Geld, “Enthalpy of Formation of Liquid Alloys of Mn with Si,”Izv. V.U.Z. Chernaya Metall., 2, 8–11 (1975) in Russian. (Thermo; Experimental)Google Scholar
  46. 75Gel:.
    P.V. Geld, P.V. Kocherov, B.A. Baum, V.M. Zamyatin, M.S. Petrushevskii, and G.V. Tyagunov, “Thermodynamic Characteristics of Manganese-SiliconMolten Alloys,”V. Sb. Termodin. Svoistva Metal. Splavov., 143–146 (1975) in Russian. (Thermo; Experimental)Google Scholar
  47. 76Sho:.
    C.B. Shoemaker and D.P. Shoemaker, “The Crystal Structure of Mn5Si2 and the D Phase (V-Fe-Si),”Acta Crystallogr. B, 32, 2306–2313 (1976). (Crys Structure; Experimental)CrossRefGoogle Scholar
  48. 77Bar:.
    I. Barin, O. Knacke, and O. Kubaschewski,Thermochemical Properties of Inorganic Substances (Supplement), Springer-Verlag, New York (1977). (Thermo; Compilation)CrossRefGoogle Scholar
  49. 77Sud:.
    V.S. Sudavtsova and G.I. Batalin, “Calculation of the Activities of the Components of Molten Metal-Si Alloys from the Phase Diagram,”Ukr. Khim. Zh., 43(3), 235–240 (1977) in Ukrainian; TR:Ukr. J. Chem., 43(3), 10–14 (1977). (Thermo; Theory)Google Scholar
  50. 77Tan:.
    A. Tanaka, “Determination of the Activities in Mn-C, Mn-Si, Mn-SiCSat; and Mn-Fe-Si-CSat. Solutions by Vapor Pressure Measurement,”J. Jpn. Inst. Met., 41(6), 601–607 (1977) in Japanese. (Thermo; Experimental)Google Scholar
  51. 78Sho:.
    C.B. Shoemaker and D.P. Shoemaker, “Refinement of an R Phase, Mn85.5Si14.5,”Acta Crystallogr. B, 34, 701–705 (1978). (Crys Structure; Experimental)CrossRefGoogle Scholar
  52. 79Mas:.
    K. Masumoto, I. Kawasumi, and M. Sakata, “Phase Analysis and Crystal Structure of Manganese-Silicon Alloys with Compositions Near Manganese Silicide MnSi1.73,”Nippon Kinzoku Gakkai-shi, 43(11), 1013–1019 (1979) in Japanese. (Crys Structure; Experimental)Google Scholar
  53. 79Tan:.
    A. Tanaka, “The Determination of the Activities in Mn-C and Mn-Si Melts by the Vapor Pressure Method,”Trans. Jpn. Inst. Met., 20, 516–522 (1979). (Thermo; Experimental)CrossRefGoogle Scholar
  54. 81Luk:.
    G.M. Lukashenko, V.R. Sidorko, and B.Ya. Kotur, “Phase Composition and Thermodynamic Properties of Alloys of the Manganese-Silicon System in the 25 to 37.5 at.% Silicon Range,”Poroshk.. Metall., 8, 67–70 (1981) in Russian. (Thermo; Experimental)Google Scholar
  55. 82Luk:.
    G.M. Lukashenko and V.R. Sidorko, “Thermodynamic Properties of Manganese-Silicon System Alloys in the Region MngSi2 and Mn6Si,”Poroshk. Metall., 7, 67–70 (1982) in Russian. (Equi Diagram, Thermo; Experimental)Google Scholar
  56. 89Gok:.
    N.A. Gokcen, “The Phase Transformations in Mn,”Bull. Alloy Phase Diagrams, 10(4), 313 (1989). (Equi Diagram; Compilation).CrossRefGoogle Scholar

Copyright information

© ASM International 1990

Authors and Affiliations

  • A. B. Gokhale
    • 1
  • R. Abbaschian
    • 1
  1. 1.Department of Materials Science and EngineeringUniversity of FloridaGainesville

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