Advertisement

Journal of Phase Equilibria

, Volume 11, Issue 5, pp 468–480 | Cite as

The Mn-Si (Manganese-Silicon) system

  • A. B. Gokhale
  • R. Abbaschian
Alloy Phase Diagram Evaluations

Keywords

Equi Diagram Alloy Phase Diagram Crys Structure Homogeneity Range Excess Entropy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Cited references

  1. 06Doe:.
    F. Doerinckel, “On the Compounds of Manganese with Silicon,”Z. Anorg. Chem., 50, 117–132 (1906) in German. (Equi Diagram; Experimental; #)CrossRefGoogle Scholar
  2. 25Wes:.
    A. Westgren and G. Phragmen, “On the Crystal Structure Forms of Manganese,”Z. Phys., 33, 787–788 (1925) in German. (Equi Diagram, Crys Structure; Experimental)ADSCrossRefGoogle Scholar
  3. 33Bor:.
    B. Boren, “X-ray Investigation of Alloys of Silicon with Chromium, Manganese, Cobolt, and Nickel,”Ark. Kern., Miner. Geol., 11A(10), 1–28 (1933) in German. (Equi Diagram, Crys Structure; Experimental)Google Scholar
  4. 33Vog:.
    R. Vogel and H. Bedarff, “The State Diagram of Manganese-Silicon,”Arch. Eisenhüttenwes., 7, 423–425 (1933-34) in German. (Equi Diagram; Experimental; #)Google Scholar
  5. 36Ama:.
    K Amark, B. Boren, and A. Westgren, “X-ray Analysis of the Manganese-Rich Side of the Manganese-Silicon Phase Diagram,”Metallwirtschaft, 15, 835–836 (1936) in German. (Equi Diagram, Crys Structure; Experimental)Google Scholar
  6. 60Aro:.
    B. Aronsson, “ANote on the Compositions and Crystal Structures of MnB2, Mn3Si, Mn5Si3, and FeSi2,”Acta Chem. Scand., 14, 1414–1418 (1960). (Crys Structure; Experimental)CrossRefGoogle Scholar
  7. 61Dav:.
    K.N. Davydov, FA Sidorenko, and P.V. Geld, “Martensitic Transformation in Mn3Si,”Fiz. Met. Metalloved., 12(3), 424–430 (1961) in Russian; TR:Phys. Met. Metallogr., 12, 108–113 (1961). (Equi Diagram, Meta Phases, Crys Structure; Experimental)Google Scholar
  8. 61Dud:.
    L.D. Dudkin and E.A. Kuznetsova, “An Investigation of the System Mn-Si in the Silicon-Rich Region,”Dokl. Akad. Nauk SSSR, 141(1), 94–97 (1961) in Russian; TR:Proc. Acad. Sci. USSR, Chem. Sect., 141, 1085–1088 (1961). (Equi Diagram; Experimental; #)Google Scholar
  9. 61Fuj:.
    Y. Fujino, D. Shinoda, S. Asanabe, and Y. Sasaki, “Phase Diagram of the Partial System MnSi-Si,”Jpn. J. Appl. Phys., 3, 431–435 (1961). (Equi Diagram, Crys Structure; Experimental; #)ADSCrossRefGoogle Scholar
  10. 61Kor:.
    V.A. Korshunov, FA Sidorenko, P.V. Geld, and K.N. Davydov, “Phase Components of the System MnSi-Si,”Fiz. Met. Metalloved., 12(2), 277–284 (1961) in Russian; TR:Phys. Met. Metallogr., 12, 101–107 (1961). (Equi Diagram; Experimental)Google Scholar
  11. 62Dud:.
    L.D. Dudkin and E.S. Kuznetsova, “Investigation of the Electrophysical Properties of Alloys Based on Semiconductor Disilicides of Chromium and Manganese,”Poroshk. Metall., 12(6), 20–31 (1962) in Russian; TR:Sov. Powder Metall. Met. Ceram., 6, 418–427 (1962). (Equi Diagram; Experimental)Google Scholar
  12. 62Kuz:.
    Yu.B. Kuzma, “β-Mn-Based Solid Solutions in the Mn-Co(Ni)-Si Ternary Systems,”Russ. J. Inorg. Chem., 7(6), 691–694 (1962). (Equi Diagram; Experimental)Google Scholar
  13. 64Gup:.
    KP. Gupta, “New Phases in the Manganese-Silicon and Iron-Manganese-Silicon Systems,”Trans. Metall. Soc. AIME, 230, 253–254 (1964). (Equi Diagram; Experimental)Google Scholar
  14. 64Kor:.
    V.A. Korshunov and P.V. Geld, “Nature of Defects in the Higher Manganese Silicide Lattice,”Fiz. Met. Metalloved., 17(2), 292–293 (1964) in Russian; TR:Phys. Met. Metallogr., 17(2), 125–126 (1964). (Equi Diagram, Crys Structure; Experimental; #)Google Scholar
  15. 64Euz:.
    Yu.B. Kuzma and E.I. Gladyshevskii, “The Co-Mn-Si System,”Russ. J. Inorg. Chem., 9(3), 373–377 (1964). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  16. 64Sch:.
    O. Schwomma, A Preisinger, H. Nowotny, and A Wittman, “The Crystal Structure of Mn11Si19 and Its Connection with Disilicide-Types,”Monatsh. Chem., 95(6), 1527–1537 (1964) in German. (Crys Structure; Experimental)CrossRefGoogle Scholar
  17. 64Sen:.
    J.P. Senateur and R. Fruchart, “On the Existence of the Silicide Mn5Si2 and Its Relation with Carbides Mn5C2 and Fe5C2,”Compt. Rend., 258, 1524–1525 (1964). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  18. 64Wie:.
    P.F. Wieser and W.D. Forgeng, “Phase Relationships in Manganese-Silicon Alloys Containing from 2 to 24 at.% Si,”Trans. Metall. Soc. AIME, 230, 1675–1681 (1964). (Equi Diagram; Experimental; #)Google Scholar
  19. 65Bar:.
    D.I. Bardos and P.A. Beck, “Notes on the Mn-Si Phase Diagram,”Trans. Metall. Soc. AIME, 233, 1446–1447 (1965). (Equi Diagram; Experimental; #)Google Scholar
  20. 65Gla:.
    E.I. Gladyshevskii, P.I. Kripyakevich, and Ya.P. Yarmolyuk, “Crystal Structures of the Compound Mn6Si,”Izv. Akad. Nauk SSSR, Neorg. Mater, 1(7), 1086–1089 (1965) in Russian; TR:Inorg. Mater, 1(7), 996–999 (1965). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  21. 65Let1:.
    S.M. Letun, P.V. Geld, and N.N. Serebrennikov, “The Thermochemistry of Mn3Si,”Ruas. Metall., 6, 97–103 (1965). (Equi Diagram, Thermo; Experimental)Google Scholar
  22. 65Let2:.
    S.M. Letun and P.V. Geld, “Some Thermodynamic Characteristics of Solid and Liquid Mn5Si3,”Teplofiz. Vys. Temp., 3(1), 47–56 (1965) in Russian; TR:High Temp., 3(1), 39–46 (1965). (Equi Diagram, Crys Structure, Thermo; Experimental)Google Scholar
  23. 66Gel:.
    P.V. Geld, S.M. Letun, and N.N. Serebrennikov, “Thermodynamics of MnSi1.70 Alloys,”Izv. V.U.Z. Chernaya Metall., 12, 5–13 (1966) in Russian. (Crys Structure, Thermo; Experimental)Google Scholar
  24. 66Mor:.
    M.A. Morkhovets, E.I. Elagina, and N.Kh. Abrikosov, “Phase Diagram of the System Mn-Si in the Region of the Higher Manganese Silicide,”zv. Akad. Nauk SSSR, Neorg. Mater., 2(4), 650–656 (1966) in Russian; TR:Inorg. Mater, 2(4), 561–565 (1966). (Equi Diagram; Experimental; #)Google Scholar
  25. 67Kno:.
    H.W. Knott, M.H. Mueller, and L. Heaton, “The Crystal Structure of Mn15Si26,”Acta Crystallogr, 23, 549–555 (1967). (Crys Structure; Experimental)CrossRefGoogle Scholar
  26. 67Lan:.
    G.H. Lander and P.J. Brown, “Electron Density Distribution in the Alloy Mn5Si3,”Philos. Mag., 16, 521–542 (1967). (Crys Structure; Experimental)ADSCrossRefGoogle Scholar
  27. 68Jan1:.
    M. Jancic and L.M. Radonjic, “Kinetics of Formation of New Phases in the System Silicon-Manganese,”Glas Hem. Drust., 33(5-6-7), 397–405 (1968). (Equi Diagram; Experimental)Google Scholar
  28. 68Jan2:.
    M. Jancic and L. Radonjic, “Mechanism of the Formation of New Phases in the Silicon-Manganese System,”Glas Hem. Drust., 33(5-6-7), 367–375 (1968). (Equi Diagram; Experimental)Google Scholar
  29. 69Aks:.
    Yu.N. Akshentsev, BA Baum, and P.V. Geld, “Microheterogeneities in Melts of the Mn-Si System,”Zh. Prikl. Khim., 42(1), 68–73 (1969) in Russian. (Thermo; Experimental)Google Scholar
  30. 70Cer:.
    D. Cerovic and B. Djuric, “Analysis of Diffusion Layers in the Si-Mn System,”Mikrochim. Acta, (Suppl. 4), 96–101 (1970) in German. (Equi Diagram; Experimental)Google Scholar
  31. 70Mag:.
    T. Mager and E. Wachtel, “On the Constitution of the Partial System MnSi-Si,”Z. Metallkd., 61(11), 853–856 (1970) in German. (Equi Diagram; Experimental; #)Google Scholar
  32. 70Nik:.
    E.N. Nikitin, A.F. Sidorov, V.I. Tarasov, and AI. Zaslavskii, “Alloying of Higher Manganese Silicide on the Basis of Microprobe-Analysis Results,”Izv. Akad. Nauk SSSR, Neorg. Mater, 6(3), 604–605 (1970) in Russian; TR:Inorg. Mater, 6(3), 537–538 (1970). (Equi Diagram; Experimental)Google Scholar
  33. 71Rid:.
    R. De Ridder and S. Amelinckx, “The Structure of Defect Manganese Silicides,”Mater. Res. Bull., 6, 1223–1234 (1971). (Equi Diagram, Crys Structure; Experimental)CrossRefGoogle Scholar
  34. 71Ros:.
    S.T. Rostovtsev, S.I. Kuitrik, B.I. Emlin, M.I. Gasik, and A.I. Pogrebnyak, “Activity of the Components in Binary Si-A1, Si-Mn, and Si-Cr Alloys,”Izv. V.U.Z. Chernaya Metall., 2, 61–63 (1971) in Russian. (Thermo; Experimental)Google Scholar
  35. 71Sho:.
    C.B. Shoemaker and D.P. Shoemaker “The Crystal Structure of the v Phase, Mn81.5Si18.5,”Acta Crystallogr B., 27, 227–235 (1971). (Crys Structure; Experimental)CrossRefGoogle Scholar
  36. 72Abr:.
    N.Kh. Abrikosov, L.D. Ivanova, and V.G. Muravev, “Preparation and Investigation of Single Crystals of Solid Solutions of Manganic Silicides with Ge and CrSi2,”Izv. Akad. Nauk SSSR, Neorg. Mater, 8(1), 1194–1200 (1972) in Russian; TR:Inorg. Mater., 8(1), 1049–1054 (1972). (Equi Diagram; Experimental)Google Scholar
  37. 72Bur:.
    B.P. Burylev, I.T. Sryvalin, and A.V. Stepanov, “Analysis of the Conservation Dependence of the Heats of Mixing of Iron and Manganese with Silicon,”Izv. V. U.Z. Chernaya Metall., 4, 9–11 (1972) in Russian. (Thermo; Experimental)Google Scholar
  38. 73Zwi:.
    G. Zwilling and H. Nowotny, “The Crystal Structure of the Defect Manganese Silicides, Mn27Si47,”Monatsh. Chem., 104, 668–675 (1973). (Crys Structure; Experimental)CrossRefGoogle Scholar
  39. 74Bab:.
    E.M. Babanova and Yu.A. Vereshchagin, “Homogeneity Region of a Trimanganese-Based Silicide,”Tr. Ural. Politekh. Inst., 231, 15–16 (1974) in Russian. (Equi Diagram, Crys Structure; Experimental)Google Scholar
  40. 74Bat:.
    G.I. Batalin and VS. Sudavtsova, “Thermodynamic Properties of Molten Manganese-Silicon Alloys,”Ukr. Khim. Zh., 40(5), 542–543 (1974) in Ukrainian; TR:Ukr. J. Chem., 40(5), 88–89 (1974). (Thermo; Experimental)Google Scholar
  41. 74Kal:.
    G.I. Kalishevich, YuA Vereshchagin, and P.V. Geld, “Low Temperature Phase Transformation in Mn3Si,”Sov. Phys. Solid State, 16(6), 1151 (1974). (Equi Diagram, Crys Structure; Experimental)Google Scholar
  42. 74Pet:.
    M.S. Petrushevskii, Yu.O. Esin, and Yu.V. Gorbanov, “Enthalpy of Formation and Short Range Structure of Molten Alloys of Mn with Si, Ge, and Sn,”Dokl. Akad. Nauk SSSR, 217(5), 1114–1117 (1974) in Russian. (Thermo; Experimental)Google Scholar
  43. 74Pol:.
    A.F. Polesya and V.N. Gudzenko, “Metastable Phases in the Mn-Si System,”Izv. Akad. Nauk SSSR, Neorg. Mater., 10(6), 1011–1015 (1974) in Russian; TR:Inorg. Mater., 10(6), 869–872 (1974). (Meta Phases, Crys Structure; Experimental; #)Google Scholar
  44. 75Bat:.
    G.I. Batalin and VS. Sudavtsova, “Thermodynamic Properties of Melts of the System Mn-Si,”Izv. Akad. Nauk SSSR, Neorg. Mater, 11(10), 1782–1787 (1975) in Russian; TR:Inorg. Mater, 11(10), 1527–1531 (1975). (Thermo; Experimental)Google Scholar
  45. 75Esi:.
    Yu.O. Esin, Y.V. Gorbunov, M.S. Petruslievskii andP.V. Geld, “Enthalpy of Formation of Liquid Alloys of Mn with Si,”Izv. V.U.Z. Chernaya Metall., 2, 8–11 (1975) in Russian. (Thermo; Experimental)Google Scholar
  46. 75Gel:.
    P.V. Geld, P.V. Kocherov, B.A. Baum, V.M. Zamyatin, M.S. Petrushevskii, and G.V. Tyagunov, “Thermodynamic Characteristics of Manganese-SiliconMolten Alloys,”V. Sb. Termodin. Svoistva Metal. Splavov., 143–146 (1975) in Russian. (Thermo; Experimental)Google Scholar
  47. 76Sho:.
    C.B. Shoemaker and D.P. Shoemaker, “The Crystal Structure of Mn5Si2 and the D Phase (V-Fe-Si),”Acta Crystallogr. B, 32, 2306–2313 (1976). (Crys Structure; Experimental)CrossRefGoogle Scholar
  48. 77Bar:.
    I. Barin, O. Knacke, and O. Kubaschewski,Thermochemical Properties of Inorganic Substances (Supplement), Springer-Verlag, New York (1977). (Thermo; Compilation)CrossRefGoogle Scholar
  49. 77Sud:.
    V.S. Sudavtsova and G.I. Batalin, “Calculation of the Activities of the Components of Molten Metal-Si Alloys from the Phase Diagram,”Ukr. Khim. Zh., 43(3), 235–240 (1977) in Ukrainian; TR:Ukr. J. Chem., 43(3), 10–14 (1977). (Thermo; Theory)Google Scholar
  50. 77Tan:.
    A. Tanaka, “Determination of the Activities in Mn-C, Mn-Si, Mn-SiCSat; and Mn-Fe-Si-CSat. Solutions by Vapor Pressure Measurement,”J. Jpn. Inst. Met., 41(6), 601–607 (1977) in Japanese. (Thermo; Experimental)Google Scholar
  51. 78Sho:.
    C.B. Shoemaker and D.P. Shoemaker, “Refinement of an R Phase, Mn85.5Si14.5,”Acta Crystallogr. B, 34, 701–705 (1978). (Crys Structure; Experimental)CrossRefGoogle Scholar
  52. 79Mas:.
    K. Masumoto, I. Kawasumi, and M. Sakata, “Phase Analysis and Crystal Structure of Manganese-Silicon Alloys with Compositions Near Manganese Silicide MnSi1.73,”Nippon Kinzoku Gakkai-shi, 43(11), 1013–1019 (1979) in Japanese. (Crys Structure; Experimental)Google Scholar
  53. 79Tan:.
    A. Tanaka, “The Determination of the Activities in Mn-C and Mn-Si Melts by the Vapor Pressure Method,”Trans. Jpn. Inst. Met., 20, 516–522 (1979). (Thermo; Experimental)CrossRefGoogle Scholar
  54. 81Luk:.
    G.M. Lukashenko, V.R. Sidorko, and B.Ya. Kotur, “Phase Composition and Thermodynamic Properties of Alloys of the Manganese-Silicon System in the 25 to 37.5 at.% Silicon Range,”Poroshk.. Metall., 8, 67–70 (1981) in Russian. (Thermo; Experimental)Google Scholar
  55. 82Luk:.
    G.M. Lukashenko and V.R. Sidorko, “Thermodynamic Properties of Manganese-Silicon System Alloys in the Region MngSi2 and Mn6Si,”Poroshk. Metall., 7, 67–70 (1982) in Russian. (Equi Diagram, Thermo; Experimental)Google Scholar
  56. 89Gok:.
    N.A. Gokcen, “The Phase Transformations in Mn,”Bull. Alloy Phase Diagrams, 10(4), 313 (1989). (Equi Diagram; Compilation).CrossRefGoogle Scholar

Copyright information

© ASM International 1990

Authors and Affiliations

  • A. B. Gokhale
    • 1
  • R. Abbaschian
    • 1
  1. 1.Department of Materials Science and EngineeringUniversity of FloridaGainesville

Personalised recommendations