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Bulletin of Alloy Phase Diagrams

, Volume 10, Issue 1, pp 11–22 | Cite as

The As (Arsenic) system

  • N. A. Gokcen
Alloy Diagram Evaluations As

Keywords

Arsenic Heat Capacity Gibbs Energy Equi Diagram Alloy Phase Diagram 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Cited References

  1. 09Jon: W.P.A. Jonker, “The Sublimation of Arsenic,”Chem. Weekblad, 5, 783–785 (1909) in German. (Equi Diagram; Experimental)Google Scholar
  2. 11Gib: G.E. Gibson, dissertation, Univ. Breslau (1911) in German; reported in [23LBT]. (Thermo; Experimental)Google Scholar
  3. 12Pre: G. Preuner and J. Brockmoller, “Measurements of Gas Pressure with a Spiral Manometer of Vitreous Silica,”Z. Phys. Chem., 81, 129–170 (1912) in German. (Thermo; Experimental)Google Scholar
  4. Indicates key paper 14Gou: M.R. Goubau, “On the Melting Point of Arsenic,”C.R. Acad. Sci., 158, Pt. 1, 121–122 (1914) in French. (Equi Diagram)Google Scholar
  5. 19Ruf: O. Ruff and B. Bergdahl, “Researches at High Temperatures. XII. The Measurement of Vapor Pressure at Very High Pressures and the Solubility of Carbon in Metals,”Z. Anorg. Allg. Chem., 106, 76–94 (1919) in German. (Thermo; Experimental)CrossRefGoogle Scholar
  6. Indicates key paper 20Ras: H. Rassow, “A Simple Method for Determination of Melting Points and Critical Temperatures,”Z. Anorg. Allg. Chem., 114, 117–150 (1920) in German. (Equi Diagram)CrossRefGoogle Scholar
  7. 21Hei: W. Heike “A Simple Method for the Determination of Melting Points and Critical Temperatures,”Z. Anorg. Allg. Chem., 118, 254 (1921) in German. (Equi Diagram)CrossRefGoogle Scholar
  8. 21Ruf: O. Russ and S. Mugdan, “High Temperature Studies. XIII. The Measurement of Vapor Pressures at High Temperatures and the Vapor Pressure of Alkali Halides,”Z. Anorg. Allg. Chem., 117, 147–171, (1921) in German. (Thermo; Experimental)CrossRefGoogle Scholar
  9. 22Las: P.N. Lashchtschenko, “Polymorphism of Arsenic,”J. Chem. Soc. (London), 121, 972–978 (1922). (Equi Diagram, Thermo; Experimental)Google Scholar
  10. Indicates key paper 23Hor: S. Horiba, “Determination of Vapor Pressures of Metallic Arsenic,”Z. Phys. Chem., 106, 295–302 (1923) in German; Also inProc. Acad. Sci. Amsterdam, 25, 387–394 (1923) in German. (Equi Diagram, Thermo; Experimental)Google Scholar
  11. 23LBT: Landoh Bornstein Tabeuen, Vol. 2, Springer, Berlin, 1332 (1923) in German. (Thermo; Compilation)Google Scholar
  12. 30And: C.T. Anderson, “The Heat Capacities of Arsenic, Arsenic Trioxide, and Arsenic Pentoxide at Low Temperatures,”J. Am. Chem. Soc., 52, 2296–3000 (1930). (Thermo; Experimental)CrossRefGoogle Scholar
  13. Indicates key paper 37Kin: G.D. Kinzer and G.M. Almy, “The Emission Spectrum of Diatomic Arsenic. II,”Phys. Rev., 52, 814–821 (1937). (Thermo; Experimental)CrossRefADSGoogle Scholar
  14. 38Wie: F. Wiechmann, M. Heimburg, and W. Biltz “The Affinity of Rhenium for Arsenic,”Z. Anorg. Allg. Chem., 240, 129–138 368 (1938) in German. (Thermo; Experimental)CrossRefGoogle Scholar
  15. 55Bre: L. Brewer and J.S. Kane, “The Importance of Complex Gaseous Molecules in High Temperature Systems,”J. Phys. Chem., 59, 105–109 (1955). (Thermo; Experimental)CrossRefGoogle Scholar
  16. 58Dro: J. Drowart and P. Goldfinger, “Thermodynamic Study of Group III–V and Group II–VI Compounds by Mass Spectrometry,”J. Chem. Phys., 55, 721–732 (1958). (Thermo; Experimental)Google Scholar
  17. 59Gol: P. Goldfinger and M. Jeunehomme, “Mass Spectrometric Studies of the Thermodynamic Properties of Group III–IV and II–VI Compounds,”Advances in Mass Spectroscopy, J.D. Waldron, Ed., Pergamon Press, London, 534–546 (1959). (Thermo; Experimental)Google Scholar
  18. 59Gut: H.B. Gutbier, “Mass Spectrometric Investigation of Processes During the Evaporation of Indium Arsenide,”Z. Naturforsch. A, 142, 32–36 (1959). (Thermo; Experimental)ADSGoogle Scholar
  19. 60Kel: K.K. Kelley, “Contribution to the Data on Theoretical Metallurgy,” U.S. Bur. Mines Bull. No. 584, 18 (1960). (Thermo; Compilation)Google Scholar
  20. Indicates key paper 60Kle: W. Klemm, H. Spitzer, and H. Niermann, “Investigations on Some Metalloids,”Angew. Chem., 72, 985–994 (1960) in German. (Equi Diagram, Thermo; Experimental)CrossRefGoogle Scholar
  21. 61Gut: H.B. Gutbier, “Mass-Spectrometric Investigation of the Evaporation Coefficient of Compounds with Zinc Blende Structure in the Temperature Region Around 1000 K,”Z. Naturforsch. A, 16, 268–279 (1961) in German. (Thermo; Experimental)ADSGoogle Scholar
  22. 61Str: B.A. Strathdee and L.M. Pidgeon, “Thermal Decomposition and Vapor-Pressure Measurements on Arsenopyrite and an Arsenic Ore,”Trans. Can. Inst. Min. Metall., 64, 506–510 (1961). (Thermo; Experimental)Google Scholar
  23. Indicates key paper 63Kle: W. Klement, Jr., A. Jayaraman, and G.C. Kennedy, “Phase Diagrams of Arsenic, Antimony and Bismuth at Pressures up to 70 Kilobars,”Phys. Rev., 131, 632–637 (1963). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  24. 63Mcg: P.J. McGonigal and A.V. Grosse, “The Density of Liquid Arsenic and the Density of Its Saturated Vapor,”J. Phys. Chem., 67, 924–925 (1963). (Equi Diagram; Experimental)CrossRefGoogle Scholar
  25. 63Nes: A.N. Nesmeyanov,Vapour Pressure of the Elements, J.I. Carasso, Ed., Academic Press, New York, 301–302 (1963). (Thermo; Compilation)Google Scholar
  26. Indicates key paper 64Hil: J. Hilsenrath, C.G. Messina, and W.H. Evans, “Ideal Gas Thermodynamic Functions for 73 Atoms and Their First and Second Ions to 10,000 K,” Air Force Weapons Lab. Rep. No. TDR-64-64, Kirtland Air Force Base, NM, 441 p (1964). (Thermo; Compilation)Google Scholar
  27. 64Wes: J.B. Westmore, K.H. Mann, and A.W. Tickner, “Mass Spectrometric Study of the Nonstoichiometric Vaporization of Cadmium Arsenide,”J. Phys. Chem., 68, 606–612 (1964). (Thermo; Experimental)CrossRefGoogle Scholar
  28. Indicates key paper 65Cha: P.E. Chaney and S.E. Babb, Jr., “Melting Curves of Tellurium and Arsenic,”J. Chem. Phys., 43, 1071 (1965). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  29. 65Tay: J.B. Taylor, S.L. Bennett, and R.D. Heyding, “Physical Properties of α- and γ-Arsenic,”J. Phys. Chem. Solids, 26, 69–74 (1965). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  30. 66Ben: S.L. Bennett and R.D. Heyding, “The Transformation of γ-to α-Arsenic and the Susceptibility of Polycrystal-line Arsenic,”J. Phys. Chem. Solids, 27, 471–472 (1966). (Meta Phases; Experimental)CrossRefADSGoogle Scholar
  31. Indicates key paper 66Nog: V.V. Nogteva, I.E. Paukov, and P.G. Strelkov, “Heat Capacity of Metallic Arsenic at Low Temperatures,”Sov. Phys. Solid State, 7(8), 1884–1886 (1966). (Thermo; Experimental)Google Scholar
  32. 67Art: J.R. Arthur, “Vapor Pressures and Phase Equilibrium in the Gallium-Arsenic System,”J. Phys. Chem. Solids, 28, 2257–2267 (1967). (Thermo; Experimental)CrossRefADSGoogle Scholar
  33. Indicates key paper 67Cul: H.V. Culbert, “Low-Temperature Specific Heat of Arsenic and Antimony,”Phys. Rev., 157, 560–563 (1967). (Thermo; Experimental)CrossRefADSGoogle Scholar
  34. 68Her: C.C. Herrick and R.C. Feber, “Vaporization Studies on Arsenic,”J. Phys. Chem., 72, 1102–1110 (1968). (Thermo; Experimental)CrossRefGoogle Scholar
  35. Indicates key paper 68Per: P. Perdigon, J. D’Incan, and J. Jeanin, “New High-Resolution Analysis of Several Bands of thed»X System of the As2 Molecule,”C.R. Acad. Sci. Paris, A, B, 267(3), 202–204 (1968) in French. (Thermo; Experimental)Google Scholar
  36. 68Ros: G.M. Rosenblatt and P.K. Lee, “Rate of Vaporization of Arsenic Single Crystals and the Vaporization Coefficient of Arsenic,”J. Chem. Phys., 49, 2995–3006 (1968). (Thermo; Experimental)CrossRefADSGoogle Scholar
  37. 69Ber: I.V. Berman and N.B. Brandt, “Superconductivity of Arsenic at High Pressures,”Zh. Eksp. Teor. Fiz. Pis’ma, 10(2), 89–91 (1969) in Russian. (Equi Diagram)ADSGoogle Scholar
  38. 69Hud: J.E. Hudson, “Electron Impact Studies of Arsenic and Antimony Vapors,” dissertation Pennsylvania State University, University Park, PA, 105 (1969). (Thermo; Experimental)Google Scholar
  39. 69Ozi: G.A. Ozin, “Gas-Phase Raman Spectroscopy of Phosphorus, Arsenic, and Saturated Sulfur Vapours,”J. Chem. Soc. D, (22), 1325–1327 (1969). (Thermo; Experimental)CrossRefGoogle Scholar
  40. Indicates key paper 69Pau: I.E. Paukov, V.V. Nogteva, and P.G. Strelkov, “The True Heat Capacity of Crystalline Black Phosphorous and Metallic Arsenic in the Temperature Range 13-300 K,”Russ. J. Phys. Chem., 43(6), 773–774 (1969). (Thermo; Experimental)Google Scholar
  41. 69Per: P. Perdigon, J. D’Incan, and J. Sfeila, “Analysis of the Rotational Structure of Several Bands ofd»X andB»X Systems of the As2 Molecule,”C. R. Acad. Sci. Paris, A, B, 268B(22), 1432–1435 (1969) in French. (Thermo; Experimental)Google Scholar
  42. Indicates key paper 69Sch: D. Schiferl and C.S. Barrett, “The Crystal Structure of Arsenic at 4.2, 78, and 229K,”J. Appl. Crystallogr., 2, 30–36 (1969). (Equi Diagram)CrossRefGoogle Scholar
  43. 70Cap: R.J. Capwell and G.M. Rosenblatt, “Infrared Spectrum of Condensed As4 and Thermodynamic Functions of As4 Gas,”J. Molec. Spectrosc., 33, 525–530 (1970). (Thermo; Experimental)CrossRefADSGoogle Scholar
  44. 70Dem: G.L. DeMaria, L. Malaspina, and V. Piacente, “Mass Spectroscopic Study of Gallium Arsenide System,”J. Chem. Phys., 52, 1019–1024 (1970). (Thermo; Experimental)CrossRefADSGoogle Scholar
  45. Indicates key paper 70Per: P. Perdigon, J. D’Incan, and J. Janin, “Electronic Spectrum of As2 Molecule,”Can. J. Phys., 48(10), 1140–1150 (1970) in French. (Thermo; Experimental)ADSGoogle Scholar
  46. 70Ros: G.M. Rosenblatt, “Vaporization Mechanism at Elevated Temperatures,”Heterogeneous Kinetics at Elevated Temperatures, G.R. Belton, Ed., Plenum Press, New York, 209–229 (1970). (Thermo; Review)Google Scholar
  47. 71Mal: L. Malaspina, R. Gigli and G. Bardi, “Determination of Thermodynamic Parameters by a Calvet-Microcalorimeter for High Temperatures,”Calore, 42, 317–326 (1971) in Italian. (Thermo; Experimental)Google Scholar
  48. 71Mam: A.N. Mamedov, S.M. Gadzhiev, and A.A. Kuliev, “Arsenic Vapor Pressure and Vapor Phase Composition,”Uch. Azerb. Univ., Khim. (2), 69–73 (1971) in Russian. (Thermo; Experimental)Google Scholar
  49. Indicates key paper 72Bru: S.B. Brumbach and G.M. Rosenblatt, “In-Cavity Laser Raman Spectroscopy of Vapors at Elevated Temperatures. As4 and As4O6,”J. Chem. Phys., 56, 3110–3117 (1972). (Thermo; Experimental)CrossRefADSGoogle Scholar
  50. 72Dug: M.J. Duggin, “High-Pressure Phase in Arsenic and Its Relation to Pressure-Induced Phase Changes in Group VB Elements,”J. Phys. Chem. Solids, 33, 1267–1271 (1972). (Equi Diagram; Experimental)CrossRefADSGoogle Scholar
  51. 72Gra: D.E. Gray, Ed.,American Institute of Physics Handbook, 3rd ed., 2–19 (1972). (Compilation)Google Scholar
  52. 72Kaz: R.I. Kazhlaeva and M.G. Shakhtakhtinskii, “Knudsen-Method Study of The Saturated Vapor-Pressure of Substances with a Slow Establishment of Vapor-Solid Equilibrium,”Izv. Akad. Nauk Azerb. SSR, Fiz, Tekh. Mat., (2), 52–55 (1972) in Russian. (Thermo; Experimental)Google Scholar
  53. Indicates key paper 73Ben: S.L. Bennett, J.L. Margrave, J.L. Franklin, and J.E. Hudson, “High Temperature Negative Ions. Electron Impact of Arsenic Vapor,”J. Chem. Phys., 59, 5814–5819 (1973). (Thermo; Experimental)CrossRefADSGoogle Scholar
  54. Indicates key paper 73Kor: J. Kordis and K.A. Gingerich, “Atomization Energy and Standard Heat of Formation of Gaseous Diatomic Arsenic,”J. Chem. Eng. Data, 18, 135–136 (1973). (Thermo; Experimental)CrossRefGoogle Scholar
  55. Indicates key paper 73Mur: J.J. Murray, C. Pupp, and R.F. Pottie, “Heat of Dissociation of Tetraarsenic (g) and the Heat of Formation of Diarsenic Gas,”J. Chem. Phys., 58, 2569–2578 (1973). (Thermo; Experimental)CrossRefADSGoogle Scholar
  56. 73Vig: E.N. Vigdorovich, V.V. Popov, M.M. Artamonov, and V.M. Andreev, “Phase Equilibria in the Ga-As System,”Izv. Akad. Nauk SSSR, Neorg. Mater., 9, 771–774 (1973) in Russian. (Thermo; Experimental)Google Scholar
  57. Indicates key paper 74Bak: E.H. Baker, “Thermodynamic Studies of the Arsenic Triple Point,”Inst. Min. Metall. Trans., C, 83, Bull. No. 817, C237-C240 (1974). (Equi Diagram, Thermo; Experimental)Google Scholar
  58. 74Fox: C.T. Foxon, B.A. Joyce, R.F.C. Farrow, and R.M. Griffiths, “Identification of Species Evolved in the Evaporation of III–V Compounds,”J. Phys. D, Appl. Phys., 7, 2422–2435 (1974). (Thermo; Experimental)CrossRefADSGoogle Scholar
  59. Indicates key paper 74Pup: C. Pupp, J.J. Murray, and R.F. Pottie, “Vapor Pressures of Arsenic Over Indium Arsenide (c) and Gallium Arsenide (c). Enthalpies of Formation of Indium Arsenide (c) and Gallium Arsenide (c),”J. Chem. Thermodyn., 6, 123–134 (1974). (Thermo; Experimental)CrossRefGoogle Scholar
  60. 75Gok: N.A. Gokcen,Thermodynamics, Techscience Inc. (1975). (Equi Diagram; Thermo)Google Scholar
  61. Indicates key paper 75Rau: H. Rau, “Vapour Composition and van der Waals Constants of Arsenic,”J. Chem. Thermodyn., 7, 27–32 (1975). (Equi Diagram, Thermo)CrossRefGoogle Scholar
  62. 76Ros: G.M. Rosenblatt, “Vaporization Rates, Surface Topography, and Vaporization Mechanisms of Single Crystals: A Case Study,”Acc. Chem. Res., 9, 169–175 (1976). (Thermo; Experimental)CrossRefGoogle Scholar
  63. 76Smi: P.M. Smith, H.A. Leadbetter, and A.J. Apling, “The Structure of Orthorhombic and Vitreous Arsenic,”Philos. Mag., 31, 57–64 (1976). (Equi Diagram; Crys Structure, Meta Phase)CrossRefADSGoogle Scholar
  64. 77Kle: P.D. Kleinschmidt, “A Study of the Relative Vaporization Rates of As2 and As4,” dissertation, Pennsylvania State University, University Park, PA, 139p (1977). (Thermo; Experimental)Google Scholar
  65. 77Mal: A.J. Mallmann “A Thermodynamic Study of the Solid-Vapor Arsenic System at Equilibrium Using Optical Absorption Techniques,” dissertation, Marquette University, Milwaukee, 143 p (1977). (Thermo; Experimental)Google Scholar
  66. 78Dro: J. Drowart, S. Smoes, and A. Vanderauwera-Mahieu, “The Atomization Enthalpies of AsSb(g), As4(g), Sb4(g), As3Sb(g), As2Sb2(g), AsSb3(g), As3SbO6(g), As2Sb2O6(g), and AsSb3O6(g). A Thermodynamic Study by the Mass-Spectrometric Knudsen-cell Method,”J. Chem. Thermodyn., 10, 453–464 (1978). (Thermo; Experimental)CrossRefGoogle Scholar
  67. 78Ita: K. Itagaki, T. Shimizu, and M. Hino, “Thermodynamic Studies of the Liquid Lead-Arsenic System,”Bull. Res. Inst. Miner. Dressing Metall., 34(1), 45–52 (1978) in Japanese. (Thermo; Experimental)Google Scholar
  68. 78Mur: V.G. Muradov, “The Partial Pressure of Atomic Arsenic in the Saturated Vapor,”Zh. Fiz. Khim., 52, 1555 (1978) in Russian. (Thermo; Experimental)Google Scholar
  69. 80Per: P. Perdigon and F. Martin, “Perturbation Study of the Ou+ Symmetry States of As2 Observed in the Energy Range 39000–45000 cm−1,”J. Molec. Spectrosc., 83, 40–63 (1980). (Thermo; Experimental)CrossRefADSGoogle Scholar
  70. 82Pan: L.B. Pankratz, “Thermodynamic Properties of Elements and Their Oxides,” U.S. Bur. Mines Bull. No. 672, 509 (1982). (Thermo; Compilation)Google Scholar
  71. Indicates key paper 82Rou: J.C. Rouland, R. Ceolin, C. Souleau, and P. Khodadad, “Differential Thermal Analysis of Arsenic Phase Diagram and Measurement of Its Enthalpy of Fusion at the Triple Point Conditions,”J. Therm. Anal., 23, 143–151 (1982) in French. (Equi Diagram, Thermo)CrossRefGoogle Scholar
  72. 82Rus: A.D. Rusin, L.M. Agamira, E.G. Zhukov, and V.T. Kalinnikov, “Sublimation Pressure of Arsenic,”Vestn. Mosk. Univ., Khim., 23(2), 104–107 (1982) in Russian. (Thermo; Experimental)Google Scholar
  73. 84Pan: L.B. Pankratz, J.M. Stuve, and N.A. Gokcen, “Thermodynamic Data for Mineral Technology,” U.S. Bur. Mines Bull. No. 677, 355 p (1984). (Thermo; Compilation)Google Scholar
  74. 84Wea: R.C. Weast,Handbook of Chemistry and Physics, 65th ed., CRC Press, Boca Raton, FL, B8 (1984–85). (Compilation)Google Scholar
  75. 87Bre: L. Brewer, private communication on thermodynamics of gaseous arsenic species (1987). (Thermo)Google Scholar
  76. 87Hud: J.E. Hudson, private communication on electron impact of As4 and As3 (1987). (Thermo)Google Scholar
  77. 87Mar: J.L. Margrave, private communication on electron impact of As4 and As3 (1987). (Thermo)Google Scholar
  78. 87Ode: L.L. Oden and G.L. Hundley, unpublished differential scanning data (1987). (Equi Diagram; Thermo)Google Scholar
  79. 87Ros: G.M. Rosenblatt, private communication on atomic and molecular spectra (1987). (Thermo)Google Scholar

Copyright information

© Springer 1989

Authors and Affiliations

  • N. A. Gokcen
    • 1
  1. 1.Dept. of InteriorAlbany Research Center, Bureau of MinesAlbany

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