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Electron energy loss spectroscopic study of Cr(CO)6, Mo(CO)6 and W(CO)6 in the vapour phase

  • T Pradeep
Inorganic and Analytical
  • 31 Downloads

Abstract

Electron energy loss spectra (EELS) of Cr, Mo and W hexacarbonyls in the vapour phase are reported. Most of the bands observed are similar to those in optical spectra, but the two high energy transitions in the 9·8–11·2 eV region are reported here for the first time. Based on the orbital energies from the ultraviolet photoelectron spectra and the electronic transition energies from EELS and earlier optical studies, the molecular energy level schemes of these molecules are constructed.

Keywords

Electron energy loss spectra transition metal hexacarbonyls molecular energy level schemes 

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Copyright information

© Indian Academy of Sciences 1990

Authors and Affiliations

  • T Pradeep
    • 1
  1. 1.Solid State and Structural Chemistry UnitIndian Institute of ScienceBangaloreIndia

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